Synthesis and Characterization of Gamma Radiation Induced Diallyldimethylammonium Chloride-Acrylic Acid-(3-Acrylamidopropyl) Trimethylammonium Chloride Superabsorbent Hydrogel
Abstract
:1. Introduction
2. Results and Discussion
2.1. Radiation Polymerization of DADMAC-AAc-APTAC
2.2. Effect of Radiation Dose on APTAC-AAc-DADMAC Gel Content
2.3. Effect of Radiation Dose on Equilibrium Swelling of Gels
2.4. Characterization of Hydrogel by FTIR Spectroscopy
2.5. X-ray Diffraction Analysis
2.6. Nuclear Magnetic Resonance (NMR) Spectroscopy
2.7. Thermogravimetric Analysis (TGA)
2.8. Surface Analysis by SEM-EDS
3. Conclusions
4. Materials and Methods
4.1. Materials and Reagents
4.2. Apparatus and Instruments
4.3. Synthesis of DADMAC-AAc-APTAC Hydrogels by Gamma Radiation
4.4. Post-Synthesis Analysis
4.4.1. Extraction and Measurement of Gel Content
4.4.2. Measurement of Super-Absorbency at Equilibrium Swelling
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Element | Weight % | Weight % Sigma |
---|---|---|
Carbon (C) | 59.15 | 0.59 |
Nitrogen (N) | 7.55 | 0.76 |
Oxygen (O) | 28.38 | 0.40 |
Chlorine (Cl) | 4.92 | 0.08 |
Total: | 100 |
Composition of Raw Materials | Observation |
---|---|
DADMAC (10%) + APTAC (10%) | No hydrogel found |
DADMAC (10%) + AAc (10%) + APTAC (10%) | Solid Hydrogel found |
DADMAC (10%) + AAc (5%) + APTAC (10%) | Solid Hydrogel found |
Radiation Dose (kGy) | 2 | 5 | 10 | 20 | 30 |
---|---|---|---|---|---|
Gel Product | Solid gel | Solid gel | Solid gel | Solid gel | Solid gel |
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Bhuyan, M.M.; Jeong, J.-H. Synthesis and Characterization of Gamma Radiation Induced Diallyldimethylammonium Chloride-Acrylic Acid-(3-Acrylamidopropyl) Trimethylammonium Chloride Superabsorbent Hydrogel. Gels 2023, 9, 159. https://doi.org/10.3390/gels9020159
Bhuyan MM, Jeong J-H. Synthesis and Characterization of Gamma Radiation Induced Diallyldimethylammonium Chloride-Acrylic Acid-(3-Acrylamidopropyl) Trimethylammonium Chloride Superabsorbent Hydrogel. Gels. 2023; 9(2):159. https://doi.org/10.3390/gels9020159
Chicago/Turabian StyleBhuyan, Md Murshed, and Jae-Ho Jeong. 2023. "Synthesis and Characterization of Gamma Radiation Induced Diallyldimethylammonium Chloride-Acrylic Acid-(3-Acrylamidopropyl) Trimethylammonium Chloride Superabsorbent Hydrogel" Gels 9, no. 2: 159. https://doi.org/10.3390/gels9020159