1. Introduction
Biomass has been the main source of energy for heating and cooking since ancient times, due to its diversity, worldwide availability and usability [
1,
2]. Over the last few decades, interest in biomass as an alternative energy source to fossil fuels has grown significantly. From a sustainability point of view, the combustion of solid biomass to convert into heat and power has attracted great interest, since it allows industries to obtain energy from wastes in an energy-efficient way [
2].
However, the combustion of solid biomass has some associated problems that in some cases can hinder the transition to this energy source. For example, although the combustion of biomass can be considered neutral regarding carbon dioxide emissions, other pollutants harmful to human health, such as particulate matter (PM) or NOx, are present [
3,
4].
In addition, the presence of alkali metals and other inorganic compounds in the biomass composition can cause ash-related problems and corrosion in biomass combustion systems. Higher content of alkalis, such as sodium and potassium, reduces the melting point of the ash. The condensation of these inorganic vapors on the heat exchange surfaces is the starting point for the generation of a fouling layer. The reduction of the ash fusion temperature also encourages the formation of slag on the surfaces in contact with the fuel bed. The fouling and slagging cause a decrease in thermal efficiency of the combustion systems, and may cause system damage [
5,
6,
7,
8,
9].
To reduce these problems, several techniques can be utilized. Differentiation can be made between primary measures, if they directly affect the combustion process while trying to avoid these phenomena, and secondary measures, such as the treatment and filtering of exhaust gases or the removal of fouling and slagging.
The most popular primary measures are focused on controlling the air injection and the temperature of the solid fuel bed. Different studies have shown how air staging reduces PM and gaseous emissions [
10,
11,
12]. Low primary air ratios lead to a reduction in PM emissions, as the lower air velocity in the bed results in less elutriation [
10,
12]. In addition, staged combustion with secondary, and even tertiary, air injections help to achieve an efficient flue gas burnout and can reduce NOx emissions [
11,
12]. Using low air excess ratios for the primary air also helps to reduce the temperatures of the solid fuel bed, lowering the risk of fouling and slagging due to ash melting [
12]. Flue gas recirculation and bed cooling techniques can also be used to reduce the temperatures of the bed. Flue gas recirculation (FGR) consists of replacing a portion of the primary air with flue gas that has previously been cooled, to reduce the oxygen concentration and, thus, reducing the temperature of the fuel bed and slowing its thermal conversion process. Studies have shown how FGR helps to reduce the unburnt species, PM and NOx emissions, and the slagging in the bed [
12,
13,
14,
15]. Bed cooling solutions consist of the refrigeration of the solid fuel bed. In medium- and large-scale systems, water-cooled grates are used to refrigerate the bed. There are studies on the implementation of cooling systems formed by a water pipe surrounding the fuel bed in domestic biomass boilers, showing a reduction of PM emissions without affecting other combustion parameters [
16,
17].
In this context, Pérez-Orozco et al. presented an experimental small-scale biomass combustion system designed to test the influence of air staging, FGR and bed cooling on biomass combustion emissions [
18]. The most novel part of this plant is the complete refrigeration system that also includes the fuel bed. To allow the characterization of the temperature distribution inside the combustion system and the pollutant emissions, the plant is equipped with thermocouples located in different zones, as well as a gas analyzer and a low-pressure impactor connected to the exhaust. Several experimental studies have already been carried out, testing the stability and repeatability of the facility, and analyzing the effectiveness of using different air ratios, FGR and bed cooling for reducing pollutant emissions [
13,
14,
18,
19].
Computational Fluid Dynamics (CFD) software is a useful tool for studying biomass combustion and analyzing combustion systems. Numerical tools allow the addressing of aspects that are not easy to characterize experimentally and reducing the costs of the design and optimization of biomass combustion systems.
CFD codes can solve fluid flow and heat transfer processes, as well as homogeneous chemical reactions occurring in the gas phase. However, to simulate the solid biomass thermal conversion process, it is necessary to use sub-models. One-dimensional sub-models, based on empirical correlations or on biomass thermal conversion models, can be easily coupled with the CFD being a simple option with a low computational cost [
20,
21,
22]. Numerical studies using coupled empirical one-dimensional bed models have shown that enhanced air staging allows a significant reduction of particulate matter and nitrogen oxide emissions [
21,
22]. However, these models cannot predict the state of the solid fuel bed. In order to track each fuel particle individually and characterize its thermal conversion process, it is necessary to employ Lagrangian models, such as the discrete element method (DEM) or the discrete phase model (DPM), coupled with biomass thermal conversion models [
23,
24]. These models allow a more realistic characterization of the solid fuel bed but have a high computational cost.
