2.2. Analysis of Particle Collision Contact Forces and Adhesion Criteria
Considering the unique adhesive behavior and plastic deformation characteristics of colloidal particles, a theoretical framework was developed by referencing and integrating multiple classical collision theories. For particle collision analysis, the Hertzian contact theory was primarily selected as the theoretical foundation. This contact theory serves as the basis for solving elastic contact problems between curved particle surfaces, with the following fundamental assumptions: the contacting particle surfaces are smooth and homogeneous, the contact area is negligible compared to the particle size, only elastic deformation occurs within the contact zone, and the contact force acts normal to the contact surface.
Building upon this foundation, an extended investigation of the adhesion behavior of gel particles was conducted. Based on fundamental contact theory and considering the viscoelastic–plastic collision characteristics inherent to the gel particles under study (as illustrated in
Figure 2), a schematic diagram of elastic collision between two gel particles is presented. In
Figure 2, the dashed lines indicate the original particle surfaces without deformation, while the normal overlap is given by Equation (1).
In this equation,
—Normal overlap displacement between colliding particles (m);
—Radius of Particle 1 (m);
—Radius of Particle 2 (m);
—Position vector of Particle 1’s spherical center (m);
—Position vector of Particle 2’s spherical center (m).
Figure 2.
Schematic diagram of contact deformation during collision between two spherical particles based on Hertzian contact theory.
Figure 2.
Schematic diagram of contact deformation during collision between two spherical particles based on Hertzian contact theory.
Upon determination of the normal overlap displacement during collision contact deformation between two spherical particles, standardization of particle radii, elastic moduli, and masses was implemented due to identical overlap conditions. The effective radius (
R), effective elastic modulus (
E), and effective mass (
m*) for the particle system are expressed by Equations (2)–(4), respectively:
In this equation,
—Effective radius between particles (m);
—Effective elastic modulus (Pa);
—Effective mass (kg);
—Elastic modulus of Particle 1 (Pa);
—Poisson’s ratio of Particle 1;
—Mass of Particle 1 (kg);
—Elastic modulus of Particle 2 (Pa);
—Poisson’s ratio of Particle 2;
—Mass of Particle 2 (kg).
The normal contact force,
P (N), acting during particle collision is determined by Equation (5).
The contact radius (
a) can be derived from the normal contact force, as given by Equation (6):
The conversion relationship between a and α is derived from Equations (6) and (7) as follows:
The incremental normal contact force, Δ
P, corresponding to an overlap increment, Δα, between two contacting particles is given by Equation (8):
The work performed by the normal contact force when the relative impact velocity,
V, reaches sufficient magnitude to induce yielding in either sphere is given by Equation (9):
In this equation,
The yield pressure,
py, is determined by Equation (10) when the contact radius reaches its yield condition value,
ay:
The yield velocity is then given by Equation (11):
However, the conventional Hertzian contact theory neglects the adhesive effects between particles and considers only their mechanical collisions. Therefore, the viscoelastic contact theory is introduced to incorporate the adhesive interactions between molecules/atoms at particle contact surfaces. This theory correlates the contact area with both the elastic material properties and surface interaction strength, while introducing the concept of particle surface energy. The modified Hertzian contact theory establishes the relationship between relative contact force and approach distance, with the corresponding relationship curve shown in
Figure 3.
In this equation,
—Surface energy of particles (mJ/m2);
—Critical adhesive force (N);
—Maximum adhesive overlap (m).
Figure 3.
Force–displacement relationship for viscoelastic adhesive spheres.
Figure 3.
Force–displacement relationship for viscoelastic adhesive spheres.
According to viscoelastic theory, when two particle surfaces come into contact, the normal force between them immediately drops to a specific value due to van der Waals forces (Point A in
Figure 3). Assuming both particles undergo purely elastic deformation without reaching the yield limit, the particle velocity reduces to zero when the contact force peaks (Point B in
Figure 3). During the entire loading phase, kinetic energy is converted to other forms of energy.
In the restitution phase, while the stored elastic energy is released, the particles remain adhered even at zero normal overlap (
α = 0). The final separation occurs at Point
P, with the required detachment work,
Ws, (equal to the area under the curve) given by Equation (14):
Neglecting energy dissipation from particle collisions, the sole work required during the impact process is that needed to separate the adhesive surfaces. Consequently, the kinetic energy equation is given by Equation (15):
In this equation,
The critical sticking velocity,
Vs, emerges when particle collisions result in zero rebound velocity, establishing the threshold condition for permanent adhesion as defined by Equation (16).
Particle collisions may induce both elastic and plastic deformation, with the latter occurring at sufficiently high impact velocities.
