Development and Applications of MOFs Derivative One-Dimensional Nanofibers via Electrospinning: A Mini-Review
Abstract
:1. Introduction
2. MOFs-Derived Nanofibers via Electrospinning
2.1. ZIFs/Electrospun Nanofibers (Z-NFs)
- (a)
- ZIFs nanoparticles are evenly loaded in the fiber matrix and the degree of loading is adjustable, which effectively avoid the large-scale agglomeration of ZIFs nanoparticles;
- (b)
- Defects, mesopores, etc. can be formed during electrospinning;
- (c)
- Nanofibers can enhance the mechanical properties and stability of Z-NFs due to its support and protection of ZIFs nanoparticles.
2.2. Other Types of M-NFs
3. Electrospun MOFs-Derived Carbon Nanofibers
3.1. Synthesis
3.2. Application
3.2.1. Battery
3.2.2. Supercapacitor
3.2.3. Sensor
3.2.4. Electrocatalyst
4. Summary and Outlook
Author Contributions
Funding
Conflicts of Interest
References
- Furukawa, H.; Cordova, K.E.; O’Keeffe, M.; Yaghi, O.M. The chemistry and applications of metal-organic frameworks. Science 2013, 341, 1230444. [Google Scholar] [CrossRef] [PubMed]
- Li, B.; Wen, H.M.; Cui, Y.; Zhou, W.; Qian, G.; Chen, B. Emerging multifunctional metal-organic framework materials. Adv. Mater. 2016, 28, 8819–8860. [Google Scholar] [CrossRef] [PubMed]
- Lee, J.; Farha, O.K.; Roberts, J.; Scheidt, K.A.; Nguyen, S.T.; Hupp, J.T. Metal-organic framework materials as catalysts. Chem. Soc. Rev. 2009, 38, 1450–1459. [Google Scholar] [CrossRef] [PubMed]
- Chen, Y.; Huang, X.; Zhang, S.; Li, S.; Cao, S.; Pei, X.; Zhou, J.; Feng, X.; Wang, B. Shaping of metal–organic frameworks: From fluid to shaped bodies and robust foams. J. Am. Chem. Soc. 2016, 138, 10810–10813. [Google Scholar] [CrossRef] [PubMed]
- Furukawa, H.; Ko, N.; Go, Y.B.; Aratani, N.; Choi, S.B.; Choi, E.; Yazaydin, A.Ö.; Snurr, R.Q.; O’Keeffe, M.; Kim, J. Ultrahigh porosity in metal-organic frameworks. Science 2010, 329, 424–428. [Google Scholar] [CrossRef] [PubMed]
- Chen, Y.; Zhang, S.; Cao, S.; Li, S.; Chen, F.; Yuan, S.; Xu, C.; Zhou, J.; Feng, X.; Ma, X.; et al. Roll-to-Roll Production of Metal-Organic Framework Coatings for Particulate Matter Removal. Adv. Mater. 2017, 29, 1606221. [Google Scholar] [CrossRef] [PubMed]
- Qiu, S.; Xue, M.; Zhu, G. Metal-organic framework membranes: From synthesis to separation application. Chem. Soc. Rev. 2014, 43, 6116–6140. [Google Scholar] [CrossRef]
- Li, J.R.; Kuppler, R.J.; Zhou, H.C. Selective gas adsorption and separation in metal-organic frameworks. Chem. Soc. Rev. 2009, 38, 1477–1504. [Google Scholar] [CrossRef]
- Li, X.; Liu, Y.; Wang, J.; Gascon, J.; Li, J.; Van der Bruggen, B. Metal-organic frameworks based membranes for liquid separation. Chem. Soc. Rev. 2017, 46, 7124–7144. [Google Scholar] [CrossRef]
- Lustig, W.P.; Mukherjee, S.; Rudd, N.D.; Desai, A.V.; Li, J.; Ghosh, S.K. Metal-organic frameworks: Functional luminescent and photonic materials for sensing applications. Chem. Soc. Rev. 2017, 46, 3242–3285. [Google Scholar] [CrossRef]
- Pan, Y.; Xue, M.; Chen, M.; Fang, Q.; Zhu, L.; Valtchev, V.; Qiu, S. ZIF-derived in situ nitrogen decorated porous carbons for CO2 capture. Inorg. Chem. Front. 2016, 3, 1112–1118. [Google Scholar] [CrossRef]
- Ahn, Y.; Park, S.; Kim, G.; Hwang, Y.; Lee, C.; Shin, H.; Lee, J. Development of high efficiency nanofilters made of nanofibers. Curr. Appl. Phys. 2006, 6, 1030–1035. [Google Scholar] [CrossRef]
- Wang, C.; Kaneti, Y.V.; Bando, Y.; Lin, J.; Liu, C.; Li, J.; Yamauchi, Y. Metal–organic framework-derived one-dimensional porous or hollow carbon-based nanofibers for energy storage and conversion. Mater. Horiz. 2018, 5, 394–407. [Google Scholar] [CrossRef]
