Abstract
Heavy metal contamination in coastal and ballast waters motivates the development of low-cost, environmentally compatible filtration media. This study investigates how 6 MeV electron-beam irradiation (0–100 Gy) modifies the surface electronic and chemical properties of quartz-rich Baltic Sea sands collected from four Latvian coastal locations (Riga, Salacgriva, Ventspils, and Liepaja), and how these modifications affect chromium removal from aqueous K2CrO4 solutions. Surface electronic behavior was evaluated by near-threshold photoelectron emission spectroscopy (PEES), including electron work function (EWF) and analysis of differentiated spectra, while irradiation-associated changes in near-surface chemistry were assessed by X-ray photoelectron spectroscopy (XPS). Filtration performance was quantified by UV–Vis absorbance of filtrates. Across all sands, EWF values remained within ~4.7–4.9 eV; however, irradiation effects were strongly site-dependent. Liepaja sand exhibited the most pronounced response, including an EWF increase at 40 Gy, a shift in the differentiated PEES peak toward higher photon energies at ≥40 Gy, and the largest integrated photoemission intensity across doses, consistent with an elevated relative photoemission response under identical acquisition and processing conditions. XPS trends for Liepaja were consistent with irradiation-driven modification of the Si–O environment, while other sites showed comparatively minor changes. Filtration results mirrored these observations: Liepaja sand demonstrated the clearest dose-dependent enhancement in chromium removal with a non-monotonic feature at 40 Gy, consistent with competing formation and transformation of oxygen-related surface-reactive centers. Overall, the results show that electron-beam irradiation can modestly enhance Cr(VI) removal by natural quartz sands, with the magnitude governed by site-specific near-surface electronic structure and its dose-dependent evolution.