Fragmentation Susceptibility of Controlled-Release Fertilizer Particles: Implications for Nutrient Retention and Sustainable Horticulture

As an important technology to enhance nutrient use efficiency and reduce agricultural non-point source pollution, controlled-release fertilizers (CRFs) have been widely applied in modern agriculture. However, during packaging, transportation, and field application, CRF particles are prone to mechanical impacts, which can lead to particle fragmentation and damage to the controlled-release coating. This compromises the release kinetics, increases nutrient loss risk, and ultimately exacerbates environmental issues such as eutrophication. Currently, studies on the impact-induced fragmentation behavior of CRF particles remain limited, and there is an urgent need to investigate their fragmentation susceptibility mechanisms from the perspective of internal stress evolution. In this study, the mechanical properties of CRF particles were first experimentally determined to obtain essential parameters. A two-layer finite element model representing the coating and core structure of the particles was then constructed, and a fragmentation susceptibility index was proposed as the key evaluation criterion. The index, defined as the ratio of fractured volume to peak impact energy, reflects the efficiency of energy conversion at the critical moment of particle rupture (1–5). An explicit dynamic simulation framework incorporating multiple influencing factors—equivalent diameter, sphericity, impact material, velocity, and angle—was developed to analyze fragmentation behavior from the perspective of energy transformation. Based on the observed effects of these variables on fragmentation susceptibility, three regression models were developed using response surface methodology to quantitatively predict fragmentation susceptibility. Comparative analysis between the simulation and experimental results showed a fragmentation rate error range of 0–11.47%. The findings reveal the relationships between particle fragmentation modes and energy responses under various impact conditions. This research provides theoretical insights and technical guidance for optimizing the mechanical stability of CRFs and developing environmentally friendly fertilization strategies.