1. Introduction
The Standard Model (SM) of particle physics describes many experimental observations with impressive accuracy and successfully withstands many experimental tests. However, there are yet unsolved puzzles that require an extended theory beyond the SM. Among others, three main issues to be addressed are dark energy, the nature of dark matter and the observed baryon asymmetry in our Universe. The latter is apparent from observations of the cosmic microwave background (CMB) [
1] and big bang nucleosynthesis (BBN) [
2], from which the ratio of the difference in matter and anti-matter number density to the number density of photons
in our Universe can be determined to be
with
and
being the number densities of barionic matter and anti-matter, respectively. In contrast, the SM expectation for this ratio is about eight orders of magnitude smaller. According to Sakharov [
3], there are three conditions to be fulfilled for the Universe to evolve into a state of baryon asymmetry: (i) departure from thermal equilibrium; (ii) baryon number violation and (iii)
C and
violation. These conditions can in principal be accounted for within the SM, i.e., through so-called “sphaleron“ processes and electroweak symmetry breaking [
4]. The last condition (iii) involves breaking of fundamental symmetries by charge-conjugation (
C) and the subsequent operation of parity- and charge-conjugation (
). The SM provides
violation via a complex phase in the CKM matrix and through the
term in strong interactions, but the known mechanisms can not account for the observed baryon asymmetry. Hence, a more complete theory requires additional
violation and experimental programs searching for its signatures are of great interest to identify the underlying physics.
Searches for electric dipole moments (EDMs) of fundamental particles, molecules and atoms offer a sensitive, direct probe of these underlying new physics. A non-zero EDM violates both parity (
P) and time-reversal (
T) symmetries (
Figure 1). Hence, assuming
to be a good symmetry, a non-zero EDM is also a manifestation of
violation and obtained experimental limits can put strong constraints on theories beyond the SM that usually require more
violation.
2. EDM Experiments Overview
In the SM, EDMs arise from two mechanisms. In QCD, the
term (
) is the leading
-odd contribution in the Lagrangian [
6]. However, experimental results of the neutron EDM [
7] put strong constraints on
via
, leading to an unnaturally small
[
6]. A possible solution to this “Strong CP-problem” was initially proposed by introducing a new particle, the axion [
8], resulting in a now very active field of axion searches. Generation of
violation in the weak interaction through the CKM matrix is only a higher order effect, e.g., with the largest contribution to an EDM of the neutron being
[
9]. Predictions of EDMs in the SM are small (c.f.
Table 1) compared to theories beyond the SM, which generally introduce more
violation and require larger EDMs. Hence, upper limits from EDM searches can help constrain the model parameters of beyond SM theories.
A summary of the most recent published upper limits for EDMs of various systems of interest and their SM predictions are shown in
Table 1. As EDMs in fundamental particles and atoms arise from different sources of underlying
-odd physics, a combination of experimental results in a global analysis is beneficiary over a sole-source analysis. The diagram in
Figure 1 shows an overview of major (solid lines) and minor (dashed lines)
violating contributions to EDMs of fundamental particles and atoms on various energy scales. The EDM of the neutron has contributions from quark EDMs and chromo EDMs as well as
-odd interactions of quarks and gluons. However, atomic EDMs arise from intrinsic EDMs of unpaired electrons or nucleons and
-odd interactions of both nucleons and electrons. For diamagnetic atoms, like
Xe, an EDM of the nucleus is screened by the closed electron shell. However, imperfect screening of the nuclear EDM due to finite size effects leads to an observable atomic moment, the so-called Schiff moment [
5].
In a global analysis, the results of different systems can be combined to improve upper bounds on individual
-odd contributions [
18]. As an example, an improved limit on the EDM of
Xe by one to two orders of magnitude can significantly improve constraints on particular electron–nucleon (
) and nucleon–nucleon (
) interactions, although the result would still be far from the superior upper limit on the EDM of
Hg. The prospect of these improvements and possible use as an additional comagnetometer in future neutron EDM experiments [
19] encourages experimental efforts with better sensitivity on the EDM of
Xe. Heavy elements with deformed nuclei like
Ra are promising candidates due to strong nuclear enhancement effects [
12]. First results have recently been published with expected significant improvements in the near future.