Eulerian models have a lower computational cost than Lagrangian models, being a more comprehensive approach than one-dimensional models [
23]. These models usually consider two zones, the bed, defined as a porous zone where the solid and gas phases coexist, and the freeboard, set as a simple fluid, allowing dynamic coupling between both phases [
25,
26,
27,
28,
29]. Eulerian models have been successfully used to simulate systems under different air/oxy-fuel conditions [
28] and on different scales, from small experimental plants [
27], to medium- [
25] and large-scale systems [
26,
29]. Although these models do not treat the fuel bed as individual particles, physics algorithms can be implemented to simulate the movements and compaction of the solid fuel inside the systems [
30,
31]. In this work, the Eulerian biomass thermal conversion model (EBiTCoM), developed by the Energy Technology Group (GTE) of the University of Vigo, will be used.
The EBiTCoM is fully integrated into the CFD commercial code ANSYS-Fluent as a user-defined function (UDF) programmed in C/C++ [
32]. The model allows the simulation of fixed-bed biomass thermal conversion systems. The model has been used to simulate various systems, from small lab-scale devices to industrial-scale systems, such as gasifiers and boilers [
26,
30,
33,
34,
35,
36,
37].
This work extends and complements the work of Pérez-Orozco et al. by presenting a CFD study on the influence of bed cooling and air staging on biomass combustion. The experimental small-scale biomass combustion system presented by Pérez -Orozco et al. will be simulated, validating the numerical modeling against the experimental data, allowing us to study the influence of bed cooling on the combustion [
19]. For this purpose, several CFD cases for different primary airflows and staging ratios, and with the bed cooling system enabled or disabled, will be studied. To validate the results, the temperature profiles inside the solid fuel bed and along the combustion unit measured in the experimental tests will be compared with the simulation results. The CFD results will be used to analyze the effect of air staging and bed cooling on different parameters, such as the fuel conversion ratio, bed morphology, temperatures, gaseous emissions, etc.
2. Model
In this work, the commercial CFD code ANSYS-Fluent 2020 R1 will be used. This software can solve the characterization of fluid phases, including the heat transfer phenomena and the homogeneous gas reactions. The EBiTCoM, which is embedded in the CFD code as a UDF, will characterize the solid fuel bed and its thermal conversion, allowing the dynamic coupling between the bed and the gas phase.
The main features, assumptions and approaches of the model are presented below. A more detailed description of the EBiTCoM characteristics and procedures can be found in previously published works [
26,
30,
35,
36].
2.1. Solid Phase
The bed is modeled as a porous zone where the solid fuel and the gas phase coexist. In this zone, user-defined scalars (UDS) are used to characterize the solid fuel properties in each cell. The scalars, which represent local volume-averaged values for each cell, are: solid fraction (m3solid/m3cell), solid temperature (K), moisture density (kg/m3solid), dry wood density (kg/m3solid), char density (kg/m3solid), ash density (kg/m3solid) and third power of the particle average diameter (m3).
The solid fraction scalar defines the ratio of cell volume that is occupied by solid fuel. The maximum value of this variable is limited to the maximum packing factor of the fuel. The densities define the composition of that solid volume. Although this approach does not consider each individual fuel particle, the particle average diameter characterizes the size of the theoretical particle (or particles) that is represented by the solid volume of each cell (Eulerian approach). The temperature of the solid volume in each cell is considered homogeneous, since the EBiTCoM is based on a thermally thin assumption and is controlled by the solid temperature scalar.
The transient evolution of each UDS is controlled by a transport equation (
Table 1). The terms on the right-hand side represent the consumption and generation of each variable. The shrinkage of the solid, which is reflected in the solid fraction and the particle diameter, only occurs during wood devolatilization and char generation [
36]. In the transport equation of the solid temperature scalar (Equation (1) there is a diffusive term, which represents the equivalent thermal conductivity between the solids. The diffusive term is not present in the other equations because there is no mass diffusion between the solids. The ash is non-reactive, but it can be compacted when the solid fuel bed collapses, due to the shrinkage of the particles [
30].
