The Palmi Shear Zone (PSZ) [
4,
26] is a roughly E-W trending strike-slip high-strain zone, a few hundred meters in thickness, with a pervasive ductile deformation starting in the Paleocene (57 Ma [
42]). The PSZ is located in the southern sector of the Calabria-Peloritani Orogen (CPO), in southern Italy [
43] (
Figure 12a). Here, an alternance of highly foliated calcsilicates with subordinate mylonitic migmatitic paragneiss and mylonitic tonalites occurs. The 400 m wide mylonitic horizon extends inland for about 1500 m, forming, with a prevalent subvertical foliation, along the contact between Late-Hercynian tonalites to the south and a high grade Hercynian metamorphic complex to the north (i.e., restitic paragneisses; migmatites and amphibolites [
4]).
According to Ortolano et al. [
4,
44] and Cirrincione et al. [
43], this subvertically foliated mylonitic zone can be interpreted as a northward relic fragment of the anastomosed regional-scale strike-slip system that controlled the mutual microplate movements of the Western Mediterranean realm since the Paleocene. The strike-slip movements caused the observed lateral juxtaposition of differently evolved crystalline basement terranes, such as those identified within the arcuate orogenic segment of the CPO. In particular, the PSZ is a segment of the dextral strike-slip system, known as the Palmi Line [
43] (
Figure 12a). This structure controlled the juxtaposition of the intensely shortened Aspromonte Massif nappe-like edifice, characterised by the presence of a pervasive Alpine re-equilibration [
3,
4,
26,
43,
45] (
Figure 12a), with the Serre Massif, forming a
quasi-complete relic fragment of a Late-Palaezoic crustal section belonging to the original southern European palaeomargin [
46].
3.2.1. Mesostructural Data Analysis
In this section, we will consider a dataset consisting of linear and planar structures measured using a geological compass during a field-survey campaign (
Figure 11b). We collected structural data from four different stations (the full dataset is provided in
Table S2 within the
Supplementary Materials), approximately aligned along a W–E oriented direction, and named ‘Reef 1′, ‘Reef 2′, ‘Beach’, and ‘Malopasso’, respectively (
Figure 1 and
Figure 7).
In order to test other specific characteristics of the ASN toolbox, we decided to use just the mylonitic foliations and the stretching lineations. Axes of isoclinal or sheath folds have been voluntarily excluded from the elaboration.
The ‘Reef 1′ station is fixed at the furthest-most sea stack with respect to the coastline. The contoured plot of poles to mylonitic foliations (n = 112;
Figure 13) was made by applying a Kamb with linear smoothing method (standard deviation set at 1.5). It shows a reasonably well-defined maximum of subvertical foliations that are steeply dipping towards the SW or NE. A second minor cluster of subvertical foliations also occur dipping toward the N-S. The mean output values for foliations are 311/74 and 316/69 (strike/dip notation) calculated with the K-means and M.E.A.D. + Fisher algorithms (azimuth tolerance = 50%, inclination tolerance = 30%, Fisher confidence = 95%), respectively. At the same site, the stretching lineations (n = 10) are roughly dispersed along the mean plane of the mylonitic foliation, and display subhorizontal to moderate plunges. The Bingham best fit plane of lineations distribution is 320/66 (strike/dip notation).
At the second station named ‘Reef 2′, we collected mylonitic foliation (n = 34) as well as stretching lineations (n = 19). Contouring of poles to foliations shows four clusters on the stereoplot (
Figure 14). Two clusters are gently dipping towards the N-S, whereas the other two are NE and NW oriented, respectively. The M.E.A.D. + Fisher algorithm (azimuth tolerance = 30%, inclination tolerance = 30%, Fisher confidence = 95%) extracted four size-decreasing ordered clusters (i.e., 098/67; 275/74; 036/61; 144/72) (
Figure 14) as shown in the stored related log file available in
Table A4 within
Appendix B. The mean planes extracted by the K-means algorithm displays similar values (i.e., 090/68; 139/72; 036/60; 275/74), but are randomly sorted and without any indication of predominant clusters. The result of the first algorithm highlighted as the main former clusters display a reasonably good correlation with the previous station, even if rotated by about 35° around a vertical axis. For the stretching lineations, we preferred to apply the K-means algorithm to extract the stretching lineations mean vector (116/05 trend/plunge notation), since the occurrence of supplementary trend values, as already explained in the first case study from Macduff.