- Wang, C.; Zheng, T.; Luo, R.; Liu, C.; Zhang, M.; Li, J.; Sun, X.; Shen, J.; Han, W.; Wang, L. In Situ Growth of ZIF-8 on PAN Fibrous Filters for Highly Efficient U(VI) Removal. ACS Appl. Mater. Interfaces 2018, 10, 24164–24171. [Google Scholar] [CrossRef] [PubMed]
- Hunley, M.T.; Long, T.E. Electrospinning functional nanoscale fibers: A perspective for the future. Polym. Int. 2008, 57, 385–389. [Google Scholar] [CrossRef]
- Lannutti, J.; Reneker, D.; Ma, T.; Tomasko, D.; Farson, D. Electrospinning for tissue engineering scaffolds. Mater. Sci. Eng. C 2007, 27, 504–509. [Google Scholar] [CrossRef]
- Li, W.J.; Laurencin, C.T.; Caterson, E.J.; Tuan, R.S.; Ko, F.K. Electrospun nanofibrous structure: A novel scaffold for tissue engineering. J. Biomed. Mater. Res. 2002, 60, 613–621. [Google Scholar] [CrossRef] [PubMed]
- Bhardwaj, N.; Kundu, S.C. Electrospinning: A fascinating fiber fabrication technique. Biotechnol. Adv. 2010, 28, 325–347. [Google Scholar] [CrossRef]
- Kim, J.F.; Kim, J.H.; Lee, Y.M.; Drioli, E. Thermally induced phase separation and electrospinning methods for emerging membrane applications: A review. Aiche J. 2016, 62, 461–490. [Google Scholar] [CrossRef]
- Stock, N.; Biswas, S. Synthesis of metal-organic frameworks (MOFs): Routes to various MOF topologies, morphologies, and composites. Chem. Rev. 2011, 112, 933–969. [Google Scholar] [CrossRef]
- Rosi, N.L.; Eckert, J.; Eddaoudi, M.; Vodak, D.T.; Kim, J.; O’Keeffe, M.; Yaghi, O.M. Hydrogen storage in microporous metal-organic frameworks. Science 2003, 300, 1127–1129. [Google Scholar] [CrossRef]
- Siró, I.; Plackett, D. Microfibrillated cellulose and new nanocomposite materials: A review. Cellulose 2010, 17, 459–494. [Google Scholar] [CrossRef]
- Fereydouni, N.; Darroudi, M.; Movaffagh, J.; Shahroodi, A.; Butler, A.E.; Ganjali, S.; Sahebkar, A. Curcumin nanofibers for the purpose of wound healing. J. Cell. Physiol. 2019, 234, 5537–5554. [Google Scholar] [CrossRef]
- Greiner, A.; Wendorff, J.H. Electrospinning: A fascinating method for the preparation of ultrathin fibers. Angew. Chem. Int. Ed. Engl. 2007, 46, 5670–5703. [Google Scholar] [CrossRef]
- Sahoo, N.G.; Rana, S.; Cho, J.W.; Li, L.; Chan, S.H. Polymer nanocomposites based on functionalized carbon nanotubes. Prog. Polym. Sci. 2010, 35, 837–867. [Google Scholar] [CrossRef]
- Sill, T.J.; von Recum, H.A. Electrospinning: Applications in drug delivery and tissue engineering. Biomaterials 2008, 29, 1989–2006. [Google Scholar] [CrossRef]
- Phan, A.; Doonan, C.J.; Uribe-Romo, F.J.; Knobler, C.B.; O’Keeffe, M.; Yaghi, O.M. Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks. Acc. Chem. Res. 2010, 43, 58–67. [Google Scholar] [CrossRef]
- Liu, Y.; Wang, R.; Zhang, T.; Liu, S.; Fei, T. Zeolitic imidazolate framework-8 (ZIF-8)-coated In2O3 nanofibers as an efficient sensing material for ppb-level NO2 detection. J. Colloid Interface Sci. 2019, 541, 249–257. [Google Scholar] [CrossRef]
- Xu, S.; Ren, L.-F.; Zhou, Q.; Bai, H.; Li, J.; Shao, J. Facile ZIF-8 functionalized hierarchical micronanofiber membrane for high-efficiency separation of water-in-oil emulsions. J. Appl. Polym. Sci. 2018, 135, 46462. [Google Scholar] [CrossRef]
- Yang, W.; Liu, X.; Chen, L.; Liang, L.; Jia, J. A metal-organic framework devised Co-N doped carbon microsphere/nanofiber hybrid as a free-standing 3D oxygen catalyst. Chem. Commun. (Camb.) 2017, 53, 4034–4037. [Google Scholar] [CrossRef]
- Quirós, J.; Boltes, K.; Aguado, S.; de Villoria, R.G.; Vilatela, J.J.; Rosal, R. Antimicrobial metal–organic frameworks incorporated into electrospun fibers. Chem. Eng. J. 2015, 262, 189–197. [Google Scholar] [CrossRef]
