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Inorganics 2016, 4(4), 41;

Ammonothermal Synthesis and Crystal Structures of Diamminetriamidodizinc Chloride [Zn2(NH3)2(NH2)3]Cl and Diamminemonoamidozinc Bromide [Zn(NH3)2(NH2)]Br

Institute of Inorganic Chemistry, Universität Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany
Institute of Process Machinery and Systems Engineering, University of Erlangen-Nuremberg, Cauerstraße 4, 91058 Erlangen, Germany
Author to whom correspondence should be addressed.
Academic Editors: Helmut Cölfen and Duncan H. Gregory
Received: 7 November 2016 / Revised: 5 December 2016 / Accepted: 6 December 2016 / Published: 9 December 2016
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The treatment of excess zinc in the presence of ammonium chloride under ammonothermal conditions of 873 K and 97 MPa leads to diamminetriamidodizinc chloride [Zn2(NH3)2(NH2)3]Cl with a two-dimensionally μ-amido-interconnected substructure. Similar reaction conditions using ammonium bromide instead of the chloride (773 K, 230 MPa) result in diamminemonoamidozinc bromide [Zn(NH3)2(NH2)]Br with one-dimensional infinite μ-amido-bridged chains. Both compounds were obtained as colorless, very moisture sensitive crystals. Crystal structures and hydrogen bond schemes are analyzed. Raman spectroscopic data of the chloride are reported. View Full-Text
Keywords: ammonothermal synthesis; amides; ammoniates; zinc ammonothermal synthesis; amides; ammoniates; zinc

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Richter, T.M.M.; Strobel, S.; Alt, N.S.A.; Schlücker, E.; Niewa, R. Ammonothermal Synthesis and Crystal Structures of Diamminetriamidodizinc Chloride [Zn2(NH3)2(NH2)3]Cl and Diamminemonoamidozinc Bromide [Zn(NH3)2(NH2)]Br. Inorganics 2016, 4, 41.

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