Application of Quantum Dot Interface Modification Layer in Perovskite Solar Cells: Progress and Perspectives
Abstract
:1. Introduction
2. Structure of PSCs
3. Introduction of QDs
4. QD-Modified Interface Layer
4.1. QD-Modified Perovskite/ETL Interface
4.1.1. CQD-Modified Perovskite/ETL Interface
4.1.2. GQD-Modified Perovskite/ETL Interface
4.1.3. PQD-Modified Perovskite/ETL Interface
4.1.4. Other-QD-Modified Perovskite/ETL Interface
4.2. QD-Modified Perovskite/HTL Interface
4.2.1. CQD- and GQD-Modified Perovskite/HTL Interface
4.2.2. PQD-Modified Perovskite/HTL Interface
4.2.3. Other-QD-Modified Perovskite/HTL Interface
QDs | Size | Device Structure | Voc | Jsc | FF % | PCE % | Ref. |
---|---|---|---|---|---|---|---|
CdTe | 10~20 nm | ITO/SnO2/FA0.57MA0.43PbIxBryCl3−x−y/ CdTe QDs/Spiro-OMeTAD/Au | 1.05 | 23.46 | 72 | 17.87 | [120] |
CdSe/CsPbI3 | ~3 nm | FTO/TiO2/MAPbI3/ CdSe/CsPbI3 QDs/ Spiro-OMeTAD/Au | 0.976 | 24.60 | 71 | 17.10 | [121] |
MoS2 | ~2.6 nm | FTO/c-TiO2/m-TiO2/MAPbI3/MoS2 QDs:Reduced graphene oxide/ Spiro-OMeTAD/Au | 1.11 | 22.81 | 80 | 20.12 | [115] |
PbS | ~3.4 nm | FTO/c-TiO2/MAPbI3/PbS QDs/ Spiro-OMeTAD/Au | 1.14 | 23.17 | 72.83 | 19.24 | [113] |
PbSO4(PbO)4 | 2~5 nm | FTO/c-TiO2/m-TiO2/CH3NH3PbI3/ PbSO4(PbO)4 QDs/ Spiro-OMeTAD/Au | 1.10 | 24.27 | 75 | 20.02 | [123] |
Black Phosphorus | ~5.2 nm | ITO/PEDOT:PSS/BP QDs/MAPbI3/PCBM/Ag | 1.01 | 20.13 | 80 | 16.69 | [122] |
5. Summary
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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QDs | Size | Device Structure | Voc | Jsc | FF % | PCE % | Ref. |
---|---|---|---|---|---|---|---|
CQDs | ~ | FTO/c-TiO2/m-TiO2/CQDs/ CsPbBr3/carbon:PtNi NWS | 1.43 | 6.78 | 80.9 | 7.86 | [76] |
GQDs | ~5 nm | FTO/c-TiO2/m-TiO2/ GQDs/CsPbBr3/Carbon | 1.46 | 8.12 | 82 | 9.72 | [26] |
GQDs | 5~10 nm | FTO/c-TiO2/m-TiO2/GQDs/ MAPbI3/Spiro-OMeTAD/Au | 0.94 | 17.06 | 64 | 10.15 | [24] |
GQDs | 7~14 nm | FTO/c-TiO2/GQDs/MAPbI3/ Spiro-OMeTAD/Au | 1.12 | 22.47 | 76 | 19.11 | [25] |
GQDs | ~ | FTO/SnO2/GQDs/MAPbI3/ Spiro-OMeTAD/Au | 1.03 | 23.36 | 68 | 16.54 | [27] |
