Synthesis of New Magnetic Crosslinked Poly (Ionic Liquid) Nanocomposites for Fast Congo Red Removal from Industrial Wastewater
Abstract
:1. Introduction
2. Experimental
2.1. Materials
2.2. Preparation Methods
2.2.1. Preparation of Magnetic Cross-Linked PIL
2.2.2. Preparation of Magnetic Cross-Linked PIL (Fe3O4-QVP/AAm)
2.3. Characterization
2.4. Dye Removal Measurements
3. Results and Discussion
3.1. Characterization
3.2. Application of Magnetic QVP/AAm Composite for CR Adsorbents
3.3. Adsorption Kinetics Isotherms and Mechanism of QVP/AAm-Fe3O4
3.4. The Reusability of QVP/AAm-Fe3O4 Nanocomposite
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Adsorbents | Langmuir Isotherm Parameters | Freundlich Isotherm Parameters | Exp. Adsorption Capacity | ||||
---|---|---|---|---|---|---|---|
Qmax mg·g−1 | Kl L·mg−1 | R2 | n (g·L−1) | Kf [(mg·g−1) (L·mg−1)(1/n) )] | R2 | Qmax mg·g−1 | |
QVP/AAm-Fe3O4 | 899.2 | 0.386 | 1 | 9.80 | 540.7 | 0.912 | 940.2 |
Cryogel Composites | qexp. (mg·g−1) | Pseudo-First Order Kinetic Parameters | Pseudo-Second-Order Kinetic Parameters | ||||
---|---|---|---|---|---|---|---|
R2 | qcalc. (mg·g−1) | K1 (min−1) | R2 | qcalc. (mg·g−1) | K2 (g·mg−1·min−1) | ||
Na-VS/Na-AMPS | 940.2 | 0.96 | 433.2 | 0.00783 | 0.999 | 966.2 | 0.07 |
ΔH0 (KJ·mol−1) | ΔS0 (J·mol−1) | ΔG0 (KJ·mol−1) | |||
---|---|---|---|---|---|
298 K | 313 K | 328 K | 343 K | ||
−32.477 | −75.24 | −10.05 | −8.9 | −7.8 | −6.66 |
Adsorbent | Contact Time (min) | Q Max (mg/g) | Reference |
---|---|---|---|
Ionic liquid-based nanoporous organosilica supported propylamine | 30 | 43.1 | [57] |
Activated carbon | 1440 | 105 | [58] |
Chitosan/organomontmorillonite | 480 | 293 | [59] |
Magnetite nanoparticle | 40 | 68.5 | [60] |
Quercetin modified α-Fe2O3 nanoparticles | 160 | 556.96 | [61] |
QVP/AAm-Fe3O4 | 35 | 903 | This work |
Adsorbent | CR Removal Efficiency (%) |
---|---|
QVP/AAm-Fe3O4 | |
Cycle 1 | 99.8 |
Cycle 2 | 99.8 |
Cycle 3 | 99.5 |
Cycle 4 | 99.4 |
Cycle 5 | 75.0 |
Cycle 6 | 65.3 |
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Atta, A.M.; Ezzat, A.O.; Moustafa, Y.M.; Sabeela, N.I.; Tawfeek, A.M.; Al-Lohedan, H.A.; Hashem, A.I. Synthesis of New Magnetic Crosslinked Poly (Ionic Liquid) Nanocomposites for Fast Congo Red Removal from Industrial Wastewater. Nanomaterials 2019, 9, 1286. https://doi.org/10.3390/nano9091286
Atta AM, Ezzat AO, Moustafa YM, Sabeela NI, Tawfeek AM, Al-Lohedan HA, Hashem AI. Synthesis of New Magnetic Crosslinked Poly (Ionic Liquid) Nanocomposites for Fast Congo Red Removal from Industrial Wastewater. Nanomaterials. 2019; 9(9):1286. https://doi.org/10.3390/nano9091286
Chicago/Turabian StyleAtta, Ayman M., Abdelrahman O. Ezzat, Yaser M. Moustafa, Nourah I. Sabeela, Ahmed M. Tawfeek, Hamad A. Al-Lohedan, and Ahmed I. Hashem. 2019. "Synthesis of New Magnetic Crosslinked Poly (Ionic Liquid) Nanocomposites for Fast Congo Red Removal from Industrial Wastewater" Nanomaterials 9, no. 9: 1286. https://doi.org/10.3390/nano9091286