Residues and Safety Assessment of Cyantraniliprole and Indoxacarb in Wild Garlic (Allium vineale)
Abstract
:1. Introduction
2. Materials and Methods
2.1. Standards and Reagents
2.2. Field Experiments
2.3. Sample Pretreatment and Analysis
2.4. Method Validation
2.5. Initial Residue Calculations
2.6. Half-Life Calculations
2.7. Safety Assessments
3. Results and Discussion
3.1. Method Validation
3.2. Initial Depositions and Dissipations of Cyantraniliprole and Indoxacarb
3.3. Residual Behavior of Pesticides
3.4. Pre-Harvest Interval (PHI)
3.5. Safety Assessment
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Pesticides | Fortification Level (mg/kg) | (Recoveries ± RSDs (a)) (%) | LOQ (b) (mg/kg) | |
---|---|---|---|---|
Intraday | Interday | |||
Cyantraniliprole | 0.01 0.1 | 94.2 ± 5.9 98.7 ± 6.0 | 89.8 ± 7.4 93.8 ± 7.7 | 0.01 |
Indoxacarb | 0.01 0.1 | 111.4 ± 4.2 105.0 ± 1.8 | 98.5 ± 5.7 95.2 ± 4.2 |
Pesticides | Residual Amount at 0 Day (mg/kg) | Initial Residual Amount (mg/kg) |
---|---|---|
Cyantraniliprole | 0.04 | 0.4 |
Indoxacarb | 0.14 | 0.7 |
Pesticides | Days after the Last Spraying | Average Residual Amount (mg/kg) |
---|---|---|
Cyantraniliprole | 0 | 0.04 B |
3 | 0.03 CB | |
7 | 0.01 ED | |
14 | 0.01 ED | |
Indoxacarb | 0 | 0.14 A |
3 | 0.02 CD | |
7 | 0.01 ED | |
14 | <0.01 E |
Pesticides | Recommended PHI | MRL (mg/kg) |
---|---|---|
Cyantraniliprole | Two treatments 7 days before harvest | 0.03 (a) |
Indoxacarb | 0.05 |
Pesticides | MRL (mg/kg) | Daily Intake (g/Day) | EDI (mg/kg) | %ADI (mg/kg) | TMDI (%) |
---|---|---|---|---|---|
Cyantraniliprole | 0.03 (1) | 0.02 | 0.1 × 10−5 | 0.3 × 10−4 | 9.80 |
Indoxacarb | 2.0 (2) | 0.4 × 10−4 | 6.7 × 10−2 | 60.54 |
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Sardar, S.W.; Choi, J.Y.; Jo, Y.J.; Ishag, A.E.S.A.; Kim, M.-w.; Ham, H.J. Residues and Safety Assessment of Cyantraniliprole and Indoxacarb in Wild Garlic (Allium vineale). Toxics 2023, 11, 219. https://doi.org/10.3390/toxics11030219
Sardar SW, Choi JY, Jo YJ, Ishag AESA, Kim M-w, Ham HJ. Residues and Safety Assessment of Cyantraniliprole and Indoxacarb in Wild Garlic (Allium vineale). Toxics. 2023; 11(3):219. https://doi.org/10.3390/toxics11030219
Chicago/Turabian StyleSardar, Syed Wasim, Jeong Yoon Choi, Yeong Ju Jo, Abd Elaziz Sulieman Ahmed Ishag, Min-woo Kim, and Hun Ju Ham. 2023. "Residues and Safety Assessment of Cyantraniliprole and Indoxacarb in Wild Garlic (Allium vineale)" Toxics 11, no. 3: 219. https://doi.org/10.3390/toxics11030219