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Inorganics 2018, 6(1), 11;

Effect of Water Content on Properties of Homogeneous [bmim]Fe(III)Cl4–H2O Mixtures and Their Application in Oxidative Absorption of H2S

Department of Environmental Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China
Author to whom correspondence should be addressed.
Received: 10 November 2017 / Revised: 22 December 2017 / Accepted: 3 January 2018 / Published: 8 January 2018
(This article belongs to the Special Issue Organometallic Ionic Liquid)
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The potential of 1-butyl-3-methylimidazolium tetrachloroferrate ([bmim]Fe(III)Cl4) for replacing an iron(III) chelate catalytic solution in the catalytic oxidation of H2S is attributed to its no side reaction and no degradation of the chelating agent. The catalytic oxidation product of water in non-aqueous [bmim]Fe(III)Cl4 possibly has an influence on the oxidative absorption of H2S. Water and hydrophobic [bmim]Fe(III)Cl4 mixtures at water volume percents from 40% to 70% formed separate phases after srirring, without affecting the oxidative absorption of hydrogen sulfide. Then, studies on the properties of homogeneous [bmim]Fe(III)Cl4–H2O mixtures at water volume percents in the range of 5.88–30% and above 80% reveal that these mixtures are both Brønsted and Lewis acids at vol % (H2O) ≤ 30%, and only Lewis acids at vol % (H2O) ≥ 80%. Raman spectra showed that [bmim]Fe(III)Cl4 was the dominating species at vol % (H2O) ≤ 30%, in contrast, [bmim]Fe(III)Cl4 decomposed into FeCl3·2H2O and [bmim]Cl at vol % (H2O) ≥ 80%. Further research on oxidative absorption of H2S by homogeneous [bmim]Fe(III)Cl4–H2O mixtures demonstrated that [bmim]Fe(III)Cl4 was reduced by H2S to [bmim]Fe(II)Cl4H and FeCl3·2H2O was reduced to FeCl2, at the same time, H2S was oxidized to S8. In addition, the decrease in acidity caused by increasing the water content increased the weight percent of absorbed H2S, and decreased volatile HCl emissions. However, it is difficult to prevent the suspended S8 generated at vol % (H2O) ≥ 80% from the formation of sulfur blockage. Therefore, oxidative absorption of H2S by [bmim]Fe(III)Cl4–H2O mixtures is feasible at vol % (H2O) < 80% without sulfur blockage. View Full-Text
Keywords: [bmim]Fe(III)Cl4; hydrogen sulfide; water; homogeneous mixtures [bmim]Fe(III)Cl4; hydrogen sulfide; water; homogeneous mixtures

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Wang, J.; Ding, R. Effect of Water Content on Properties of Homogeneous [bmim]Fe(III)Cl4–H2O Mixtures and Their Application in Oxidative Absorption of H2S. Inorganics 2018, 6, 11.

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