Recognition of Heavy Metals by Using Resorcin[4]arenes Soluble in Water
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Equipments and Experimental Techniques
2.2.1. Conductometry
2.2.2. Ion-Selective Potentiometry (ISE)
2.2.3. Atomic Absorption
3. Results and Discussion
3.1. Complexation of Na4BRA with Cu2+
3.2. Complexation of Na4BRA with Pb2+
3.3. Complexation of Na4BRA with either Cd2+ or Hg2+
3.4. Complexation of Na4SRA with Hg2+
3.5. Complexation of Na4SRA with either Cu2+, Pb2+, or Cd2+
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Host | Cu2+ | Pb2+ | Cd2+ | Hg2+ |
---|---|---|---|---|
Na4BRA | Conductometry Ion-selective potentiometry (ISE) | Conductometry Atomic absorption | ·Conductometry | Conductometry |
Na4SRA | Conductometry | Conductometry | ·Conductometry | Conductometry Atomic absorption |
Substance | Source | Purity |
---|---|---|
Cu(ClO4)2·6H2O | Alfa Aesar | >98% |
Pb(ClO4)2·3H2O | Alfa Aesar | 97% min. |
Cd(ClO4)2·6H2O | Alfa Aesar | >99% |
Hg(ClO4)2·3H2O | Alfa Aesar | >99% |
Host/Guest | Cu2+ | Pb2+ | Cd2+ | Hg2+ |
---|---|---|---|---|
Na4BRA | 1:1 | 1:2 | - | - |
Na4SRA | - | - | - | 1:1 |
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Sanabria, E.; Esteso, M.A.; Vargas, E.F. Recognition of Heavy Metals by Using Resorcin[4]arenes Soluble in Water. Toxics 2022, 10, 461. https://doi.org/10.3390/toxics10080461
Sanabria E, Esteso MA, Vargas EF. Recognition of Heavy Metals by Using Resorcin[4]arenes Soluble in Water. Toxics. 2022; 10(8):461. https://doi.org/10.3390/toxics10080461
Chicago/Turabian StyleSanabria, Edilma, Miguel A. Esteso, and Edgar F. Vargas. 2022. "Recognition of Heavy Metals by Using Resorcin[4]arenes Soluble in Water" Toxics 10, no. 8: 461. https://doi.org/10.3390/toxics10080461