Pulsed Laser Deposition of Epitaxial Non-Doped PbTiO3 Thin Films from PbO–TiO2 Mosaic Targets
Abstract
:1. Introduction
2. Experiments
2.1. Fabrication and Characterization of Targets
2.2. Thin Films Growth
2.3. Characterization of Films
3. Results
3.1. Morphology and Composition of the Target Surface
3.2. Properties of PTO Films
4. Discussion
- (i)
- selective ablation at the target (which would drive the film composition to Pb-rich);
- (ii)
- re-evaporation from the substrate (to Pb-poor);
- (iii)
- the CSC mechanism (to stoichiometry).
5. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Sample Name | PbO:TiO2 Areal Ratio | Number of Pulses Irradiated on PbO:TiO2 per 1 Cycle | PTO Growth Rate (10−3 nm/pulse) | PTO out-of-Plane Lattice Spacing (Å) | PTO 002 Rocking Curve FWHM (deg) |
---|---|---|---|---|---|
SP | - | - | 28 | 4.158 | 0.080 |
PC35 | 3:5 | 12:30 | 15 | 4.146 | 0.081 |
PC44 | 4:4 | 18:24 | 14 | 4.146 | 0.087 |
PC53 | 5:3 | 24:18 | 8.6 | 4.141 | 0.090 |
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Sakai, J.; Roque, J.M.C.; Vales-Castro, P.; Padilla-Pantoja, J.; Sauthier, G.; Santiso, J. Pulsed Laser Deposition of Epitaxial Non-Doped PbTiO3 Thin Films from PbO–TiO2 Mosaic Targets. Coatings 2021, 11, 662. https://doi.org/10.3390/coatings11060662
Sakai J, Roque JMC, Vales-Castro P, Padilla-Pantoja J, Sauthier G, Santiso J. Pulsed Laser Deposition of Epitaxial Non-Doped PbTiO3 Thin Films from PbO–TiO2 Mosaic Targets. Coatings. 2021; 11(6):662. https://doi.org/10.3390/coatings11060662
Chicago/Turabian StyleSakai, Joe, José Manuel Caicedo Roque, Pablo Vales-Castro, Jessica Padilla-Pantoja, Guillaume Sauthier, and José Santiso. 2021. "Pulsed Laser Deposition of Epitaxial Non-Doped PbTiO3 Thin Films from PbO–TiO2 Mosaic Targets" Coatings 11, no. 6: 662. https://doi.org/10.3390/coatings11060662
APA StyleSakai, J., Roque, J. M. C., Vales-Castro, P., Padilla-Pantoja, J., Sauthier, G., & Santiso, J. (2021). Pulsed Laser Deposition of Epitaxial Non-Doped PbTiO3 Thin Films from PbO–TiO2 Mosaic Targets. Coatings, 11(6), 662. https://doi.org/10.3390/coatings11060662