- Bechelany, M.; Drobek, M.; Vallicari, C.; Abou Chaaya, A.; Julbe, A.; Miele, P. Highly crystalline MOF-based materials grown on electrospun nanofibers. Nanoscale 2015, 7, 5794–5802. [Google Scholar] [CrossRef]
- Ostermann, R.; Cravillon, J.; Weidmann, C.; Wiebcke, M.; Smarsly, B.M. Metal-organic framework nanofibers via electrospinning. Chem. Commun. (Camb) 2011, 47, 442–444. [Google Scholar] [CrossRef]
- Lian, Z.; Huimin, L.; Zhaofei, O. In situ crystal growth of zeolitic imidazolate frameworks (ZIF) on electrospun polyurethane nanofibers. Dalton Trans. 2014, 43, 6684–6688. [Google Scholar] [CrossRef] [Green Version]
- Gao, M.; Zeng, L.; Nie, J.; Ma, G. Polymer–metal–organic framework core–shell framework nanofibers via electrospinning and their gas adsorption activities. RSC Adv. 2016, 6, 7078–7085. [Google Scholar] [CrossRef]
- Morabito, J.V.; Chou, L.Y.; Li, Z.; Manna, C.M.; Petroff, C.A.; Kyada, R.J.; Palomba, J.M.; Byers, J.A.; Tsung, C.K. Molecular encapsulation beyond the aperture size limit through dissociative linker exchange in metal-organic framework crystals. J. Am. Chem. Soc. 2014, 136, 12540–12543. [Google Scholar] [CrossRef]
- Xu, P.; Xu, T.; Yu, H.; Li, X. Resonant-Gravimetric Identification of Competitive Adsorption of Environmental Molecules. Anal. Chem. 2017, 89, 7031–7037. [Google Scholar] [CrossRef]
- Wang, C.; Wang, H.; Luo, R.; Liu, C.; Li, J.; Sun, X.; Shen, J.; Han, W.; Wang, L. Metal-organic framework one-dimensional fibers as efficient catalysts for activating peroxymonosulfate. Chem. Eng. J. 2017, 330, 262–271. [Google Scholar] [CrossRef]
- Chou, Y.; Shao, C.; Li, X.; Su, C.; Xu, H.; Zhang, M.; Zhang, P.; Zhang, X.; Liu, Y. BiOCl nanosheets immobilized on electrospun polyacrylonitrile nanofibers with high photocatalytic activity and reusable property. Appl. Surf. Sci. 2013, 285, 509–516. [Google Scholar] [CrossRef]
- Zhang, Y.; Zhang, Y.; Wang, X.; Yu, J.; Ding, B. Ultrahigh Metal-Organic Framework Loading and Flexible Nanofibrous Membranes for Efficient CO2 Capture with Long-Term, Ultrastable Recyclability. ACS Appl. Mater. Interfaces 2018, 10, 34802–34810. [Google Scholar] [CrossRef]
- Zhang, C.; Shen, L.; Shen, J.; Liu, F.; Chen, G.; Tao, R.; Ma, S.; Peng, Y.; Lu, Y. Anion-Sorbent Composite Separators for High-Rate Lithium-Ion Batteries. Adv. Mater. 2019, 31, e1808338. [Google Scholar] [CrossRef]
- Wu, Y.-N.; Li, F.; Liu, H.; Zhu, W.; Teng, M.; Jiang, Y.; Li, W.; Xu, D.; He, D.; Hannam, P.; et al. Electrospun fibrous mats as skeletons to produce free-standing MOF membranes. J. Mater. Chem. 2012, 22, 16971–16978. [Google Scholar] [CrossRef]
- Peterson, G.W.; Lu, A.X.; Epps, T.H., III. Tuning the Morphology and Activity of Electrospun Polystyrene/UiO-66-NH2 Metal-Organic Framework Composites to Enhance Chemical Warfare Agent Removal. ACS Appl. Mater. Interfaces 2017, 9, 32248–32254. [Google Scholar] [CrossRef]
- Lu, A.X.; McEntee, M.; Browe, M.A.; Hall, M.G.; DeCoste, J.B.; Peterson, G.W. MOFabric: Electrospun Nanofiber Mats from PVDF/UiO-66-NH2 for Chemical Protection and Decontamination. ACS Appl. Mater. Interfaces 2017, 9, 13632–13636. [Google Scholar] [CrossRef]
- Leus, K.; Krishnaraj, C.; Verhoeven, L.; Cremers, V.; Dendooven, J.; Ramachandran, R.K.; Dubruel, P.; Van Der Voort, P. Catalytic carpets: Pt@MIL-101@electrospun PCL, a surprisingly active and robust hydrogenation catalyst. J. Catal. 2018, 360, 81–88. [Google Scholar] [CrossRef]
- Ismail, F.M.; Abdellah, A.M.; Ali, P.A.; Shawky, S.M.; Alkordi, M.H.; El-Sherbiny, I.M. Bilayer sandwich-like membranes of metal organic frameworks-electrospun polymeric nanofibers via SiO2 nanoparticles seeding. Mater. Today Commun. 2017, 12, 119–124. [Google Scholar] [CrossRef]
