Composite Nanostructure of Manganese Cluster and CHA-Type Silicoaluminaphosphates: Enhanced Catalytic Performance in Dimethylether to Light Olefins Conversion
Abstract
:1. Introduction
2. Experimental
2.1. Chemicals
2.2. Preparation of MnNC@SAPO-34 Catalysts
2.3. Characterization
2.4. Catalytic Evaluation in the DTO Reaction
3. Results and Discussion
3.1. Synthesis and Characterization of the MnNC@SAPO-34 Catalysts
3.2. Catalytic Performance of the Catalysts
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Sample | Physical Structures | Acid Density (mmol/g) | |||||
---|---|---|---|---|---|---|---|
SBET (cm2/g) a | Vtotal (cm3/g) b | Vmic (cm3/g) c | Vmes (cm3/g) d | Dpore (nm) e | Weak Acid Site | Strong Acid Site | |
SAPO-34 | 188.40 | 0.12 | 0.08 | 0.04 | 6.1 | 0.415 | 0.702 |
MnNC@SAPO-34 | 150.26 | 0.12 | 0.06 | 0.06 | 12.1 | 0.568 | 0.953 |
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Ping, G.; Zheng, K.; Fang, Q.; Li, G. Composite Nanostructure of Manganese Cluster and CHA-Type Silicoaluminaphosphates: Enhanced Catalytic Performance in Dimethylether to Light Olefins Conversion. Nanomaterials 2021, 11, 24. https://doi.org/10.3390/nano11010024
Ping G, Zheng K, Fang Q, Li G. Composite Nanostructure of Manganese Cluster and CHA-Type Silicoaluminaphosphates: Enhanced Catalytic Performance in Dimethylether to Light Olefins Conversion. Nanomaterials. 2021; 11(1):24. https://doi.org/10.3390/nano11010024
Chicago/Turabian StylePing, Guichen, Kai Zheng, Qihua Fang, and Gao Li. 2021. "Composite Nanostructure of Manganese Cluster and CHA-Type Silicoaluminaphosphates: Enhanced Catalytic Performance in Dimethylether to Light Olefins Conversion" Nanomaterials 11, no. 1: 24. https://doi.org/10.3390/nano11010024
APA StylePing, G., Zheng, K., Fang, Q., & Li, G. (2021). Composite Nanostructure of Manganese Cluster and CHA-Type Silicoaluminaphosphates: Enhanced Catalytic Performance in Dimethylether to Light Olefins Conversion. Nanomaterials, 11(1), 24. https://doi.org/10.3390/nano11010024