Characterisation Method of the Passivation Mechanisms during the pre-discharge Stage of Plasma Electrolytic Oxidation Indicating the Mode of Action of Fluorides in PEO of Magnesium
Abstract
:1. Introduction
1.1. Plasma Electrolytic Oxidation
1.2. Experimental Investigation of Passivation
1.3. Electrolyte Constituents
2. Experimental Procedure
2.1. Setup, Methods, and Materials
2.2. Test Series
3. Results
4. Discussion
- formation of magnesium hydroxide:
- dissociation of water molecules and hydroxide ions:
- physiochemical passivation: adsorption of glycerol molecules on the substrate surface
- electrochemical passivation: passive layer enforcement by reaction of phosphate and fluoride with magnesium to stable, electrical isolating compounds
5. Conclusion
- A new method for the quantification of the passivation behaviour of substrate electrolyte combinations has been established. This procedure requires only low volumes and is suitable for the further development of PEO processes.
- A depassivation effect that occurs on formed Mg passive films has been described, which represents a significant difference to the passivation of aluminium materials.
- i
- An electrochemical model was developed to describe this mechanism.
- ii
- The model was used to explain the occurrence of insufficient layer adhesion in the PEO of magnesium and fluoride-free electrolytes.
- The following categorisation of the passivation mechanisms relevant for the PEO has been proposed:
- i
- physiochemical passivation by adsorption of organic compounds at the substrate/electrolyte interface
- ii
- chemical passivation by buffering of anodic formed protons
- iii
- electrochemical passivation by formation of chemically stable, electrically insulating, insoluble reaction products within the passive layer
- A new theory about the mode of action of fluoride compounds in PEO electrolytes for magnesium has been presented.
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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n | 1 | 2 | 3 | 4 | 5 | 6 |
---|---|---|---|---|---|---|
/V | 0 | 100 | 100 | 0 | 100 | 0 |
/s | 0 | 100 | 220 | 320 | 420 | ≈420 |
Mass Fraction/% | ||||
---|---|---|---|---|
Element | Al 99.5 | AlMgSi1 | Pure Mg | AZ31 |
Al | balance | balance | 0 | 3 |
Mg | 0 | 1 | ≥99.9 | balance |
Si | ≤0.25 | 0.7–1.3 | 0 | 0 |
Zn | 0 | 0 | 0 | 1 |
Substance | c/mol · l | /mS · cm |
---|---|---|
NaHPO | 0.03 | 36.1 |
0.10 | 53.5 | |
CH(OH) | 0.03 | 20.3 |
(glycerol) | 0.10 | 21.9 |
NaF | 0.03 | 20.9 |
0.10 | 26.8 |
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Simchen, F.; Sieber, M.; Mehner, T.; Lampke, T. Characterisation Method of the Passivation Mechanisms during the pre-discharge Stage of Plasma Electrolytic Oxidation Indicating the Mode of Action of Fluorides in PEO of Magnesium. Coatings 2020, 10, 965. https://doi.org/10.3390/coatings10100965
Simchen F, Sieber M, Mehner T, Lampke T. Characterisation Method of the Passivation Mechanisms during the pre-discharge Stage of Plasma Electrolytic Oxidation Indicating the Mode of Action of Fluorides in PEO of Magnesium. Coatings. 2020; 10(10):965. https://doi.org/10.3390/coatings10100965
Chicago/Turabian StyleSimchen, Frank, Maximilian Sieber, Thomas Mehner, and Thomas Lampke. 2020. "Characterisation Method of the Passivation Mechanisms during the pre-discharge Stage of Plasma Electrolytic Oxidation Indicating the Mode of Action of Fluorides in PEO of Magnesium" Coatings 10, no. 10: 965. https://doi.org/10.3390/coatings10100965