- Efome, J.E.; Rana, D.; Matsuura, T.; Lan, C.Q. Insight Studies on Metal-Organic Framework Nanofibrous Membrane Adsorption and Activation for Heavy Metal Ions Removal from Aqueous Solution. ACS Appl. Mater. Interfaces 2018, 10, 18619–18629. [Google Scholar] [CrossRef]
- Yan, X.; Komarneni, S.; Zhang, Z.; Yan, Z. Extremely enhanced CO2 uptake by HKUST-1 metal–organic framework via a simple chemical treatment. Microporous Mesoporous Mater. 2014, 183, 69–73. [Google Scholar] [CrossRef]
- Zhang, Y.; Yuan, S.; Feng, X.; Li, H.; Zhou, J.; Wang, B. Preparation of Nanofibrous Metal-Organic Framework Filters for Efficient Air Pollution Control. J. Am. Chem. Soc. 2016, 138, 5785–5788. [Google Scholar] [CrossRef]
- Zhang, Y.; Guan, J.; Wang, X.; Yu, J.; Ding, B. Balsam-Pear-Skin-Like Porous Polyacrylonitrile Nanofibrous Membranes Grafted with Polyethyleneimine for Postcombustion CO2 Capture. ACS Appl. Mater. Interfaces 2017, 9, 41087–41098. [Google Scholar] [CrossRef]
- Zhang, W.; Tu, Z.; Qian, J.; Choudhury, S.; Archer, L.A.; Lu, Y. Design Principles of Functional Polymer Separators for High-Energy, Metal-Based Batteries. Small 2018, 14, e1703001. [Google Scholar] [CrossRef]
- Laurila, E.; Thunberg, J.; Argent, S.P.; Champness, N.R.; Zacharias, S.; Westman, G.; Öhrström, L. Enhanced Synthesis of Metal-Organic Frameworks on the Surface of Electrospun Cellulose Nanofibers. Adv. Eng. Mater. 2015, 17, 1282–1286. [Google Scholar] [CrossRef] [Green Version]
- Yang, Q.; Zhang, M.; Song, S.; Yang, B. Surface modification of PCC filled cellulose paper by MOF-5 (Zn3(BDC)2) metal-organic frameworks for use as soft gas adsorption composite materials. Cellulose 2017, 24, 3051–3060. [Google Scholar] [CrossRef]
- Zhao, J.; Lee, D.T.; Yaga, R.W.; Hall, M.G.; Barton, H.F.; Woodward, I.R.; Oldham, C.J.; Walls, H.J.; Peterson, G.W.; Parsons, G.N. Ultra-Fast Degradation of Chemical Warfare Agents Using MOF–Nanofiber Kebabs. Angew. Chem. Int. Ed. 2016, 55, 13224–13228. [Google Scholar] [CrossRef]
- Wu, B.; Pan, J.; Ge, L.; Wu, L.; Wang, H.; Xu, T. Oriented MOF-polymer composite nanofiber membranes for high proton conductivity at high temperature and anhydrous condition. Sci. Rep. 2014, 4, 4334. [Google Scholar] [CrossRef]
- Kohsari, I.; Shariatinia, Z.; Pourmortazavi, S.M. Antibacterial electrospun chitosan-polyethylene oxide nanocomposite mats containing ZIF-8 nanoparticles. Int. J. Biol. Macromol. 2016, 91, 778–788. [Google Scholar] [CrossRef]
- Liu, F.; Xu, H. Development of a novel polystyrene/metal-organic framework-199 electrospun nanofiber adsorbent for thin film microextraction of aldehydes in human urine. Talanta 2017, 162, 261–267. [Google Scholar] [CrossRef]
- Yan, Z.; Wu, M.; Hu, B.; Yao, M.; Zhang, L.; Lu, Q.; Pang, J. Electrospun UiO-66/polyacrylonitrile nanofibers as efficient sorbent for pipette tip solid phase extraction of phytohormones in vegetable samples. J. Chromatogr. A 2018, 1542, 19–27. [Google Scholar] [CrossRef]
- Asiabi, M.; Mehdinia, A.; Jabbari, A. Preparation of water stable methyl-modified metal-organic framework-5/polyacrylonitrile composite nanofibers via electrospinning and their application for solid-phase extraction of two estrogenic drugs in urine samples. J. Chromatogr. A 2015, 1426, 24–32. [Google Scholar] [CrossRef]
- Hong, Y.; Liu, C.; Cao, X.; Chen, Y.; Chen, C.; Chen, Y.; Pan, Z. Process Evaluation of the Metal-Organic Frameworks for the Application of Personal Protective Equipment with Filtration Function. Polymers 2018, 10, 1386. [Google Scholar] [CrossRef]
