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Open AccessArticle

Gold Film over SiO2 Nanospheres—New Thermally Resistant Substrates for Surface-Enhanced Raman Scattering (SERS) Spectroscopy

Department of Physical Electronics, Faculty of Nuclear Sciences and Physical Engineering, Czech Technical University in Prague, Břehová 7, 115 19 Prague 1, Czech Republic
Institute of Physics, Faculty of Mathematics and Physics, Charles University, Ke Karlovu 5, 121 16 Prague 2, Czech Republic
Author to whom correspondence should be addressed.
Nanomaterials 2019, 9(10), 1426;
Received: 20 September 2019 / Revised: 6 October 2019 / Accepted: 8 October 2019 / Published: 9 October 2019
(This article belongs to the Special Issue Computational and Spectroscopic Studies on Metal Nanoparticles)
Surface-enhanced Raman scattering (SERS) sensors are constructed from metallic plasmonic nanostructures providing high sensitivity and spectral reproducibility. In many cases, irradiation of the SERS substrate by the laser beam leads to an increase of the local temperature and consequently to thermal degradation of metallic nanostructure itself and/or adsorbed analyte. We report here a “bottom-up” technique to fabricate new thermally resistant gold “film over nanosphere” (FON) substrates for SERS. We elaborated the simple and straightforward method of preparation of homogeneously and closely packed monolayer of SiO2 nanoparticles (50 nm in diameter) and covered it by a thin (20 nm) layer of magnetron-sputtered gold. The spectral testing using biologically important molecules (methylene blue, cationic porphyrin, and fungicide 1-methyl-1H-benzimidazole-2-thiol) proved a sensitivity and reproducibility of our AuSiO2 substrates. The main advantage of such SERS-active substrates is high thermal stability and low intensity of background and signal of graphitic carbon. View Full-Text
Keywords: SERS; AuFON; reproducibility; SiO2; thermal resistance SERS; AuFON; reproducibility; SiO2; thermal resistance
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Kouba, K.; Proška, J.; Procházka, M. Gold Film over SiO2 Nanospheres—New Thermally Resistant Substrates for Surface-Enhanced Raman Scattering (SERS) Spectroscopy. Nanomaterials 2019, 9, 1426.

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