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Carbon-Based Nanomaterials Functionalized with Ionic Liquids for Microextraction in Sample Preparation

Laboratory of Analytical Chemistry, Department of Chemistry, University of Ioannina, Ioannina 45110, Greece
Author to whom correspondence should be addressed.
Academic Editors: Jared L. Anderson and Victoria F. Samanidou
Separations 2017, 4(2), 14;
Received: 9 February 2017 / Revised: 30 March 2017 / Accepted: 4 April 2017 / Published: 10 April 2017
(This article belongs to the Special Issue Trends in Microextraction Techniques for Sample Preparation)
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A large number of carbon-based nanomaterials has been investigated as sorbents in sample preparation, including fullerenes, carbon nanotubes, nanofibers, nanohorns and graphene, as well as their functionalized forms. Taking into account their properties, carbon-based nanomaterials have found a wide range of applications in different sample preparation techniques. Ionic liquids, as an alternative to environmentally-harmful ordinary organic solvents, have attracted extensive attention and gained popularity in analytical chemistry covering different fields like chromatography, electrochemistry and (micro)extraction. Some of the properties of ionic liquids, including polarity, hydrophobicity and viscosity, can be tuned by the proper selection of the building cations and anions. Their tunable nature allows the synthesis of tailor-made solvents for different applications. This review provides a snapshot of the most important features and applications of different carbon-based nanomaterials functionalized with ionic liquids for sample preparation. Emphasis is placed on the description of the different works that have provided interesting results for the use of graphene and carbon nanotubes, in this analytical field. View Full-Text
Keywords: graphene; carbon nanotubes; ionic liquid; magnetic; microextraction; sample preparation graphene; carbon nanotubes; ionic liquid; magnetic; microextraction; sample preparation

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Chatzimitakos, T.; Stalikas, C. Carbon-Based Nanomaterials Functionalized with Ionic Liquids for Microextraction in Sample Preparation. Separations 2017, 4, 14.

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