Magnetochemistry 2016, 2(4), 46; https://doi.org/10.3390/magnetochemistry2040046
Synthesis and Characterization of Ethylenedithio-MPTTF-PTM Radical Dyad as a Potential Neutral Radical Conductor
Manuel Souto 1, Dan Bendixen 2, Morten Jensen 2, Valentín Díez-Cabanes 3, Jérôme Cornil 3, Jan O. Jeppesen 2, Imma Ratera 1,*
, Concepció Rovira 1 and Jaume Veciana 1,*
, Concepció Rovira 1 and Jaume Veciana 1,*
1
Department of Molecular Nanoscience and Organic Materials, Institut de Ciència de Materials de Barcelona (ICMAB-CSIC)/CIBER-BBN, Campus de la UAB, 08193 Bellaterra, Spain
2
Department of Physics, Chemistry and Pharmacy, University of Southern Denmark, 5230 Odense, Denmark
3
Laboratory for the Chemistry of Novel Materials, Université de Mons, 7000 Mons, Belgium
*
Authors to whom correspondence should be addressed.
Academic Editor: Manuel Almeida
Received: 3 November 2016 / Revised: 7 December 2016 / Accepted: 9 December 2016 / Published: 16 December 2016
(This article belongs to the Special Issue Magnetism of Molecular Conductors)
Abstract
During the last years there has been a high interest in the development of new purely-organic single-component conductors. Very recently, we have reported a new neutral radical conductor based on the perchlorotriphenylmethyl (PTM) radical moiety linked to a monopyrrolo-tetrathiafulvalene (MPTTF) unit by a π-conjugated bridge (1) that behaves as a semiconductor under high pressure. With the aim of developing a new material with improved conducting properties, we have designed and synthesized the radical dyad 2 which was functionalized with an ethylenedithio (EDT) group in order to improve the intermolecular interactions of the tetrathiafulvalene (TTF) subunits. The physical properties of the new radical dyad 2 were studied in detail in solution to further analyze its electronic structure. View Full-TextKeywords:
neutral organic radical; perchlorotriphenylmethyl radical; tetrathiafulvalene; donor-acceptor
▼
Figures
Figure 1
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).
Share & Cite This Article
MDPI and ACS Style
Souto, M.; Bendixen, D.; Jensen, M.; Díez-Cabanes, V.; Cornil, J.; Jeppesen, J.O.; Ratera, I.; Rovira, C.; Veciana, J. Synthesis and Characterization of Ethylenedithio-MPTTF-PTM Radical Dyad as a Potential Neutral Radical Conductor. Magnetochemistry 2016, 2, 46.
Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.
Related Articles
Article Metrics
Comments
[Return to top]
Magnetochemistry
EISSN 2312-7481
Published by MDPI AG, Basel, Switzerland
RSS
E-Mail Table of Contents Alert