NSGQDS | ~3 nm | FTO/α-Fe2O3/NSGQDs/ MAPbI3:NSGQDs/ NSGQDs/Spiro-OMeTAD/Au | 1.03 | 23.50 | 79 | 19.20 | [78] |
I-GQDs | 10 nm | ITO/SnO2/I-GQDs/FAPbI3/ PCBM:C60/Ag | 1.073 | 25.42 | 82 | 22.37 | [79] |
UC GQDs | 4~4.5 nm | FTO/CuI/ Cs0.05(MA0.17FA0.83)0.95Pb(I0.83Br0.17)3/ UC GQDs/PCBM/Au | 1.15 | 20.99 | 82 | 19.79 | [80] |
Graphdiyne | 3~5 nm | FTO/TiO2/GD QDs/CH3NH3PbI3:GD QDS/Spiro-OMeTAD:GD QDs/Au | 1.12 | 22.48 | 79 | 19.89 | [83] |
Graphite carbon nitride | 10~30 nm | FTO/SnO2/Graphite carbon nitride QDs/CsxMAyFA1−x−yPbIzBr3−z/ Spiro-OMeTAD/Au | 1.14 | 23.39 | 80 | 21.23 | [77] |
QDs | Size | Device Structure | Voc | Jsc | FF % | PCE % | Ref. |
---|---|---|---|---|---|---|---|
CsPbI3 | ~10 nm | ITO/PTAA/ Cs0.05(FA0.83MA0.17)0.95Pb(I0.83Br0.17)3 /CsPbI3 QDs/C60/BCP/Cu | 1.15 | 22.90 | 78 | 20.60 | [86] |
CsPbBr3 | ~18 nm | ITO/PTAA/ Cs0.05(FA0.83MA0.17)0.95Pb(I0.83Br0.17)3 /CsPbBr3 QDs/C60/BCP/Cu | 1.19 | 22.95 | 77 | 21.03 | [85] |
CsPbBrCl2 | ~7 nm | ITO/PTAA/MAPbI3/CsPbBrCl2 QDs/ C60/BCP/Copper | 1.15 | 23.40 | 80 | 21.5 | [84] |
QDs | Size | Device Structure | Voc | Jsc | FF % | PCE % | Ref. |
---|---|---|---|---|---|---|---|
PbS | 5 nm | FTO/TiO2/PbS QDs/CH3NH3PbI3/P3HT/Pt | 0.88 | 6.30 | 49.3 | 4.92 | [87] |
CdS | 4~5 nm | ITO/m-TiO2/CdS QDs/MAPbI3/ Spiro-OMeTAD/Au | 0.94 | 16.86 | 64 | 10.52 | [93] |
CdS | 5 nm | FTO/c-TiO2/CdS QDs/MAPbI3/ Spiro-OMeTAD/Au | 0.95 | 20.6 | 54 | 13.2 | [94] |
CdSe | 2.4~3.5 nm | ITO/c-TiO2/m-TiO2/CdSe QDs/MAPbI3/ Spiro-OMeTAD/Au | 1.08 | 20.57 | 70 | 15.68 | [99] |
CdSe@ZnS | 6~7 nm | ITO/PEDOT:PSS/MAPbI3/CdSe@ZnS QDs/C60/BCP/Ag | 1.08 | 23.5 | 77 | 19.6 | [95] |
CuInS2 | 3~5 nm | ITO/TiO2 nanorod arrays/CuInS2 QDs/ MAPbI3/Spiro-OMeTAD/Au | 0.98 | 17.60 | 69 | 11.70 | [96] |
CuInS2 | 1~3 nm | FTO/TiO2/CuInS2 QDs/MAPbI3/ Spiro-OMeTAD/Au | 0.98 | 19.2 | 71 | 13.3 | [97] |
NaYF4:Yb/Er | 16.3 nm | FTO/c-TiO2/NaYF4:Yb/Er QDs/CH3NH3PbI3/ Spiro-OMeTAD/Ag | 1.06 | 23.1 | 73.8 | 18.1 | [98] |
QDs | Size | Device Structure | Voc | Jsc | FF % | PCE % | Ref. |
---|---|---|---|---|---|---|---|
CQDs | ~20 nm | FTO/c-TiO2/m-TiO2/ CsPbBr3/CQDs/ Spiro-OMeTAD/Ag | 1.06 | 11.34 | 69 | 8.29 | [100] |
