Effect of Nickel Doping on the Cure Kinetics of Epoxy/Fe3O4 Nanocomposites
Abstract
:1. Problem Description
2. Development and Characterization of Nanocomposite
2.1. Chemicals
2.2. Preparation of Epoxy Nanocomposites
2.3. Characterization of Epoxy Nanocomposites
3. Quantitative Cure Analysis
3.1. Cure Behavior Analysis
3.2. Cure Kinetics Analysis
Determining the Reaction Model and the Order of Reaction
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Conflicts of Interest
References
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Sample | Tg (°C) |
---|---|
EP | 100.2 |
EP/Fe3O4 | 92.6 |
EP/Ni-Fe3O4 | 101.5 |
Designation | Heating Rate (°C/min) | αp∞ | αm | αp |
---|---|---|---|---|
EP [22,29] | 5 | 0.487 | 0.144 | 0.512 |
10 | 0.555 | 0.073 | 0.510 | |
15 | 0.418 | 0.236 | 0.498 | |
20 | 0.383 | 0.251 | 0.483 | |
EP/Fe3O4 [22,29] | 5 | 0.479 | 0.248 | 0.490 |
10 | 0.407 | 0.279 | 0.491 | |
15 | 0.532 | 0.193 | 0.518 | |
20 | 0.462 | 0.201 | 0.491 | |
EP/Ni-Fe3O4 | 5 | 0.473 | 0.146 | 0.490 |
10 | 0.400 | 0.296 | 0.475 | |
15 | 0.361 | 0.249 | 0.463 | |
20 | 0.514 | 0.208 | 0.487 |
Designation | Heating Rate (°C/min) | Friedman | KAS | ||||
---|---|---|---|---|---|---|---|
m | n | lnA (s−1) | m | n | lnA (s−1) | ||
EP [22,29] | 5 | 0.41 | 1.54 | 18.80 | 0.43 | 1.52 | 18.18 |
10 | 0.52 | 1.59 | 19.05 | 0.51 | 1.59 | 19.13 | |
15 | 0.44 | 1.68 | 18.98 | 0.46 | 1.66 | 18.39 | |
20 | 0.55 | 1.73 | 19.12 | 0.57 | 1.71 | 18.54 | |
EP/Fe3O4 [22,29] | 5 | 0.36 | 1.22 | 13.25 | 0.30 | 1.27 | 15.01 |
10 | 0.51 | 1.40 | 13.79 | 0.46 | 1.45 | 15.51 | |
15 | 0.32 | 1.18 | 13.24 | 0.25 | 1.23 | 14.89 | |
20 | 0.33 | 1.27 | 13.32 | 0.27 | 1.32 | 14.95 | |
Epoxy/Ni-Fe3O4 | 5 | 0.43 | 1.48 | 15.78 | 0.44 | 1.47 | 15.35 |
10 | 0.55 | 1.68 | 16.24 | 0.57 | 1.66 | 15.82 | |
15 | 0.46 | 1.54 | 15.90 | 0.47 | 1.53 | 15.50 | |
20 | 0.41 | 1.51 | 15.83 | 0.43 | 1.49 | 15.43 |
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Jouyandeh, M.; Karami, Z.; Paran, S.M.R.; Mashhadzadeh, A.H.; Ganjali, M.R.; Bagheri, B.; Zarrintaj, P.; Habibzadeh, S.; Vijayan P., P.; Saeb, M.R. Effect of Nickel Doping on the Cure Kinetics of Epoxy/Fe3O4 Nanocomposites. J. Compos. Sci. 2020, 4, 102. https://doi.org/10.3390/jcs4030102
Jouyandeh M, Karami Z, Paran SMR, Mashhadzadeh AH, Ganjali MR, Bagheri B, Zarrintaj P, Habibzadeh S, Vijayan P. P, Saeb MR. Effect of Nickel Doping on the Cure Kinetics of Epoxy/Fe3O4 Nanocomposites. Journal of Composites Science. 2020; 4(3):102. https://doi.org/10.3390/jcs4030102
Chicago/Turabian StyleJouyandeh, Maryam, Zohre Karami, Seyed Mohammad Reza Paran, Amin Hamed Mashhadzadeh, Mohammad Reza Ganjali, Babak Bagheri, Payam Zarrintaj, Sajjad Habibzadeh, Poornima Vijayan P., and Mohammad Reza Saeb. 2020. "Effect of Nickel Doping on the Cure Kinetics of Epoxy/Fe3O4 Nanocomposites" Journal of Composites Science 4, no. 3: 102. https://doi.org/10.3390/jcs4030102