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Communication

Boosting Photovoltaic Performance in Organic Solar Cells by Manipulating the Size of MoS2 Quantum Dots as a Hole-Transport Material

1
Division of Advanced Materials Engineering, Kongju National University, Cheonan-si 32588, Korea
2
Nano Hybrid Technology Research Center, Korea Electrotechnology Research Institute, 12 Jeongiui-gil, Seongsan-gu, Changwon-si 51543, Korea
3
Department of Chemical Engineering, Sunchon National University, 255 Jungang-Ro, Suncheon-si 57922, Korea
*
Author to whom correspondence should be addressed.
Nanomaterials 2021, 11(6), 1464; https://doi.org/10.3390/nano11061464
Submission received: 16 April 2021 / Revised: 24 May 2021 / Accepted: 27 May 2021 / Published: 1 June 2021

Abstract

The design of photoactive materials and interface engineering between organic/inorganic layers play a critical role in achieving enhanced performance in energy-harvesting devices. Two-dimensional transitional dichalcogenides (TMDs) with excellent optical and electronic properties are promising candidates in this regard. In this study, we demonstrate the fabrication of size-controlled MoS2 quantum dots (QDs) and present fundamental studies of their optical properties and their application as a hole-transport layer (HTL) in organic solar cells (OSCs). Optical and structural analyses reveal that the as-prepared MoS2 QDs show a fluorescence mechanism with respect to the quantum confinement effect and intrinsic/extrinsic states. Moreover, when incorporated into a photovoltaic device, the MoS2 QDs exhibit a significantly enhanced performance (5/10-nanometer QDs: 8.30%/7.80% for PTB7 and 10.40%/10.17% for PTB7-Th, respectively) compared to those of the reference device (7.24% for PTB7 and 9.49% for PTB7-Th). We confirm that the MoS2 QDs clearly offer enhanced transport characteristics ascribed to higher hole-mobility and smoother root mean square (Rq) as a hole-extraction material. This approach can enable significant advances and facilitate a new avenue for realizing high-performance optoelectronic devices.
Keywords: quantum dot; transition metal dichalcogenide; hole-transport layer; polymer solar cells; conventional structure quantum dot; transition metal dichalcogenide; hole-transport layer; polymer solar cells; conventional structure

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MDPI and ACS Style

Park, K.H.; Jung, S.; Kim, J.; Ko, B.-M.; Shim, W.-G.; Hong, S.-J.; Song, S.H. Boosting Photovoltaic Performance in Organic Solar Cells by Manipulating the Size of MoS2 Quantum Dots as a Hole-Transport Material. Nanomaterials 2021, 11, 1464. https://doi.org/10.3390/nano11061464

AMA Style

Park KH, Jung S, Kim J, Ko B-M, Shim W-G, Hong S-J, Song SH. Boosting Photovoltaic Performance in Organic Solar Cells by Manipulating the Size of MoS2 Quantum Dots as a Hole-Transport Material. Nanomaterials. 2021; 11(6):1464. https://doi.org/10.3390/nano11061464

Chicago/Turabian Style

Park, Kwang Hyun, Sunggyeong Jung, Jungmo Kim, Byoung-Min Ko, Wang-Geun Shim, Soon-Jik Hong, and Sung Ho Song. 2021. "Boosting Photovoltaic Performance in Organic Solar Cells by Manipulating the Size of MoS2 Quantum Dots as a Hole-Transport Material" Nanomaterials 11, no. 6: 1464. https://doi.org/10.3390/nano11061464

APA Style

Park, K. H., Jung, S., Kim, J., Ko, B.-M., Shim, W.-G., Hong, S.-J., & Song, S. H. (2021). Boosting Photovoltaic Performance in Organic Solar Cells by Manipulating the Size of MoS2 Quantum Dots as a Hole-Transport Material. Nanomaterials, 11(6), 1464. https://doi.org/10.3390/nano11061464

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