Figure 4 illustrates the normal contact force loading path when plastic deformation occurs. During collision, the normal contact force initially increases along the primary loading stiffness curve until reaching maximum overlap. As the particles begin recovery, the contact force follows an unloading stiffness curve due to yielding, eventually reaching zero at a residual overlap defined as the plastic overlap length,
δp. In subsequent collisions, the contact force first increases along the previous unloading stiffness curve until reaching the historical maximum force, then transitions back to the primary loading curve. During unloading, when the normal overlap decreases below
δp, adhesive forces develop up to a maximum value,
fmin, before diminishing with further unloading.
The analysis reveals that plastic deformation produces non-unique unloading stiffness curves. The collision outcome can be determined by comparing the positive work (area above the force–displacement curve) to the negative work (area below the curve). Particle separation occurs when positive work exceeds negative work, while adhesion dominates in the opposite case. This energy-based criterion effectively captures the competition between plastic dissipation and adhesive bonding in particle collisions.
As evidenced by the loading path model in
Figure 4, the normal contact force curve undergoes significant modifications with variations in the loading branch exponent, n. The model reduces to a linear formulation when n = 1, as demonstrated in
Figure 5, which serves as the basis for calculating the work performed by normal contact forces.
The expression for the constant pull-off force,
, is given by Equation (17):
The expression for the initial loading stiffness,
, is given by Equation (18):
The coefficient of restitution,
, during particle collision, which also determines the outcome of the collision, is given by Equation (19):
The relationship between the initial loading stiffness,
, and the unloading stiffness,
, is given by Equation (20):
Introducing the contact plasticity ratio,
, between particles, which links the initial loading stiffness,
, and the unloading stiffness,
, is achieved by Equation (21):
is the maximum overlap.
can be obtained from Equations (2)–(7) and Equations (2)–(9) and is given by Equation (22):
The plastic overlap,
, is calculated from the contact plasticity ratio,
, and the maximum overlap,
. The plastic overlap,
, is given by Equation (23):
fmin is the maximum adhesion force, given by Equation (24):
In this equation,
is the overlap corresponding to zero contact normal force during the loading phase, given by Equation (25):
First, calculate the work performed by the contact force in the positive direction,
, given by Equation (26):
In this equation,
Next, calculate the work performed by the contact force in the reverse direction,
, given by Equation (27):
Expanding and simplifying Equation (27) yields the final expression for
, given by Equation (28):
The final comparison between the magnitudes of W1 and W2 determines the particle collision outcome.
Through the aforementioned analysis, both the yield velocity for plastic deformation and the critical adhesion velocity for elastic deformation of particles have been established. This reveals that during particle collisions, the relative impact velocity must first be analyzed to determine the deformation type: For elastic deformation, compare the velocity with the critical adhesion velocity. For plastic deformation, calculate the work performed by normal contact forces and compare the magnitudes of positive (W1) and negative (W2) work to obtain the collision result.
Analysis of the Collision Deformation Process of Colloidal particles under Two Working Conditions:
- (1)
Condition 1: Yield Velocity Greater than Adhesion Velocity
When the relative collision velocity is less than the critical adhesion velocity, the collision velocity is also necessarily less than the yield velocity. The particle collision is thus determined to undergo elastic deformation, as shown in
Figure 6a. Based on the aforementioned theory, the particles are deemed to adhere. When the relative collision velocity exceeds the critical adhesion velocity but remains below the yield velocity, the particle collision is still determined to undergo elastic deformation, as shown in
Figure 6b. Consequently, the elastic energy generated by the collision is released, causing the particles to separate. When the relative collision velocity exceeds the yield velocity, the particles undergo plastic deformation. Part of the kinetic energy is converted into elastic energy, while another part is dissipated, resulting in irreversible plastic deformation, as shown in
Figure 6c. This scenario requires separate discussion.
- (2)
Condition 2: Yield Velocity Less than Adhesion Velocity
When the relative collision velocity is less than the yield velocity, it is also necessarily less than the critical adhesion velocity. As shown in
Figure 6d, the particle collision is determined to undergo elastic deformation. Based on the aforementioned theory, the particles are deemed to adhere. When the relative collision velocity exceeds the yield velocity but remains below the critical adhesion velocity, part of the kinetic energy is converted into elastic energy, while another part is dissipated, resulting in irreversible plastic deformation. However, since the particles would still adhere under conditions where the energy is fully converted into elastic energy, the particles are determined to adhere in this case. When the relative collision velocity exceeds the adhesion velocity, the particles undergo plastic deformation. Part of the kinetic energy is converted into elastic energy, while another part is dissipated, resulting in irreversible plastic deformation. This scenario should be discussed together with the third case of Condition 1. It is necessary to calculate whether the total work performed by the contact normal force in the positive direction can exceed the total work performed when the contact normal force is in the reverse direction to determine whether adhesion occurs between the particles.