Large-Scale Fabrication of Nanostructure on Bio-Metallic Substrate for Surface Enhanced Raman and Fluorescence Scattering
Abstract
:1. Introduction
2. Materials and Methods
2.1. Sample Preparation
2.2. Surface Characterization
2.3. Reflectance and Absorption Spectroscopy
2.4. Raman and Fluorescence Spectroscopy
3. Results and Discussion
3.1. Topography of the Hierarchical LIPSS
3.2. Optical Properties
3.3. SERS Characteristics
3.4. SEF Characteristics
4. Conclusions
- The hierarchical LIPSS structure consisting of micro-grooves, nano-ripples, and nano-particles with strong SPR was produced by one-step femtosecond laser processing, which may open up new possibilities in both SERS and SEF.
- Due to the combination effect of SPR and “hot spots”, the hierarchical LIPSS substrate exhibits an ultra-sensitive detectability, which shows an EFs of 7.85 × 105 for CV and LOD of 10−11 mol/L.
- The intensity of the CV fluorescence on the hierarchical LIPSS substrate was enhanced by about 14 times with the LOD of 1 × 10−10 mol/L, which is attributed to the LSPR and “hot spots” from the hierarchical LIPSS.
Author Contributions
Funding
Conflicts of Interest
References
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Peak (cm−1) | 913 | 1175 | 1229 | 1539 | 1587 | 1618 |
---|---|---|---|---|---|---|
LIPSS | 8.83 × 103 | 1.99 × 104 | 2.15 × 103 | 8.29 × 103 | 3.59 × 104 | 2.16 × 104 |
Hierarchical LIPSS | 2.82 × 104 | 6.27 × 104 | 7.85 × 105 | 7.28 × 104 | 2.32 × 105 | 1.36 × 105 |
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Lu, L.; Zhang, J.; Jiao, L.; Guan, Y. Large-Scale Fabrication of Nanostructure on Bio-Metallic Substrate for Surface Enhanced Raman and Fluorescence Scattering. Nanomaterials 2019, 9, 916. https://doi.org/10.3390/nano9070916
Lu L, Zhang J, Jiao L, Guan Y. Large-Scale Fabrication of Nanostructure on Bio-Metallic Substrate for Surface Enhanced Raman and Fluorescence Scattering. Nanomaterials. 2019; 9(7):916. https://doi.org/10.3390/nano9070916
Chicago/Turabian StyleLu, Libin, Jiaru Zhang, Lishi Jiao, and Yingchun Guan. 2019. "Large-Scale Fabrication of Nanostructure on Bio-Metallic Substrate for Surface Enhanced Raman and Fluorescence Scattering" Nanomaterials 9, no. 7: 916. https://doi.org/10.3390/nano9070916