The general technique to search for an EDM
d is to place a spin polarized species (e.g., spin 1/2) in an applied magnetic and electric field and determine the difference in Larmor precession frequencies
for magnetic and electric fields aligned in parallel and anti-parallel:
assuming the magnetic field is equal for both measurements and
. The rather simple method comes with technical challenges, e.g., correction of magnetic field drifts, in particular when they are correlated with electric field reversal. It is interesting to note that an EDM sensitivity of
typically (assuming
) corresponds to a frequency sensitivity of
and—for nuclear magnetic moments—to a magnetic field variation of only
. An overview of the history of experimental progress in EDM results for neutrons, atoms and the electron is shown in
Figure 2. In the remainder, the focus will be on experiments searching for an EDM of the neutron, particularly the neutron EDM project at TRIUMF and recent efforts of the HeXeEDM collaboration to improve sensitivity for the EDM of the diamagnetic atom
Xe.
3. Neutron EDM Experimental Status
The neutron is a simple system in terms of the fundamental contributions to it’s EDM (c.f.
Figure 1). First measurements in the 1950s were based on neutron beams superseded in the 1980s by storage experiments using ultra cold neutrons (UCN) (see
Figure 2).
Most next generation neutron EDM searches are using UCN with energies below a few hundreds of neV. UCN can be stored for long periods of several hundreds of seconds using wall materials with a high Fermi potential. Suitable choices are e.g., copper (∼), stainless steel (∼), Ni (∼). Relevant for EDM experiments are also non-metallic insulator materials, e.g., SiO (∼) or AlO (∼).
The last improvement of sensitivity on the EDM of the neutron with the result of
(90% C.L.) by the ILL/RAL/Sussex collaboration [
7] was enabled by introducing a mercury (
Hg) comagnetometer. The apparatus used is described in detail in [
20]. Polarized UCN were filled into a storage cell located inside a four-layer magnetic shield. Ramsey’s method of separated oscillatory fields was employed to determine the phase accumulated by the neutrons during a free precession period of applied magnetic and electric fields. UCNs are counted after measurements at four different working points using off-resonant spin-flip frequencies. Their precession frequency is determined by fitting the data to the Ramsey fringe curve.
The statistical sensitivity to an EDM
is determined by
where
is the visibility (depending on initial spin polarization, spin lifetime and analyzer efficiency),
E the electric field strength,
T the free spin precession time and
N the number of neutrons. Next generation experiments mainly rely on a significant improvement on
N limited mainly by the yield of current UCN sources, but also by efficient UCN transport. Another major focus to achieve better EDM sensitivity is improvement on leading systematic effects, which are currently dominated by magnetic field quality.
A challenging new approach to overcome limitations by measuring the neutron EDM in situ, i.e., inside the UCN production volume filled with superfluid helium, is being pursued at the ORNL spallation neutron source. In addition, new efforts reviving neutron EDM searches using crystal diffraction [
21] and a neutron beam [
22] are proposed. Most next generation neutron EDM experiments (ILL, PSI, FRM-II and TRIUMF) are based on previously employed concepts of a room-temperature UCN storage cell with internal comagnetometery surrounded by various magnetometers. However, experiments are using different types of UCN sources, the “UCN turbine” (PNPI-ILL), solid deuterium UCN sources (PSI, FRM-II, LANL) and superfluid helium UCN sources (ILL PanEDM, TRIUMF, ORNL).
