Cellulose-Based Metallogels—Part 1: Raw Materials and Preparation
Abstract
:1. Introduction
2. Cellulose Metallogels
3. Raw Materials
4. Preparation of Cellulose Hydrogels
4.1. N,N-Dimethylacetamide/LiCl
4.2. Dimethyl Sulfoxide/LiCl
4.3. N-Methylmorpholine-N-oxide
4.4. Alkaline Aqueous Systems
- (1)
- Protocols for the production of hydrogels from cellulose are very similar for the three organic solvents considered, namely DMAc/LiCl, DMSO/LiCl, NNMO, while cellulose hydrogels obtained from NaOH-aqueous solutions involve cooling of the system.
- (2)
- The most common solvents are DMAc/LiCl and NaOH; NNMO and DMSO/LiClare used less frequently.
- (3)
- Each solvent has pros and cons (Table 2). Thus, the NaOH-aqueous system is inexpensive and environmentally beneficial; however, there are limitations to the dissolution of some types of cellulose. These drawbacks can be minimized due to extensive pre-treatment of cellulose which is an additional step in the production process. Usually, the hydrogels are synthesized from NaOH-solutions with such additives as urea and/or thiourea and crosslinking with ECH.
Solvent | Pre-Treatment of Cellulose | Dissolution Process | Gelation Process | Price * | Toxicity |
---|---|---|---|---|---|
DMAc/LiCl | solvent exchange (not compulsory) | 25–80 °C | humid ambient condition | 161 GBP/L (+28 GBP/100 g for LiCl) | harmful, flammable |
DMSO/LiCl | ball-milling complexation | 65–70 °C | ethanol, cross-linking | 89 GBP/L (+28 GBP/100 g for LiCl) | non-toxic, flammable |
NMMO | - | 110 °C, −0.1 MPa | 110 °C, −0.1 MPa | 1110 GBP/kg | low toxic, non- flammable |
NaOH/water | hydrothermal, steam explosion, chemical, or enzymatic treatment | (−20)–0 °C, addition of urea/ thiourea | cross-linking (not compulsory), cooling (approximately 0 °C) | 35 GBP/kg | non-toxic, non- flammable |
5. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Acknowledgments
Conflicts of Interest
References
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Mikhailidi, A.; Volf, I.; Belosinschi, D.; Tofanica, B.-M.; Ungureanu, E. Cellulose-Based Metallogels—Part 1: Raw Materials and Preparation. Gels 2023, 9, 390. https://doi.org/10.3390/gels9050390
Mikhailidi A, Volf I, Belosinschi D, Tofanica B-M, Ungureanu E. Cellulose-Based Metallogels—Part 1: Raw Materials and Preparation. Gels. 2023; 9(5):390. https://doi.org/10.3390/gels9050390
Chicago/Turabian StyleMikhailidi, Aleksandra, Irina Volf, Dan Belosinschi, Bogdan-Marian Tofanica, and Elena Ungureanu. 2023. "Cellulose-Based Metallogels—Part 1: Raw Materials and Preparation" Gels 9, no. 5: 390. https://doi.org/10.3390/gels9050390