Selective Adsorption of Ionic Species Using Macroporous Monodispersed Polyethylene Glycol Diacrylate/Acrylic Acid Microgels with Tunable Negative Charge
Abstract
:1. Introduction
2. Results and Discussion
2.1. Optimisation of Fluid Flow Rates and UV Exposure Time
2.2. Droplet and Particle Polydispersity
2.3. ATR-FTIR
2.4. SEM Characterisation
2.5. Adsorption of Organic Dyes onto PEGDA and PEGDA–AA Microgels
2.5.1. Adsorption of Cationic Dye (MB) onto Nonporous and Macroporous PEGDA and PEGDA/AA Microgels
2.5.2. Comparison of Adsorption Efficiency of Cationic Dye (MB) and Amphoteric Dye (RhB) onto Nonporous PEGDA/AA Microgels
2.5.3. Adsorption of Anionic Dyes (MO and CR) onto Nonporous PEGDA/AA Microgels
2.5.4. Adsorption of Copper Cations onto Nonporous and Macroporous PEGDA and PEGDA/AA Microgels
3. Conclusions
4. Materials and Methods
4.1. Materials
4.2. Glass Capillary Microfluidic Device
4.3. Microgel Synthesis
4.4. Characterisation of Droplets and Particles
4.5. Batch Adsorption Experiments
4.6. Equilibrium Analysis
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Sample | DP Flow Rate, Qd (mL/h) | CP Flow Rate, Qc (mL/h) | UV Exposure Time (s) |
---|---|---|---|
PEGDA | 0.10 | 0.35 | 75 |
PEGDA–PEG | 0.13 | 0.70 | 300 |
PEGDA–AA(2%) | 0.16 | 0.45 | 360 |
PEGDA–PEG–AA(2%) | 0.20 | 0.55 | 600 |
PEGDA–AA(4%) | 0.16 | 0.45 | 360 |
PEGDA–PEG–AA(4%) | 0.17 | 0.34 | 600 |
Adsorbent | Langmuir Isotherm | Freundlich Isotherm | ||||
---|---|---|---|---|---|---|
qm, mg/g | KL | R | nF | KF | R | |
PEGDA, pH = 6.3 | 2.9 | 0.58 | 0.984 | 4.6 | 1.2 | 0.955 |
PEGDA–PEG, pH = 6.3 | 6.4 | 0.33 | 0.996 | 3.5 | 2.0 | 0.964 |
PEGDA–AA(2%), pH = 6.3 | 8.8 | 0.19 | 0.989 | 2.9 | 2.1 | 0.975 |
PEGDA–PEG–AA(2%), pH = 6.3 | 15 | 0.20 | 0.996 | 2.8 | 3.5 | 0.974 |
PEGDA–AA(4%), pH = 6.3 | 15 | 0.15 | 0.996 | 2.6 | 3.0 | 0.982 |
PEGDA–PEG–AA(4%), pH = 6.3 | 30 | 0.15 | 0.993 | 2.1 | 5.0 | 0.967 |
PEGDA–AA(4%), pH = 8.6 | 23 | 0.58 | 0.991 | 3.5 | 8.8 | 0.991 |
PEGDA–PEG–AA(4%), pH = 8.6 | 45 | 0.21 | 0.978 | 3.4 | 15 | 0.983 |
Dye | , % | , mg/g |
---|---|---|
MB | 81.1 | 3.0 |
RhB | 52.6 | 2.0 |
Dye | , % | , mg/g |
---|---|---|
MO | 0 | 0 |
CR | 29.6 | 0.7 |
Adsorbent | pH | , % | , mg/g |
---|---|---|---|
PEGDA | 5.5 | 6.2 | 1.1 |
PEGDA–AA(2%) | 5.5 | 7.0 | 1.3 |
PEGDA–AA(4%) | 5.5 | 27.1 | 3.7 |
PEGDA–PEG–AA(4%) | 5.5 | 72.2 | 13.8 |
PEGDA–AA(4%) | 6.7 | 67.4 | 11.2 |
PEGDA–PEG–AA(4%) | 6.7 | 98.3 | 22.7 |
PI (wt%) | PEGDA (wt%) | AA (wt%) | PEG (wt%) | DIW (wt%) | |
---|---|---|---|---|---|
PEGDA | 2 | 98 | - | - | - |
PEGDA–PEG | 2 | 78 | - | 20 | - |
PEGDA–AA (2%) | 2 | 76 | 2 | - | 20 |
PEGDA–PEG–AA (2%) | 2 | 38 | 2 | 20 | 38 |
PEGDA–AA (4%) | 2 | 74 | 4 | - | 20 |
PEGDA–PEG–AA (4%) | 2 | 38 | 4 | 20 | 36 |
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Chen, M.; Kumrić, K.R.; Thacker, C.; Prodanović, R.; Bolognesi, G.; Vladisavljević, G.T. Selective Adsorption of Ionic Species Using Macroporous Monodispersed Polyethylene Glycol Diacrylate/Acrylic Acid Microgels with Tunable Negative Charge. Gels 2023, 9, 849. https://doi.org/10.3390/gels9110849
Chen M, Kumrić KR, Thacker C, Prodanović R, Bolognesi G, Vladisavljević GT. Selective Adsorption of Ionic Species Using Macroporous Monodispersed Polyethylene Glycol Diacrylate/Acrylic Acid Microgels with Tunable Negative Charge. Gels. 2023; 9(11):849. https://doi.org/10.3390/gels9110849
Chicago/Turabian StyleChen, Minjun, Ksenija R. Kumrić, Conner Thacker, Radivoje Prodanović, Guido Bolognesi, and Goran T. Vladisavljević. 2023. "Selective Adsorption of Ionic Species Using Macroporous Monodispersed Polyethylene Glycol Diacrylate/Acrylic Acid Microgels with Tunable Negative Charge" Gels 9, no. 11: 849. https://doi.org/10.3390/gels9110849