Apart from the shrinkage and compaction, the model also includes physics algorithms to simulate the effect of gravity on the solid fuel bed, which, being a granular material, will have a tendency to form piles [
31,
38]. In addition, the model has different fuel feeding methods, to simulate the feeding mechanisms of different combustion systems. In this case, a feeding method that uses the ANSYS-Fluent discrete phase model (DPM) will be used. This method tracks the trajectories of the fuel particles falling from the fuel inlet to the bed zone, and deploys the corresponding fresh fuel mass in the final particle position [
36].
In
Table 2, the equations defining the consumption rates of the solid fuel components are shown. The moisture of the solid fuel starts to evaporate when the temperature of the solid is equal to or higher than 373.15 K (Equation (8)). The particles dry from the outside inward. This means that when the outer layers of the particles are dry, there is still moisture on the inside. Because of this, the average temperature of the particle keeps rising before it is totally dried. To model this effect, half of the heat received by the solid is employed in the drying process, and the other half is in the heating of the solid fuel. The pyrolysis is modeled as three conversion processes, converting the dry wood into gas tar and char. The wood consumption ratio is the sum of the three Arrhenius equations that control these processes (Equation (9)). The char generated in the pyrolysis is consumed by direct oxidation and two gasification reactions, which are also controlled by Arrhenius equations. The char consumption ratio is the sum of the three reaction ratios, taking into account the diffusion of oxygen, carbon dioxide and water vapor for each respective reaction (Equation (10)).
The kinetics of the solid heterogeneous reactions are collected in
Table 3 [
39,
40,
41]. The ratio for CO/CO
2 produced by the char oxidation (φ) is calculated by a temperature-dependent correlation [
40,
42].
The solid fuel exchanges energy with the gas phase by convection and radiation. The convective heat transfer coefficient is calculated by an experimental correlation to obtain the Nusselt number for particle-to-fluid heat transfer in packed beds [
43]. In the same way, the mass transfer coefficients are calculated with an experimental correlation to obtain the Sherwood number [
44]. The radiation heat exchange is calculated by a modified version of the discrete ordinates model to take into account the influence of the solid phase on the absorption and scattering coefficients of the cell and adding an emissivity term for the solid [
30,
45]. These heat exchanges between phases are computed using energy sources that absorb from or give energy to one of the phases and do the opposite in the other phase. Energy sources are also used to model the heat exchanges produced during the drying, devolatilization and char reactions.
2.2. Gas Phase
CFD codes have been extensively used to simulate biomass combustion in many types of systems. This software can solve the conservation equations applied to the gas phase with its built-in algorithms. In this case, the continuity, momentum, energy, turbulence, chemical species, and soot conservation equations are calculated.
The turbulence model used is the realizable k-ε model, which is commonly used in biomass combustion system simulations [
23,
25,
26]. The radiation model chosen is the discrete ordinates model, which has been modified to take into account the contribution of the solid phase [
45]. The finite rate–eddy dissipation (FR-ED) model, which is suitable for most biomass combustion cases since the turbulent mixing is the rate-limiting step in the consumption of the gaseous species, is used to compute the interaction of turbulence and kinetics [
46]. The Moss-Brookes model is used for soot nucleation and reaction. The effect of the porous bed on the gas flow is modeled using a dispersed porous media approach with physical velocity condition and a momentum source [
30].
During the thermal processes that affect the solid fuel, a series of gaseous emissions are released. The drying produces water vapor, and the heterogeneous char reactions produce CO, CO
2 and H
2, consuming O
2, CO
2 and H
2O(v), respectively. To model the devolatilization, a simplified list of species is used. This includes CH
4, C
6H
6, CO, CO
2, H
2 and H
2O(v). The methane and benzene represent the light hydrocarbons and tars, respectively. The composition of the emissions is estimated by a method based on an elemental and energy balance equation system that is closed with two experimental expressions [
47]. In this case, experimental CO and CH
4 yields in the function of the temperature of pyrolysis are taken as the closure equations [
48]. All the species generated and consumed in the solid fuel thermal processes are exchanged with the gas phase, using mass sources.
To model the gas-phase reaction scheme, a set of chemical reactions that includes the species considered is established. These reactions (
Table 4) include the partial oxidation of benzene and methane, the oxidation of hydrogen and carbon monoxide, and the water–gas shift two-way reaction [
49,
50].
4. Results
A transient simulation is calculated for each case. Different variables are monitored to check if the combustion plant has reached its pseudo-steady state, as solid biomass combustion usually presents an oscillatory behavior. In addition, the pseudo-random fuel feeding method used in this work causes disturbances. Because of this, the monitored variables do not tend to stabilize to a constant value but instead describe periodic oscillations around it. When these oscillations are stable inside a constant range, it is considered that a pseudo-steady state has been reached. At this moment, the temperatures at the thermocouples are registered for 500 s of flowtime to obtain averaged values.