E-g-C3N4 | 20~50 nm | FTO/c-TiO2/CH3NH3PbI3/E-g-C3N4 QDs/Spiro-OMeTAD/Au | 1.10 | 23.2 | 62 | 15.8 | [101] |
Hydrophobic GQDs | 7 nm | ITO/SnO2/CH3NH3PbI3/HGQDs/ Spiro-OMeTAD/Au | 1.10 | 22.27 | 75 | 18.30 | [102] |
QDs | Size | Device Structure | Voc | Jsc | FF % | PCE % | Ref. |
---|---|---|---|---|---|---|---|
CsPbBrI2 | 15~20 nm | FTO/TiO2/CsPbBrI2/CsPbBrI2 NSs/CsPbBrI2 QDs/PTAA/Au | 1.19 | 12.93 | 80.5 | 12.39 | [108] |
CsPbBrI2 | 10~15 nm | FTO/c-TiO2/CsPbBrI2/ CsPbBrI2 QDs/PTAA/Au | 1.22 | 14.51 | 79.6 | 14.12 | [112] |
CsPbBr3 | ~7.5 nm | ITO/SnO2/MAPbI3/CsPbBr3 QDs/Spiro-OMeTAD/Au | 1.11 | 23.57 | 76.88 | 20.17 | [111] |
CsPbI3 | 9~13 nm | FTO/c-TiO2/m-TiO2/ MA0.17FA0.83Pb(I0.83Br0.17)3/ CsPbI3 QDs/Spiro-OMeTAD/Au | 1.09 | 24.42 | 69.72 | 18.56 | [105] |
Mn-CsPbI3 | 15~20 nm | FTO/c-TiO2/CsPbI2Br/Mn-CsPbI3 QDs/PTAA/Au | 1.20 | 14.45 | 78.7 | 14.45 | [104] |
Cs0.57FA0.43PbI3 | 10.7 nm | FTO/SnO2/FAPbI3/Cs0.57FA0.43PbI3 QDs/Spiro-OMeTAD/Au | 1.12 | 24.44 | 76 | 20.82 | [110] |
CsPbBr1.85I1.15 | ~10 nm | FTO/c-TiO2/m-TiO2/ Cs0.05(FA0.85MA0.15)0.95Pb(I0.85Br0.15)3/CsPbBr1.85I1.15 QDs/ Spiro-OMeTAD/Au | 1.14 | 23.42 | 79 | 21.14 | [109] |
MAPbBr0.9I2.1 | ~5 nm | FTO/c-TiO2/MAPbI3/ MAPbBr0.9I2.1 QDs/ Spiro-OMeTAD/Cr/Au | 0.95 | 19.51 | 72 | 13.32 | [103] |
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Zhou, Y.; Luo, X.; Yang, J.; Qiu, Q.; Xie, T.; Liang, T. Application of Quantum Dot Interface Modification Layer in Perovskite Solar Cells: Progress and Perspectives. Nanomaterials 2022, 12, 2102. https://doi.org/10.3390/nano12122102
Zhou Y, Luo X, Yang J, Qiu Q, Xie T, Liang T. Application of Quantum Dot Interface Modification Layer in Perovskite Solar Cells: Progress and Perspectives. Nanomaterials. 2022; 12(12):2102. https://doi.org/10.3390/nano12122102
Chicago/Turabian StyleZhou, Yankai, Xingrui Luo, Jiayan Yang, Qingqing Qiu, Tengfeng Xie, and Tongxiang Liang. 2022. "Application of Quantum Dot Interface Modification Layer in Perovskite Solar Cells: Progress and Perspectives" Nanomaterials 12, no. 12: 2102. https://doi.org/10.3390/nano12122102