4. Neutron EDM Project and UCN Facility at TRIUMF
The planned neutron EDM experiment at TRIUMF is based on a room-temperature storage cell located inside a large multi-layer magnetic shield and filled with UCNs produced in a superfluid helium source. The electric field of up to 13 kV/cm is applied to an electrode centered in a stack of two storage cells with ground electrodes on their outer faces. The double cell combined with simultanous neutron spin detection allows for measurements of neutron spin precession frequencies for both alignments of magnetic and electric field in a single fill cycle. For an improved understanding of systematic effects related to magnetic field quality, both an array of spin-exchange relaxation free (SERF) magnetometers [
23] and a second comagnetometer species are anticipated to be implemented in the experiment. The additional comagnetometer species
Xe, with a magnetic moment of same sign as the neutron magnetic moment, provides a second measurement of the magnetic field, complementing the
Hg comagnetometer. The dual species comagnetometer enables the determination of vertical magnetic field as well as the vertical magnetic field gradient to correct for a false neutron EDM signal arising from the geometric phase effect [
19,
24].
To meet the statistics requirements for an anticipated sensitivity of , the TUCAN (TRIUMF Ultra Cold Advanced Neutron source) collaboration is developing a strong, world-leading UCN source to generate a UCN density of several hundreds of UCN per cm in the EDM storage cells. A secondary goal is to establish a leading UCN user facility at TRIUMF. The first milestone towards the new UCN facility has been reached in 2016 with commissioning of the UCN beamline.
4.1. UCN Beamline
The UCN beamline at TRIUMF is designed to allow sharing of proton beams between other users and UCN. A kicker magnet operated by a power supply ramping to full current of 180 A within
enables diverting 520 MeV proton bunches from TRIUMF beamline 1A onto the UCN spallation target. An average current of up to
can be taken from the maximum current of
in beamline 1A allowing simultaneous operation with other users at TRIUMF. Details on the beamline can be found in a recently submitted publication [
25].
4.2. UCN Source and First Production Results
In early 2017, a prototype UCN source developed and formerly operated at RCNP [
26] was installed at TRIUMF. The thermal neutrons created in the UCN spallation target are slowed down in two moderator stages of D
O at room temperature and ice D
O at 20 K before being converted to UCN in a He-II volume. Slow neutrons (
) can be efficiently scattered in liquid helium and lose almost all of their kinetic energy to phonon excitations [
27,
28]. A critical parameter for the UCN production yield is the temperature of the He-II, as unfavorable upscattering processes scale with temperature as ∼
, but can be strongly suppressed by cooling the He-II to temperatures of ∼
and below.
The protoype UCN source uses of He-II as UCN production volume reaching a minimum temperature of when idling at static heat load of ≈. Due to the additional heat load during target irradiation, the He-II temperature during production increases and the maximum UCN source lifetime measured at RCNP was , significantly below the expected ∼ at 0.85 K. He-II inside the UCN production volume is cooled via a He-II filled channel to a heat-exchanger thermally connected to a liquid He bath. The He bath is cooled to by lowering the vapour pressure to < via pumping. Pre-cooling of the circulated He gas is accomplished through two cooling stages using natural helium at 4 K and at 1.6 K, the latter cooled by lowering the vapor vapour pressure through pumping.
Using the prototype UCN source, the first UCNs at TRIUMF were successfully produced in November 2017. In the initial measurements, we obtained yields of 40,000 and 300,000 detected UCNs at a proton beam current of
and
, respectively, when irradiating the spallation target for 60 s. The linear scaling of UCN yield with proton current was demonstrated at shorter irradiation times of 30 s, which was necessary to reduce effects from beam heating. More details and further results can be found in a recently submitted paper [
29].
With successful demonstration of UCN production using the prototype source, the facility is now available for tests of components for the new UCN source and equipment for the neutron EDM experiment.
4.3. Design of a New UCN Source at TRIUMF
The new UCN source under development for the TRIUMF UCN user facility and the neutron EDM experiment will use an improved, more efficient cooling concept also based on a heat-exchanger connected to a He bath. Additionally, improvements are anticipated from using a combination of heavy water and liquid deuterium (LD) as moderators.