The simulation results are compared against the experimental measures presented by Pérez-Orozco et al. [
19]. The temperature profiles represent the temperature variation along the central z-axis from the grate to the chimney of the combustion plant.
Figure 4 shows the comparisons of the experimental and numerical raw tests. It can be seen that the maximum temperatures, which are registered at the thermocouples located closest to the grate, are directly proportional to the primary airflows, increasing as the primary airflow rate increases. The maximum temperature is accurately predicted, with an average error of 6%. This deviation comes from a slight overestimation of the maximum temperature, which is higher in the cases with higher primary airflow. The middle and top row bed thermocouples’ experimental measurements show a temperature decrease that is not fully reflected in the CFD simulations. On average, the calculated bed temperatures are 21% higher than the measurements. This may be caused by the boundary conditions that are applied to the CFD case in the bed zone when the cooling bed circuit is off, which resulted in a more adiabatic situation than in the experimental tests. Another possible cause of this temperature overestimation in the bed zone might be the assumption that it is thermally thin. The consideration that the temperature of the solid in each cell is homogeneous throughout its volume causes faster heating rates [
26]. This leads to faster drying and pyrolysis rates, reducing the layer of wood in the bed and increasing the proportion of char in it. A higher volume of char and a thinner wet wood layer results in a higher average bed temperature.
For the gas phase measurements, the predicted values show very good accordance, especially for the 6 kg/h total airflow cases (1.8 kg/h raw and 3 kg/h raw). For the 9 kg/h total airflow cases (2.7 kg/h raw and 4.5 kg/h raw), the numerical gas temperatures are 10% higher on average. For the four raw cases, the numerical gas temperatures have an average error of 8%.
In
Figure 5, the obtained numerical results for the cooled bed tests are compared against the experimental data. In the four cases, the bed model predicts higher maximum temperatures, especially for the 9 kg/h total airflow cases (2.7 kg/h CB and 4.5 kg/h CB). For these two cases, 35% and 42% higher maximum temperatures are predicted, while for the 6 kg/h total airflow cases (1.8 kg/h CB and 3 kg/h CB), the maximum numerical temperatures registered are around 12% and 18% higher. In the same way as for the raw simulations, the temperature overestimation in the solid fuel bed is probably a result of the thermally thin assumption. Another possible cause of the temperature difference could be that if experimental tests take too long, or if there is poor cleaning between tests, an excessive accumulation of non-reactive ash at the surface of the grate may occur. The thickness of the ash layer can affect the temperature measurements of the lower thermocouples, decreasing the average temperature readings of the zone.
The influence of the bed cooling system in the temperature profiles of the solid fuel bed is clearly seen in all cases, both for CFD and experimental tests. The 9 kg/h total airflow cases show a higher temperature decrease than the 6 kg/h cases, which can be attributed to a higher temperature gradient, due to higher maximum temperatures. On average, for the four cases, at the higher row of bed thermocouples, the numerical temperatures are 30% higher than the experimental measures.
For the gas phase measures, the difference between CFD and experimental is smaller, especially for the 6 kg/h total airflow cases in which the temperature profiles show almost no deviation. For the 9 kg/h total airflow cases, the predicted temperatures are around 12% higher on average than the experimental ones. It can also be seen that in all cases, the temperature at the outlet is predicted with high accuracy.
Based on these results, it can be said that, although the model has shown a tendency to predict higher maximum bed temperatures than experimental ones, the error is within an acceptable range, and that the influence of the internal bed cooling system has been correctly modeled. Outside the bed region, in the freeboard, the numerical temperature profiles have shown great accuracy when compared with the experimental test results.
Once the CFD results have been validated, the influence of the different operating parameters on the combustion can be analyzed.
In
Figure 6, the temperature profiles of the eight numerical studied cases can be seen. The primary airflow has a direct relationship with both maximum and average bed temperatures. Higher primary airflows lead to higher conversion ratios of the solid fuel, resulting in higher temperatures. In a similar way, increasing the total airflow also increases the average gas temperature along the length of the plant, which is directly related to the secondary airflow increase.
