Next Article in Journal / Special Issue
Dehydrogenation of Surface-Oxidized Mixtures of 2LiBH4 + Al/Additives (TiF3 or CeO2)
Previous Article in Journal
Ruthenium-Catalyzed Dimerization of 1,1-Diphenylpropargyl Alcohol to a Hydroxybenzocyclobutene and Related Reactions
Previous Article in Special Issue
Tetrahydroborates: Development and Potential as Hydrogen Storage Medium
Article Menu
Issue 4 (December) cover image

Export Article

Open AccessArticle
Inorganics 2017, 5(4), 81; https://doi.org/10.3390/inorganics5040081

Thermodynamic Properties and Reversible Hydrogenation of LiBH4–Mg2FeH6 Composite Materials

1
Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan
2
Department of Nanotechnology for Sustainable Energy, School of Science and Technology, Kwansei Gakuin University, Sanda 669-1337, Japan
3
Department of Nanotechnology, Institute of Materials Research, Helmholtz-Zentrum Geesthacht, D-21502 Geesthacht, Germany
4
WPI-Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Sendai 980-8577, Japan
*
Author to whom correspondence should be addressed.
Received: 8 October 2017 / Revised: 2 November 2017 / Accepted: 2 November 2017 / Published: 16 November 2017
(This article belongs to the Special Issue Functional Materials Based on Metal Hydrides)
Full-Text   |   PDF [3177 KB, uploaded 16 November 2017]   |  

Abstract

In previous studies, complex hydrides LiBH4 and Mg2FeH6 have been reported to undergo simultaneous dehydrogenation when ball-milled as composite materials (1 − x)LiBH4 + xMg2FeH6. The simultaneous hydrogen release led to a decrease of the dehydrogenation temperature by as much as 150 K when compared to that of LiBH4. It also led to the modified dehydrogenation properties of Mg2FeH6. The simultaneous dehydrogenation behavior between stoichiometric ratios of LiBH4 and Mg2FeH6 is not yet understood. Therefore, in the present work, we used the molar ratio x = 0.25, 0.5, and 0.75, and studied the isothermal dehydrogenation processes via pressure–composition–isothermal (PCT) measurements. The results indicated that the same stoichiometric reaction occurred in all of these composite materials, and x = 0.5 was the molar ratio between LiBH4 and Mg2FeH6 in the reaction. Due to the optimal composition ratio, the composite material exhibited enhanced rehydrogenation and reversibility properties: the temperature and pressure of 673 K and 20 MPa of H2, respectively, for the full rehydrogenation of x = 0.5 composite, were much lower than those required for the partial rehydrogenation of LiBH4. Moreover, the x = 0.5 composite could be reversibly hydrogenated for more than four cycles without degradation of its H2 capacity. View Full-Text
Keywords: complex hydride; composite material; hydrogen storage complex hydride; composite material; hydrogen storage
Figures

Figure 1

This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).
SciFeed
Printed Edition Available!
A printed edition of this Special Issue is available here.

Share & Cite This Article

MDPI and ACS Style

Li, G.; Matsuo, M.; Takagi, S.; Chaudhary, A.-L.; Sato, T.; Dornheim, M.; Orimo, S.-I. Thermodynamic Properties and Reversible Hydrogenation of LiBH4–Mg2FeH6 Composite Materials. Inorganics 2017, 5, 81.

Show more citation formats Show less citations formats

Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]
Inorganics EISSN 2304-6740 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top