The design was highly optimized by simulations in terms of geometry and volume of LD and He-II with a maximum allowable heat load on the He-II of 10 W at 1.15 K. In the resulting layout with a long horizontal He-II section of volume (of which 34 L are the UCN production volume), the main considerations for cryogenics are thermal conductivity through He-II and the heat-exchanger. Both are limiting the heat transfer from the UCN production volume close to the spallation target to the He bath side of the heat-exchanger. Transfer through He-II is accounted for by appropriate sizing of the He-II volume in terms of diameter and length, while thermal conductivity of the heat-exchanger is mainly limited by the Kapitza resistance of the nickel-plated copper to He-II boundary surface. Test measurements of the Kapitza conductance done at KEK showed very promising results eliminating a major cryogenic design risk.
Figure 3 shows a draft design of the new UCN source layout and geometry. The temperature goal of the UCN production volume of 1.15 K allows for sufficiently long storage lifetimes in He-II while locating the source cryostat far away in an area with reduced radiation levels. The
UCN production volume of superfluid, isotopically purified
He are kept at an operating temperature of 1.15 K during a period of 60 s of target irradiation with a proton beam power of 20 kW (
of
protons). The full proton beam power produces a heat load on the order of 10 W to the He-II inside the UCN production volume close to the target. The cooling power required to keep the
He side of the heat-exchanger at ∼
is provided by a pumping system capable of sustaining a
He throughput of 1.12 g/s (or
). The peak design mass flow is based on assuming a full transfer of the 10 W heat load through the heat-exchanger to the
He bath.
From simulations and the optimization process, the new UCN source is expected to produce about . This improvement of two orders of magnitude compared to the prototype UCN source is driven mainly by enabling operation at full proton beam current of , a four-fold increased He-II production volume close to the spallation target and an improved moderator concept using LD rather than ice DO.
The new UCN source at TRIUMF is scheduled to be installed during the main shutdown in early 2021 with first UCN production expected by the end of 2021. Successful commissioning of the new UCN source facilitates the neutron EDM experiment at TRIUMF anticipated to start taking data in 2022 with the goal of achieving a sensitivity to an EDM of the neutron on the order of within less than 500 measurement days.
5. Xenon EDM Experimental Status
Results from searches for atomic EDMs as more complex systems than the neutron make additional manifestations of new physics accessible due to the electron EDM or
-odd interactions between nuclei and between nuclei and electrons. While paramagnetic atoms or molecules are particularly sensitive to an electron EDM with only higher order contributions involving nuclei, diamagnetic atoms such as
Hg,
Xe or
Ra exhibit many
-odd processes contributing to an EDM (c.f.
Figure 1).
The current limit on an EDM of
Xe was published in 2001 [
11], with the result of
(95% C.L.). The experiment was based on a spin maser driving nuclear spin polarizations of the two noble gas species
He and
Xe, where
He was used as a comagnetometer. With continuously supplying polarized gas diffusing from a pump cell attached to the EDM cell with high voltage electrodes, the maser technique can achieve almost continuous long-term observation. The main limitation in the experiment was the stability of the feedback electronics.
There are currently three ongoing efforts towards a new limit of the EDM of
Xe; an improved version of the spin maser using an optical readout of the nuclear spin precession [
30] and two similar approaches followed by the MIXed [
31] and HeXeEDM collaborations [
32] using a sample of freely precessing
He and
Xe nuclear spins detected by SQUID sensors.
6. Progress towards a New Measurement of the EDM of Xe: HeXeEDM
The HeXeEDM collaboration is seeking to improve the upper limit on an EDM of the diamagentic isotope
Xe by one to two orders of magnitude compared to the current limit of
[
11]. The HeXeEDM experiment also uses a
He comagnetometer, but with freely precessing nuclear spins of
He and
Xe in a highly shielded magnetically stable environment rather than a driven oscillation as in the nuclear spin maser. Very long observation times in excess of several hours are accessible inside a large magnetically shielded room (MSR) with particularly low residual magnetic field gradients. Because of the high magnetic field quality, long spin relaxation time constants are possible even at high pressure of the noble gas species inside the EDM cell, as no motional narrowing is required to average field inhomogeneities. In turn, the high total gas pressure of 0.5 to 1.0 bar allows high electric field strengths without the need of buffer gases. New EDM cells have been developed using glass cylinders (Pyrex) with heat bonded silicon electrodes and a glass valve attached to one electrode with a center hole. Nuclear spin precession of the two noble gas species is detected by highly sensitive SQUID sensors with magnetic field noise below
, allowing for large signal-to-noise ratios.
