Nanostructuring Effect of Nano-CeO2 Particles Reinforcing Cobalt Matrix during Electrocodeposition Process
Abstract
:1. Introduction
2. Materials and Methods
3. Results
3.1. Layer Systems Obtained by Electrocodeposition
3.2. Structural Characterization of Nanocomposite Layers by XRD
3.3. Nanostructuring Effect of Nano-CeO2 Particles Embedded into the Cobalt Matrix
3.4. Surface Wettability and Roughness Characterization
3.5. Correlation between Crystallite Size Dimensions of Nanocomposite Layers and Wettability
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Characteristics | Technical Specifications |
---|---|
Molecular mass | 172.11 g/mol |
Color | White-pale, yellow pal |
Morphology | Nanopowder |
The specific size of the surface | 35–55 m2/g |
Particle size | <25 nm |
Density at 20 °C | 7.22 g/cm2 |
Melting point | 2340 °C |
Boiling point | 3500 °C |
Amount of Dispersed Nano-CeO2 Added to Plating Electrolyte | Current Density | Amount of Dispersed Nano-CeO2 Added to Plating Electrolyte |
---|---|---|
0 g/L CeO2 | 23 | 0 |
48 | 0 | |
72 | 0 | |
10 g/L CeO2 | 23 | 6.81 ± 0.2 |
48 | 4.65 ± 0.3 | |
72 | 3.35 ± 0.1 | |
20 g/L CeO2 | 23 | 15.0 ± 0.4 |
48 | 9.70 ± 0.1 | |
72 | 6.40 ± 0.2 | |
30 g/L CeO2 | 23 | 20.0 ± 0.1 |
48 | 17.11 ± 0.2 | |
72 | 12.22 ± 0.3 |
Surface Studied | Current Density [mA/cm2] | Ra [µm] |
---|---|---|
Pure Co layer (0% CeO2) | 23 | 0.142 ± 0.002 |
48 | 0.207 ± 0.004 | |
72 | 0.297 ± 0.001 | |
Co/nano-CeO2—10 g/L layer (6.81, 4.65, and 3.35 wt. %) | 23 | 0.346 ± 0.006 |
48 | 0.421 ± 0.003 | |
72 | 0.504 ± 0.005 | |
Co/nano-CeO2—20 g/L layer (15, 9.70, and 6.40 wt. %) | 23 | 0.609 ± 0.001 |
48 | 0.693 ± 0.003 | |
72 | 0.755 ± 0.009 | |
Co/nano-CeO2—30 g/L layer (20, 17.11, and 12.22 wt. %) | 23 | 0.849 ± 0.004 |
48 | 0.991 ± 0.007 | |
72 | 1.233 ± 0.003 |
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Nicoleta, B.; Lidia, B.; Daniela-Laura, B.; Vasile, B.; Jean-Pierre, C. Nanostructuring Effect of Nano-CeO2 Particles Reinforcing Cobalt Matrix during Electrocodeposition Process. Nanomaterials 2022, 12, 2923. https://doi.org/10.3390/nano12172923
Nicoleta B, Lidia B, Daniela-Laura B, Vasile B, Jean-Pierre C. Nanostructuring Effect of Nano-CeO2 Particles Reinforcing Cobalt Matrix during Electrocodeposition Process. Nanomaterials. 2022; 12(17):2923. https://doi.org/10.3390/nano12172923
Chicago/Turabian StyleNicoleta, Bogatu, Benea Lidia, Buruiană Daniela-Laura, Bașliu Vasile, and Celis Jean-Pierre. 2022. "Nanostructuring Effect of Nano-CeO2 Particles Reinforcing Cobalt Matrix during Electrocodeposition Process" Nanomaterials 12, no. 17: 2923. https://doi.org/10.3390/nano12172923