At the third station along the beach, several useful outcrops are well exposed. The 275 available mylonitic foliations depict a main northward cluster followed by a secondary southward one. The application of M.E.A.D. + Fisher algorithm set preliminary with a high number of cluster constraints, highlighted more than eight or nine clusters, with the large number of coalescing data due to the occurrence of highly strained isoclinal folds evolving into sheath folds. Setting the ‘Number of Clusters’ parameter to four, the obtained mean vectors are: 101/69, 283/70, 064/67, 257/77 (strike/dip notation, azimuth tolerance = 20%, inclination tolerance = 20%, Fisher confidence = 95%), which followed the trend of the results of previous structural stations. In this case, we also used a K-means approach for the stretching lineations (n = 56) mean vector extraction. The result is a nearly subhorizontal mean lineation (099/04—trend/plunge notation) (
Figure 15), as a consequence of the occurrence of two quite dispersed clusters around E and W directions.
The fourth structural station, located close to the Malopasso locality (
Figure 1 and
Figure 7), consists of 39 mylonitic foliations and 8 stretching lineations. In this case, all the applied mean extracting algorithms, for both main foliations and stretching lineations, converge. Therefore, we selected the M.E.A.D. + Fisher algorithm to show two confidence cones (
Figure 16). The green confidence cone surrounds the pole to mean foliation (310/69—strike/dip notation) with a Fisher angle of 5.28 degrees, while the yellow one is referred to the stretching lineation mean vector (127/10—trend/plunge notation), with Fisher angle of 9,29 degrees (see
Table A6 in
Appendix B). In both cases, we set the following algorithm-control parameters: azimuth tolerance = 50%, inclination tolerance = 30%, Fisher confidence = 95%.
In general, the orientations of all mesoscopic structures collected at the various localities are quite similar, with only slight differences. In particular, a good association between foliations collected at the first station (
Figure 13) and the fourth Malopasso station (
Figure 16) has been observed. These stations, which are the northernmost studied localities within the PSZ, have steeply dipping NE-dipping foliations (ca. 70°) with an average NW–SE strike and subhorizontal NW–SE oriented stretching lineations. The other structural stations show a mainly E-W striking foliation that dips either to the N or S (ca. 75°) and is associated with horizontal stretching lineations dispersed toward the E and W.
3.2.2. Microstructural Data Analysis
Two thin sections have been selected for quantitative microstructural analysis in order to create rose diagrams with ASN (see Ortolano et al. [
4] for details of microstructure). These rose diagrams depict the preferred orientations of minerals belonging to porphyroclastic domains, where pre-kinematic clasts behave as rigid phases during subsimple shearing plastic deformation. The samples, PAL11 and PAL12a (
Figure 12,
Figure 17a and
Figure 18a), consist of a mylonitic paragneiss from the ‘Malopasso’ station and a mylonitic skarn collected from near the ‘Beach’ station, respectively. The thin section analysis was performed by means of the Min-GSD routine within the Micro-Fabric Analyzer tool [
47] which, operating already within the ArcGIS
® platform, is suitable as an ‘ASN-friendly’ input feature. The 2D orientation data, obtained via Min-GSD through a stepwise controlled overlaying procedure of X-Ray and Grain-boundary maps of thin sections, permitted storage of microstructural information of minerals in shapefile format [
47] (
Figure 17a and
Figure 18a), and is provided in
Table S3 and
Table S4 within
Supplementary Materials. Specifically, the minimum bounding geometry approach was applied to about 800 clasts per thin section, with the azimuthal values of the preferred orientation of porphyroclasts ranging from 0 to 180 degrees with respect to the normal axis to the main foliation of the sample (
Figure 17b). These values can be computed by the ‘Rose Diagrams’ tool while the feature type input parameter can be filled with the mineral name field. Six and twelve rose diagrams have been created, respectively, for PAL11 and PAL12a samples. In both samples, we constructed standard rose diagrams (
Figure 17c,e,g, and
Figure 18b,d,f,h,j,l), which display directional data and the frequency of minerals, and also weighted rose diagrams (
Figure 17b,f,h, and
Figure 18c,e,g,i,k,m), which were useful to assign greater or smaller importance to each grain orientation as a function of a specific weighting factor (e.g., their area in mm
2). In both cases, we selected the ‘Mirrored behaviour’ option as the azimuthal values only range from 0 to 180 degrees.
For the mylonitic paragneiss (PAL11), a total of 30 amphibole porphyroclasts, 100 K-feldspars and 604 plagioclases were analysed.
The unweighted rose diagram for the amphiboles, which have equivalent spherical diameters [
48] (ESD) ranging from 0.25 mm to 0.83 mm, highlights a maximum alignment (i.e., 90°–270°) parallel to the mylonitic foliation, which is oriented in a WNW–ESE direction (
Figure 17c). In addition, a weaker alignment with an orientation that deviates by ~20 degrees from the main foliation, can also be recognized. The same results are obtained from the weighted rose diagram (
Figure 17d), which does however assign less statistical impact to grains showing an orientation that deviates from the main foliation, due to their small cumulative area.