- Koo, W.-T.; Jang, J.-S.; Choi, S.-J.; Cho, H.-J.; Kim, I.-D. Metal–organic framework templated catalysts: Dual sensitization of PdO–ZnO composite on hollow SnO2 nanotubes for selective acetone sensors. ACS Appl. Mater. Interfaces 2017, 9, 18069–18077. [Google Scholar] [CrossRef]
- Guo, J.; Chen, B.; Hao, Q.; Nie, J.; Ma, G. Pod-like structured Co/CoOx nitrogen-doped carbon fibers as efficient oxygen reduction reaction electrocatalysts for Zn-air battery. Appl. Surf. Sci. 2018, 456, 959–966. [Google Scholar] [CrossRef]
- Chen, Y.M.; Yu, L.; Lou, X.W. Hierarchical Tubular Structures Composed of Co3O4 Hollow Nanoparticles and Carbon Nanotubes for Lithium Storage. Angew. Chem. Int. Ed. Engl. 2016, 55, 5990–5993. [Google Scholar] [CrossRef]
- Eftekhari, A.; Kim, D.-W. Cathode materials for lithium–sulfur batteries: A practical perspective. J. Mater. Chem. A 2017, 5, 17734–17776. [Google Scholar] [CrossRef]
- Elazari, R.; Salitra, G.; Garsuch, A.; Panchenko, A.; Aurbach, D. Sulfur-impregnated activated carbon fiber cloth as a binder-free cathode for rechargeable Li-S batteries. Adv. Mater. 2011, 23, 5641–5644. [Google Scholar] [CrossRef]
- Lavoie, N.; Malenfant, P.R.; Courtel, F.M.; Abu-Lebdeh, Y.; Davidson, I.J. High gravimetric capacity and long cycle life in Mn3O4/graphene platelet/LiCMC composite lithium-ion battery anodes. J. Power Sources 2012, 213, 249–254. [Google Scholar] [CrossRef]
- Nam, I.; Kim, N.D.; Kim, G.-P.; Park, J.; Yi, J. One step preparation of Mn3O4/graphene composites for use as an anode in Li ion batteries. J. Power Sources 2013, 244, 56–62. [Google Scholar] [CrossRef]
- Wang, C.; Yin, L.; Xiang, D.; Qi, Y. Uniform carbon layer coated Mn3O4 nanorod anodes with improved reversible capacity and cyclic stability for lithium ion batteries. ACS Appl. Mater. Interfaces 2012, 4, 1636–1642. [Google Scholar] [CrossRef]
- Yang, Q.; Feng, C.; Liu, J.; Guo, Z. Synthesis of porous Co3O4/C nanoparticles as anode for Li-ion battery application. Appl. Surf. Sci. 2018, 443, 401–406. [Google Scholar] [CrossRef]
- Cheong, J.Y.; Koo, W.-T.; Kim, C.; Jung, J.-W.; Kim, I.-D. Feasible Defect Engineering by Employing Metal Organic Framework Templates into One-Dimensional Metal Oxides for Battery Applications. ACS Appl. Mater. Interfaces 2018, 10, 20540–20549. [Google Scholar] [CrossRef]
- Cheong, J.Y.; Kim, C.; Jung, J.W.; Yoon, K.R.; Kim, I.D. Porous SnO2-CuO nanotubes for highly reversible lithium storage. J. Power Sources 2018, 373, 11–19. [Google Scholar] [CrossRef]
- Yang, C.; Yao, Y.; Lian, Y.; Chen, Y.; Shah, R.; Zhao, X.; Chen, M.; Peng, Y.; Deng, Z. A Double-Buffering Strategy to Boost the Lithium Storage of Botryoid MnOx/C Anodes. Small 2019, 15, e1900015. [Google Scholar] [CrossRef]
- Zhang, W.M.; Cao, P.; Zhang, Z.H.; Zhao, Y.J.; Zhang, Y.; Li, L.; Yang, K.; Li, X.W.; Gu, L. Nickel/cobalt metal-organic framework derived 1D hierarchical NiCo2O4/NiO/carbon nanofibers for advanced sodium storage. Chem. Eng. J. 2019, 364, 123–131. [Google Scholar] [CrossRef]
- Zhang, C.L.; Lu, B.R.; Cao, F.H.; Yu, Z.L.; Cong, H.P.; Yu, S.H. Hierarchically structured Co3O4@carbon porous fibers derived from electrospun ZIF-67/PAN nanofibers as anodes for lithium ion batteries. J. Mater. Chem. A 2018, 6, 12962–12968. [Google Scholar] [CrossRef]
- Wang, Q.; Lei, Y.; Chen, Z.; Wu, N.; Wang, Y.; Wang, B.; Wang, Y. Fe/Fe3C@C nanoparticles encapsulated in N-doped graphene–CNTs framework as an efficient bifunctional oxygen electrocatalyst for robust rechargeable Zn–air batteries. J. Mater. Chem. A 2018, 6, 516–526. [Google Scholar] [CrossRef]