The bed cooling system allows an effective reduction of temperatures, both in the bed and along the length of the plant. Its effect is higher in the middle and upper part of the bed, where an average temperature decrease of 240 °C is achieved. In the bottom zone, closer to the grate, the temperature reduction achieved is around 87 °C. Outside the bed region, the effect of bed cooling is translated into an average temperature decrease of 73 °C. This accounts for an average reduction of 21% in bed temperatures and 12% in gas temperatures.
The bed temperature contours (
Figure 7) confirm the effect of the bed cooling system on the average temperature of the solid fuel bed. In addition, it can be clearly seen how the increment of the primary air ratio increases the temperature of the solid fuel. These temperature variations affect the thermal conversion ratio of the biomass fuel, resulting in different bed thicknesses. The cases with lower primary air ratios tend to accumulate more fuel, due to the slower conversion rates caused by the lower flow of primary oxygen. Comparing the bed cooling and the raw cases with the same airflows, it can be seen that the cooled cases present larger bed volumes, due to lower conversion ratios caused by the temperature reduction.
Figure 8 shows the temperatures of the gas phase and the water of the cooling circuits. It can be seen how the secondary air is injected toward the bed, and how the flame is started when this airflow encounters the volatile gases leaving the fuel bed. It can also be seen how the bed cooling and the different air ratios influence the gas temperature. The average temperature of the whole plant in the cooled bed cases is lower than in the raw cases. In addition, it can be easily seen in the raw cases that the 9 kg/h total airflow cases reach higher temperatures than in the 6 kg/h cases. This is a direct effect of the secondary airflow increase. This increases the turbulence and oxygen concentration in the combustion chamber, allowing for more complete combustion of the gases. The cases with higher secondary airflows, apart from higher temperatures in the gas phase, have also shown lower CO, CH
4 and C
6H
6 emissions.
Figure 9 and
Figure 10 show the solid bed densities of moisture, wood and char for the cooled bed cases and the raw cases, respectively. The most notable difference between cases is the thickness of the solid bed, the causes of which have already been discussed above. The bed is mostly composed of char, with the dry wood and wet fuel on top of the bed. The amount of moisture is similar in all cases, but the amount of dry wood is higher in the cooled bed cases because the lower bed temperatures slow down the wood pyrolysis, increasing its residence time.
In addition, it can be seen that the fresh fuel has a tendency to accumulate on the right side. This happens because the fuel is fed from an inlet located on the right side-wall of the combustion chamber module, which increases the chances of the particles falling closer to the right wall.
5. Conclusions
In this work, an experimental biomass fixed bed combustion plant, equipped with an internal bed cooling system, was numerically studied. A CFD commercial code and an Eulerian biomass thermal conversion model were used to carry out the simulations. Eight cases with different air ratios, and with the bed cooling system activated or not activated, were simulated to analyze the effect of air staging and bed cooling on the biomass thermal conversion processes. The obtained numerical results were compared against experimental results to validate the solution.
The CFD results showed good accordance with the experimental test measures. The bed model predicted maximum temperatures between 12% and 18% higher than the experimental values, and around 6% higher for the raw cases. The gas-phase measurements have a better adjustment, with an average deviation of around 8% for both bed-cooled and raw tests.
The bed cooling system reduces the bed temperatures by around 21%, and the gas temperatures around 12%, on average. This translates to an average reduction of 240 °C at the bed’s middle and upper zones. In the bottom zone, where the highest temperatures are recorded, the bed’s internal cooling system has less effect, due to the airflow going upward.
The air staging strategy has been proved effective in order to reduce bed temperatures. The direct relationship between the increase of the primary air ratio and the increment of bed temperatures has been predicted correctly. Because of this, in this type of system, it is advisable to work with low primary air ratios to reduce the bed temperatures and to reduce the PM elutriation. Air staging also helps to reduce the unburnt species emission, due to the increase of the secondary airflow.
The reduction of the bed’s average temperature help to reduce the number of inorganic alkali compounds volatilized, which are the main precursors of fouling and slagging over the refrigerated surfaces and of corrosion.
As futures lines of work, it would be interesting to study the slagging phenomena over the tubes of the internal bed cooling system and its influence on the heat transfer coefficients. The addition of a cooled grate in combination with the actual cooling system to reduce the maximum temperatures should also be taken into consideration. Regarding the modeling, in order to check the influence of the thermally thin assumption on the results, the simulations could be repeated using a thermally thick model that considers internal temperature gradients for the solid fuel bed particles. In addition, pollutant emissions modeling, such as PM and NOx formation mechanisms, could be implemented to study how the bed cooling and air staging strategies affect these phenomena.