The unweighted rose diagram for the K-feldspars (0.25 mm < ESD < 3.67 mm) highlights a maximum alignment (i.e., 80°–260°) that deviates by ~10 degrees from the main foliation (
Figure 17e), although several families with orientations that vary about the 120°–300° and 40°–220° directions also occur. However, the existence of these families is minimized by the weighted rose diagram (
Figure 17f), which shows a clear orientation at 80°–260°, preserved especially by the largest porphyroclasts, where the simple shear component is more pronounced (see Ortolano et al. [
4] for details).
Similar to the amphiboles, the unweighted rose diagram for the plagioclases (0.25 mm < ESD < 2.45 mm) highlights a prevalent orientation (i.e., 90°–270°) along the mylonitic foliation (
Figure 17g). However, several families show a dispersal in orientation towards N-S and E-W directions with respect to the main foliation, probably linked to the activation of S-C’ planes. This dispersion is highlighted by the weighted rose diagram (
Figure 17h), in which the most weighted porphyroclasts show a clear trend along the N-S direction (i.e., 120°–300°).
The mylonitic skarn (PAL12a) allowed us to process a total of 144 calcite clasts, 102 calc-silicate minerals, 231 clinopyroxenes, 149 K-feldspars, 63 plagioclases and 186 scapolite porphyroclasts, with the calculated orientations illustrated in
Figure 18.
The unweighted rose diagram for the calcite porphyroclasts (0.18 mm < ESD < 0.50 mm) highlights high dispersion in the orientation data with respect to the mylonitic foliation oriented on average E-W (
Figure 18b). Most weighted grains do however show a dominant orientation about E-W (i.e., 80°–260°) as also obtained with the weighted rose diagram (
Figure 18c).
The unweighted rose diagram for the calc-silicates (0.18 mm < ESD < 0.79 mm) highlights a lesser dispersion in the orientation data when compared with calcite porphyroclasts, with a high number of grains aligned parallel to the mylonitic foliation (
Figure 18d). Nevertheless, by considering the cumulative area of porphyroclasts with the same orientation, as highlighted by the weighted rose diagram (
Figure 18e), other families oriented about NE–SW (i.e., 30°–210°) and WNW-ESE (i.e., 110°–290°) orientations can also be recognized.
Similar to the previous mineral phases, the unweighted rose diagram for the clinopyroxenes (0.18 mm < ESD < 1.21 mm) highlights high dispersion in the orientation data with respect to the mylonitic foliation (
Figure 18f). Such dispersion is also shown by the weighted rose diagram (
Figure 18g), with a dominant ESE–WNW orientation (i.e., 120°–300°) observed.
The unweighted rose diagram for the K-feldspars (0.18 mm < ESD < 1.35 mm) highlights a maximum alignment (i.e., 90°–270°) parallel to the main foliations (
Figure 18e). Such alignment is also preserved in the weighted rose diagram (
Figure 18i), where fewer families show a ~N-S orientation (i.e., 20°–200°).
Similar to the calcite porphyroclasts, the unweighted rose diagram for the plagioclases (0.18 mm < ESD < 1.03 mm) highlights high dispersion in the orientation data (
Figure 18j), with a dominant trend about the E-W (i.e., 80°–260°) and N-S (i.e., 20°–200°) directions. This dispersion is made even more evident by the weighted rose diagram (
Figure 18k).
The unweighted rose diagram for the scapolites (0.18 mm < ESD < 7.26 mm) highlights two dominant alignments oriented about the E–W (i.e., 90°–270°) and ENE–WSW (i.e., 50°–230°) directions (
Figure 18l), which are further emphasized in the weighted rose diagram (
Figure 18m).
Unlike the mylonite paragneiss (PAL11), a greater dispersion in the orientation of the porphyroclasts is observed in the mylonitic skarn (PAL12a) due to the higher contrast in behaviour between weakening (i.e., calcite) and hardening (i.e., porphyroclasts) layers. This leads to a major passive rotation of the PAL12a porphyroclasts during the mylonitic flow due to the high rheology contrast with respect to the calcite weak layers. Differently, PAL11 porphyroclasts, which are surrounded by quartz-rich weak layers (i.e., with a lower rheology contrast with respect to PAL12a), facilitate wing formation, producing greater resistance to the mylonitic flow and, in turn, a clearer evidence of subsimple shear kinematic indicator formation.