A high nuclear spin polarization—orders of magnitude above the thermal polarization—is generated in a spin-exchange optical pumping (SEOP) setup where both noble gas species are simultaneously polarized via spin-exchange collisions with optically pumped rubidium vapour [
33]. The optical pumping cell is placed inside an oven to increase the vapour density of rubidium, particularly for efficient spin exchange to
He. Typically,
He is first polarized for several hours at temperatures of >
, before the temperature is lowered for several minutes to efficiently polarize
Xe at ∼
. The gas mixture of polarized
He and
Xe as well as nitrogen quenching gas—typically in ratios of
:
:
= 75:15:10—is filled into an evacuated EDM cell in the fringe field of the polarizer magnetic holding field (∼
). The EDM cell is then transported into a MSR avoiding zero magnetic field crossings and placed underneath a liquid helium dewar with six SQUID sensors. A grounding silicon wafer protects the sensitive SQUIDs from damage due to possible discharges (c.f.
Figure 4). After applying a transverse
spin flip pulse combined for both species, the nuclear spin precession in the magnetic holding field (1–2
T) is recorded, while a sequence of zero,
and
electric field (
) is applied.
Initial test measurements and developments were done in the MSR at FRM-II [
34], with further details on the experimental setup available in [
32]. A main systematic effect, i.e., drift of the comagnetometer corrected frequencies, was investigated with important implications on the comagnetometer approach and understanding of the observed drifts [
35]. The MSR at FRM-II moved to ILL (Grenoble) in 2017 to be used as a magnetic shield for a neutron EDM measurement. The HeXeEDM experiment relocated to PTB Berlin, where several weeks of tests and EDM measurement runs were taken out in 2017 and 2018 inside the BMSR-2 [
36]. In both runs, many systematic effects were investigated and several parameters varied during EDM measurements, i.e., high-voltage ramp speed, high-voltage dwell times, high-voltage starting polarity, EDM cells, magnetic holding field direction and total gas pressure.
Data of 120 individual EDM measurements were recorded within one week in 2017 and are currently in the final stage of data analysis. Sources and sizes of systematic effects are being evaluated and the final result is expected to be comparable to the most recent published limit [
11].
The EDM run in 2018 is not yet included in the analysis, but typically had a ten-fold larger He comagnetometer signal due to better polarizations achieved in the SEOP setup.
For the next EDM run, a liquid helium dewar with lower intrinsic noise and a better understanding will be used and hence reduction of major systematic effects is anticipated. An improvement in sensitivity by at least one order of magnitude is expected.
7. Conclusions
Searches for permanent EDMs of fundamental particles and atoms provide a direct probe of time-reversal violation and physics beyond the SM. Results from EDM experiments have put strong constraints on many new physics models, which typically require larger EDMs. In a global analysis, the combination of many EDM results using different systems can improve limits on violating sources compared to a sole-source analysis. Hence, even with the superior sensitivity of the Hg EDM measurement, further effort is necessary on other systems for a more detailed understanding of the underlying physics.
Of the many neutron EDM experiments around the world, the first are expected to start taking data within the next years with the goal to improve the sensitivity by at least an order of magnitude. Progress is to be expected soon on the EDM sensitivity of diamagnetic atoms, e.g., Xe and from new experiments using heavy isotopes, like Ra. New measurements will provide a better insight into violating fundamental processes and the implications for physics beyond the SM.