Calcium Sulfate and Calcium Carbonate Scaling of Thin-Film Composite Polyamide Reverse Osmosis Membranes with Surface-Tethered Polyacrylic Acid Chains
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Atmospheric-Pressure-Induced Graft Polymerization (APPIGP)
2.3. Surface Scanning Images
2.4. Membrane Performance Characterization
2.4.1. Permeability
2.4.2. Mineral Scaling Tests
3. Results and Discussion
3.1. Membrane Scaling
3.2. Membrane Cleaning and Water Permeability Recovery
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
Appendix A
References
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Membrane (b) | Permeability (c) (L·m−1·h−1·bar−1) | Rejection (d) (%) | |
---|---|---|---|
Observed | Intrinsic | ||
SNS-PAA-PA | 1.69 | 99.3 | 99.5 |
Toray SWRO | 1.33 | 99.0 | 99.2 |
Base-PA | 2.91 | 99.0 | 99.3 |
Dow SW30 | 1.60 | 89.9 | 99.2 |
Ions | Model Solution Composition (a) | |
---|---|---|
Calcium Sulfate | Calcium Carbonate | |
Ca2+ | 11.29 mM | 11.29 mM |
Na+ | 127.95 mM | 160.33 mM |
Cl− | 33.67 mM | 178.89 mM |
SO42− | 58.43 mM | - |
HCO3− | - | 4.02 mM |
pH | 5.7 | 7.9 |
TDS | 2611 mg/L | 2611 mg/L |
Saturation index in solution (b) | SIg = 1.0 | SIc = 6.3 |
Saturation index at membrane surface (c) | SIg,m = 1.7 | SIc,m = 10.6 |
Membrane | Scalant | J/Jo (b) | Lp/Lp,o (c) |
---|---|---|---|
SNS-PAA-PA | Gypsum | 0.89 | 1.00 |
Dow SW30 | Gypsum | 0.81 | 1.00 |
Toray SWRO | Gypsum | 0.84 | 0.98 |
Base-PA | Gypsum | 0.85 | 0.92 |
SNS-PAA-PA | Calcite | 0.85 | 0.94 |
Dow SW30 | Calcite | 0.80 | 1.00 |
Toray SWRO | Calcite | 0.83 | 1.00 |
Base-PA | Calcite | 0.79 | 1.00 |
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Chen, Y.; Cohen, Y. Calcium Sulfate and Calcium Carbonate Scaling of Thin-Film Composite Polyamide Reverse Osmosis Membranes with Surface-Tethered Polyacrylic Acid Chains. Membranes 2022, 12, 1287. https://doi.org/10.3390/membranes12121287
Chen Y, Cohen Y. Calcium Sulfate and Calcium Carbonate Scaling of Thin-Film Composite Polyamide Reverse Osmosis Membranes with Surface-Tethered Polyacrylic Acid Chains. Membranes. 2022; 12(12):1287. https://doi.org/10.3390/membranes12121287
Chicago/Turabian StyleChen, Yian, and Yoram Cohen. 2022. "Calcium Sulfate and Calcium Carbonate Scaling of Thin-Film Composite Polyamide Reverse Osmosis Membranes with Surface-Tethered Polyacrylic Acid Chains" Membranes 12, no. 12: 1287. https://doi.org/10.3390/membranes12121287