- Wu, M.; Hu, X.; Li, C.; Li, J.; Zhou, H.; Zhang, X.; Liu, R. Encapsulation of metal precursor within ZIFs for bimetallic N-doped carbon electrocatalyst with enhanced oxygen reduction. Int. J. Hydrog. Energy 2018, 43, 14701–14709. [Google Scholar] [CrossRef]
- Wang, G.; Ling, Y.; Qian, F.; Yang, X.; Liu, X.-X.; Li, Y. Enhanced capacitance in partially exfoliated multi-walled carbon nanotubes. J. Power Sources 2011, 196, 5209–5214. [Google Scholar] [CrossRef]
- Hong, J.-Y.; Wie, J.J.; Xu, Y.; Park, H.S. Chemical modification of graphene aerogels for electrochemical capacitor applications. PCCP 2015, 17, 30946–30962. [Google Scholar] [CrossRef]
- Shen, L.; Wang, D.; Jin, Z.; Che, L.; Cai, N.; Wang, Y.; Lu, Y. The effect of drying modes on aqueous dispersion of graphene oxide solids. Funct. Mater. Lett. 2019, 12, 1950043. [Google Scholar] [CrossRef]
- Cai, N.; Fu, J.; Chan, V.; Liu, M.; Chen, W.; Wang, J.; Zeng, H.; Yu, F. MnCo2O4@nitrogen-doped carbon nanofiber composites with meso-microporous structure for high-performance symmetric supercapacitors. J. Alloys Compd. 2019, 782, 251–262. [Google Scholar] [CrossRef]
- Cai, N.; Fu, J.; Zeng, H.; Luo, X.; Han, C.; Yu, F. Reduced graphene oxide-silver nanoparticles/nitrogen-doped carbon nanofiber composites with meso-microporous structure for high-performance symmetric supercapacitor application. J. Alloys Compd. 2018, 742, 769–779. [Google Scholar] [CrossRef]
- Kim, C.; Choi, Y.-O.; Lee, W.-J.; Yang, K.-S. Supercapacitor performances of activated carbon fiber webs prepared by electrospinning of PMDA-ODA poly (amic acid) solutions. Electrochim. Acta 2004, 50, 883–887. [Google Scholar] [CrossRef]
- Chen, Y.; Dong, J.; Qiu, L.; Li, X.; Li, Q.; Wang, H.; Liang, S.; Yao, H.; Huang, H.; Gao, H. A catalytic etching-wetting-dewetting mechanism in the formation of hollow graphitic carbon fiber. Chem 2017, 2, 299–310. [Google Scholar] [CrossRef]
- Yao, Y.; Wu, H.; Huang, L.; Li, X.; Yu, L.; Zeng, S.; Zeng, X.; Yang, J.; Zou, J. Nitrogen-enriched hierarchically porous carbon nanofiber network as a binder-free electrode for high-performance supercapacitors. Electrochim. Acta 2017, 246, 606–614. [Google Scholar] [CrossRef]
- Yao, Y.; Liu, P.; Li, X.; Zeng, S.; Lan, T.; Huang, H.; Zeng, X.; Zou, J. Nitrogen-doped graphitic hierarchically porous carbon nanofibers obtained via bimetallic-coordination organic framework modification and their application in supercapacitors. Dalton Trans. 2018, 47, 7316–7326. [Google Scholar] [CrossRef]
- Wang, H.; Yuan, X.; Wu, Y.; Zeng, G.; Chen, X.; Leng, L.; Li, H. Synthesis and applications of novel graphitic carbon nitride/metal-organic frameworks mesoporous photocatalyst for dyes removal. Appl. Catal. B Environ. 2015, 174–175, 445–454. [Google Scholar] [CrossRef]
- Hermes, S.; Schröter, M.K.; Schmid, R.; Khodeir, L.; Muhler, M.; Tissler, A.; Fischer, R.W.; Fischer, R.A. Metal@MOF: Loading of highly porous coordination polymers host lattices by metal organic chemical vapor deposition. Angew. Chem. Int. Ed. 2005, 44, 6237–6241. [Google Scholar] [CrossRef]
- Jiang, H.-L.; Akita, T.; Ishida, T.; Haruta, M.; Xu, Q. Synergistic catalysis of Au@Ag core−shell nanoparticles stabilized on metal−organic framework. J. Am. Chem. Soc. 2011, 133, 1304–1306. [Google Scholar] [CrossRef]
- Ma, Q.; Wang, J.; Dong, X.; Yu, W.; Liu, G. Flexible Janus nanoribbons array: A new strategy to achieve excellent electrically conductive anisotropy, magnetism, and photoluminescence. Adv. Funct. Mater. 2015, 25, 2436–2443. [Google Scholar] [CrossRef]
- Koo, W.-T.; Choi, S.-J.; Kim, S.-J.; Jang, J.-S.; Tuller, H.L.; Kim, I.-D. Heterogeneous sensitization of metal–organic framework driven metal@metal oxide complex catalysts on an oxide nanofiber scaffold toward superior gas sensors. J. Am. Chem. Soc. 2016, 138, 13431–13437. [Google Scholar] [CrossRef]
