Advanced Sensing of Antibiotics with Sr@Se Flower-Like Structure on Phosphorus-Doped g-C3N4 Composite: Application towards Detection of Chloramphenicol in Food Samples
Abstract
:1. Introduction
2. Materials and Methods
2.1. Reagents and Materials
2.2. Apparatus
2.3. Synthesis of Sr@Se
2.4. Preparation of PGCN
2.5. Fabrication of the Sr@Se/PGCN/GCE
3. Results
3.1. Electrochemical Performance of the Sr@Se/PGCN Nanocomposite
3.2. Electrochemical Performance of the Sr@Se/PGCN Composite with CAP
3.3. pH and CAP Concentrations
3.4. Scan Rate
3.5. Quantification of CAP
3.6. Interference Studies
3.7. Reproducibility and Stability
3.8. Real Sample Analysis
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Acknowledgments
Conflicts of Interest
References
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Electrocatalyst | Detection Technique | pH Values | Linear Range (µM) | LOD (nM) | References |
---|---|---|---|---|---|
Fe3O4/Au/GCE | DPV | 5 | 1.0–12 | 144 | [51] |
Co@NCNP/GCE | DPV | 7 | 5–268.83 | 500 | [52] |
Ag/CMC@TiO2/LIG | DPV | 7 | 0.01–100 | 7 | [53] |
GdBiVO4@rGO/SPCE | DPV | 7 | 0.05–2336.55 | 22.9 | [54] |
Sr2Co2O5/GCE | DPV | 7 | 0.01–931.1 | 2.3 | [55] |
Sr@Se/PGCN/GCE | DPV | 9 | 5–450 | 2.7 | Present work |
Samples | Added (µM) | Found (µM) | Recovery (%) | RSD (%) |
---|---|---|---|---|
Milk | 50 | 49.97 | 99.40 | 2.8 |
100 | 99.9 | 99.9 | 2.3 | |
Honey | 50 | 49.5 | 90.0 | 3.6 |
100 | 99.95 | 99.77 | 2.8 |
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Prasanna, S.B.; Kumar, G.K.S.; Shadakshari, S.; Shivamurthy, S.A.; Shanthakumar, K.C.; Nagaraja, B.M.; Chung, R.-J. Advanced Sensing of Antibiotics with Sr@Se Flower-Like Structure on Phosphorus-Doped g-C3N4 Composite: Application towards Detection of Chloramphenicol in Food Samples. Chemosensors 2022, 10, 425. https://doi.org/10.3390/chemosensors10100425
Prasanna SB, Kumar GKS, Shadakshari S, Shivamurthy SA, Shanthakumar KC, Nagaraja BM, Chung R-J. Advanced Sensing of Antibiotics with Sr@Se Flower-Like Structure on Phosphorus-Doped g-C3N4 Composite: Application towards Detection of Chloramphenicol in Food Samples. Chemosensors. 2022; 10(10):425. https://doi.org/10.3390/chemosensors10100425
Chicago/Turabian StylePrasanna, Sanjay Ballur, Gagan Kumar Sakaleshpur Kumar, Sandeep Shadakshari, Santhosh Arehalli Shivamurthy, Karthik Chimatahalli Shanthakumar, Bhari Mallanna Nagaraja, and Ren-Jei Chung. 2022. "Advanced Sensing of Antibiotics with Sr@Se Flower-Like Structure on Phosphorus-Doped g-C3N4 Composite: Application towards Detection of Chloramphenicol in Food Samples" Chemosensors 10, no. 10: 425. https://doi.org/10.3390/chemosensors10100425