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Magnetochemistry
Volume 2
Issue 4
10.3390/magnetochemistry2040046
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Open AccessFeature PaperArticle

Synthesis and Characterization of Ethylenedithio-MPTTF-PTM Radical Dyad as a Potential Neutral Radical Conductor

by
Manuel Souto
1,
Dan Bendixen
2,
Morten Jensen
2,
Valentín Díez-Cabanes
3,
Jérôme Cornil
3,
Jan O. Jeppesen
2,
Imma Ratera
1,*,
Concepció Rovira
1 and
Jaume Veciana
1,*
1
Department of Molecular Nanoscience and Organic Materials, Institut de Ciència de Materials de Barcelona (ICMAB-CSIC)/CIBER-BBN, Campus de la UAB, 08193 Bellaterra, Spain
2
Department of Physics, Chemistry and Pharmacy, University of Southern Denmark, 5230 Odense, Denmark
3
Laboratory for the Chemistry of Novel Materials, Université de Mons, 7000 Mons, Belgium
*
Authors to whom correspondence should be addressed.
Academic Editor: Manuel Almeida
Magnetochemistry 2016, 2(4), 46; https://doi.org/10.3390/magnetochemistry2040046
Received: 3 November 2016 / Revised: 7 December 2016 / Accepted: 9 December 2016 / Published: 16 December 2016
(This article belongs to the Special Issue Magnetism of Molecular Conductors)
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Abstract

During the last years there has been a high interest in the development of new purely-organic single-component conductors. Very recently, we have reported a new neutral radical conductor based on the perchlorotriphenylmethyl (PTM) radical moiety linked to a monopyrrolo-tetrathiafulvalene (MPTTF) unit by a π-conjugated bridge (1) that behaves as a semiconductor under high pressure. With the aim of developing a new material with improved conducting properties, we have designed and synthesized the radical dyad 2 which was functionalized with an ethylenedithio (EDT) group in order to improve the intermolecular interactions of the tetrathiafulvalene (TTF) subunits. The physical properties of the new radical dyad 2 were studied in detail in solution to further analyze its electronic structure. View Full-Text
Keywords: neutral organic radical; perchlorotriphenylmethyl radical; tetrathiafulvalene; donor-acceptor neutral organic radical; perchlorotriphenylmethyl radical; tetrathiafulvalene; donor-acceptor
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MDPI and ACS Style

Souto, M.; Bendixen, D.; Jensen, M.; Díez-Cabanes, V.; Cornil, J.; Jeppesen, J.O.; Ratera, I.; Rovira, C.; Veciana, J. Synthesis and Characterization of Ethylenedithio-MPTTF-PTM Radical Dyad as a Potential Neutral Radical Conductor. Magnetochemistry 2016, 2, 46.

AMA Style

Souto M, Bendixen D, Jensen M, Díez-Cabanes V, Cornil J, Jeppesen JO, Ratera I, Rovira C, Veciana J. Synthesis and Characterization of Ethylenedithio-MPTTF-PTM Radical Dyad as a Potential Neutral Radical Conductor. Magnetochemistry. 2016; 2(4):46.

Chicago/Turabian Style

Souto, Manuel; Bendixen, Dan; Jensen, Morten; Díez-Cabanes, Valentín; Cornil, Jérôme; Jeppesen, Jan O.; Ratera, Imma; Rovira, Concepció; Veciana, Jaume. 2016. "Synthesis and Characterization of Ethylenedithio-MPTTF-PTM Radical Dyad as a Potential Neutral Radical Conductor" Magnetochemistry 2, no. 4: 46.

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