- Guo, L.; Chen, F.; Xie, N.; Kou, X.; Wang, C.; Sun, Y.; Liu, F.; Liang, X.; Gao, Y.; Yan, X.; et al. Ultra-sensitive sensing platform based on Pt-ZnO-In2O3 nanofibers for detection of acetone. Sens. Actuators B Chem. 2018, 272, 185–194. [Google Scholar] [CrossRef]
- Chu, S.; Majumdar, A. Opportunities and challenges for a sustainable energy future. Nature 2012, 488, 294–303. [Google Scholar] [CrossRef]
- Zhang, J.; Zhao, Z.; Xia, Z.; Dai, L. A metal-free bifunctional electrocatalyst for oxygen reduction and oxygen evolution reactions. Nat. Nanotechnol. 2015, 10, 444–452. [Google Scholar] [CrossRef]
- Xia, B.Y.; Yan, Y.; Li, N.; Wu, H.B.; Lou, X.W.D.; Wang, X. A metal–organic framework-derived bifunctional oxygen electrocatalyst. Nat. Energy 2016, 1, 15006. [Google Scholar] [CrossRef]
- Debe, M.K. Electrocatalyst approaches and challenges for automotive fuel cells. Nature 2012, 486, 43–51. [Google Scholar] [CrossRef]
- Huang, J.; Liu, Y.; Hou, H.; You, T. Simultaneous electrochemical determination of dopamine, uric acid and ascorbic acid using palladium nanoparticle-loaded carbon nanofibers modified electrode. Biosens. Bioelectron. 2008, 24, 632–637. [Google Scholar] [CrossRef]
- Niu, Q.; Guo, J.; Chen, B.; Nie, J.; Guo, X.; Ma, G. Bimetal-organic frameworks/polymer core–shell nanofibers derived heteroatom-doped carbon materials as electrocatalysts for oxygen reduction reaction. Carbon 2017, 114, 250–260. [Google Scholar] [CrossRef]
- Wu, M.; Li, C.; Liu, R. Freestanding 1D Hierarchical Porous Fe-N-Doped Carbon Nanofibers as Efficient Oxygen Reduction Catalysts for Zn–Air Batteries. Energy Technol. 2019, 7, 1800790. [Google Scholar] [CrossRef]
- Li, Z.; Tang, B. Mn3O4/nitrogen-doped porous carbon fiber hybrids involving multiple covalent interactions and open voids as flexible anodes for lithium-ion batteries. Green Chem. 2017, 19, 5862–5873. [Google Scholar] [CrossRef]
- Liu, W.; Xu, L.; Sheng, K.; Zhou, X.; Zhang, X.; Chen, C.; Dong, B.; Bai, X.; Geyu, L.; Song, H. Facile synthesis of controllable TiO2 composite nanotubes via templating route: Highly sensitive detection of toluene by double driving from Pt@ZnO NPs. Sens. Actuators B Chem. 2018, 273, 1676–1686. [Google Scholar] [CrossRef]
Sample | ZIF-8 Concentration (wt %) | BET surface area/m2 g−1 | Ref. |
---|---|---|---|
ZIF-8 | 100 | 960 | [33] |
ZIF-8/PVP | 22 | 180 | [33] |
ZIF-8/PVP | 56 | 530 | [33] |
PVP | 0 | 10 | [33] |
ZIF-8/PS | 25 | 210 | [33] |
ZIF-8 | 100 | 1195 | [34] |
ZIF-8/PU | 63 | 566 | [34] |
ZIF-8 | 100 | 1219 | [34] |
PAN@ZIF-8 | - | 983 | [35] |
M-NFs | Metal center of MOFs | Property or application | Value | Ref. |
---|---|---|---|---|
ZIF-8/PVDF | Zn | Oil/water separation | Rejection rate 92.93% | [29] |
Co-MOF/PLA | Co | Antimicrobial mats | - | [31] |
ZIF-67/PLA | Co | Antibacterial film | - | [32] |
ZIF-8/PU | Zn | BET surface area | 566 cm2 g −1 | [34] |
ZIF-8/PAN | Zn | BET surface area | 983 cm2 g −1 | [35] |
HKUST-1/PAN | Cu | CO2 capture | 3.9 mmol g−1 | [40] |
UiO-66-NH2/PS | Zr | Chemical warfare agent removal | Soman half-lives (t1/2) 95 min | [43] |
MOF-808/PAN | Zr | Heavy metal ions removal | Adsorption capacities (225.05 mg g−1 for Cd2+ 287.06 mg g−1 for Zn2+) | [47] |
HKUST-1/Cellulose | Cu | BET surface area | Increased 44 to 440 m2 g−1 | [52] |
MOF-5/Cellulose | Zn | Gas adsorption. | - | [53] |
Zr-MOF/PA-6 | Zr | Degradation of CWAs | Half-lives of nerve agent soman 2.3 min | [54] |
Zn-MOF/SPPESK | Zn | Proton exchange membrane fuel cell | Proton conductivity (8.2 ± 0.16) × 10−2 S cm−1 (160 °C) | [55] |
ZIF-8/CS-PEO | Zn | Antimicrobial mats | 100% antibacterial activity against Gram-positive Staphylococcus aureus | [56] |
MOF-199/PS | Cu | Determination of acetaldehyde in human urine | Limits of detection 0.01 to 0.02 ng mL−1 | [57] |
UiO-66/PAN | Zr | Determination of plant hormone content | Limit of detection 0.01 ng mL−1 | [58] |
MOF-5/PAN | Zn | Solid-phase extraction of two estrogenic drugs in urine samples | Limit of detection 0.02 g L−1 | [59] |
ZIF-8/PAN | Zn | Functional textiles with filtration function | Removal of PM2.5 78.35% | [60] |
Composites | Precursor (or Template) | Property (or Application) | Value | Ref. | |
---|---|---|---|---|---|
Mn3O4/graphene | Mn/GO | Lithium ion battery | Reversible capacity of 500 mAh g−1 at a current density of 60 mA g−1 | [67] | |
Mn3O4@C | Mn/PVP | Lithium ion battery | Reversible capacity of 473 mAh g−1 at a current density of 40 mA g−1 | [68] | |
Co3O4/C | ZIF-67/PAN | Lithium ion battery | Capacity of 1024.1mAh g−1 after 100 cycles | [69] | |
SnO2-Co3O4 NFs | ZIF-67 | Lithium ion battery | Reversible capacity of 1287 mAh g–1 after 300 cycles | [70] | |
MnOx/CNFs | Mn-MOF | Lithium ion battery | Prolonged stability over 1000 cycles | [72] | |
NiCo2O4/NiO/CNFs | Ni/Co-MOF | Sodium ion battery | Sodium-storage capacity of 210 mAh g−1 | [73] | |
Co3O4@CNFs | ZIF-67/PAN | Lithium ion battery | The reversible capacity 558 mAh g−1 after 500 cycles at 5 A g−1 | [74] | |
Mn3O4/NPCs | Mn-MOF | Lithium ion battery | Specific capacity (1058 mAh g−1 at 50 mA g−1) | [99] | |
N-doped Co/CoOx CNFs | ZIF-67@PAN | Zn-air battery | Discharge specific capacity of 610 mAh g−1 | [62] | |
Fe-N-doped CNFs | Zn-Fe-ZIF/PAN | Zn-air battery | Comparable with the commercial 20wt % Pt/C | [98] | |
Exfoliated-CNTs | Multi-walled carbon nanotubes | Supercapacitors | Specific capacitance of 165 F g−1 at current density of 5 A g−1 | [77] | |
Graphene aerogels(GAs) | GO | Supercapacitors | - | [78] | |
Graphitized polyimide web | Pyromellitic dianhydride (PMDA)/4,4’-oxydianiline (ODA) | Supercapacitors | Specific capacitance 175 F g−1 at current density of 1000 mA g−1 | [82] | |
N-doped graphitic hierarchically porous carbon nanofibers (NGHPCF) | Zn/Co-MOF | Supercapacitors | Specific capacitance of 326 F g−1 at current density of 0.5 A g−1 | [85] | |
Pd@MOF-5 | MOF-5 | - | - | [87] | |
Au@Ag/ZIF-8 | ZIF-8 | Catalysis | - | [88] | |
PdO@ZnO-SnO2 NTs | Pd@ZIF-8 | Acetone sensor | Rair/Rgas = 5.06 at 400 °C@1 ppm | [61] | |
Pt@ZnOTiO2 NTs | Pt@ZIF-8 | Toluene sensor | Detection limit (23 parts per billion) | [100] | |
Pt-ZnO-In2O3 NFs | Pt@ZIF-8 | Acetone sensor | Response and recovery times to 100 ppm acetone (1/44 s) at 300 °C | [91] | |
Zn/Co@C-NCNFs | Zn-Co-ZIF/PAN | ORR | Electron selectivity 3.69 | [97] | |
Pt@MIL-101@PCL | MIL-101 | Hydrogenation catalyst | Complete reaction within 90 min | [45] |
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Liu, M.; Cai, N.; Chan, V.; Yu, F. Development and Applications of MOFs Derivative One-Dimensional Nanofibers via Electrospinning: A Mini-Review. Nanomaterials 2019, 9, 1306. https://doi.org/10.3390/nano9091306
Liu M, Cai N, Chan V, Yu F. Development and Applications of MOFs Derivative One-Dimensional Nanofibers via Electrospinning: A Mini-Review. Nanomaterials. 2019; 9(9):1306. https://doi.org/10.3390/nano9091306
Chicago/Turabian StyleLiu, Mingming, Ning Cai, Vincent Chan, and Faquan Yu. 2019. "Development and Applications of MOFs Derivative One-Dimensional Nanofibers via Electrospinning: A Mini-Review" Nanomaterials 9, no. 9: 1306. https://doi.org/10.3390/nano9091306