Vanadium and Cobalt Occurrence in the Fe-Ti-V Oxide Deposits Related to Mesoproterozoic AMCG Complex in NE Poland
Abstract
:1. Introduction
2. Geological Setting
2.1. Regional Geology
2.2. Geology of Fe-Ti-V Oxide Deposits
2.2.1. The Krzemianka Fe-Ti-V Oxide Deposit
2.2.2. The Udryn Fe-Ti-V Oxide Deposit and Other Prospects
3. Analytical Methods
3.1. The Whole-Rock Geochemistry
3.2. The Ore Microscope and Microprobe Studies
4. Results
4.1. Metallic Mineralization in Light of the Microscopic and EPMA Studies
4.2. Trace Element Distribution in Fe-Ti-Oxides and Sulphides Mineralization Determined by EPMA
4.3. Bulk-Rock Geochemical Investigation of Fe-Ti-V Oxide and Sulphide Ores
5. Discussion
5.1. Genetic Implications for Vanadium and Cobalt Occurrence in the SAM
5.2. Economic Potential of Vanadium and Cobalt in the SAM
6. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
Appendix A
Analytical Point | Fe | Al | Mn | V | Cr | Mg | Ti | O | Total | Fe/Ti | Al + V + Cr | Mg + Mn |
---|---|---|---|---|---|---|---|---|---|---|---|---|
KR-24_03_obsz-01_fot-1.1 | 70.436 | 0.285 | 0.027 | 0.324 | 0.16 | 0.068 | 1.006 | 21.394 | 93.751 | 70.0 | 0.769 | 0.095 |
KR-24_03_obsz-01_fot-1.2 | 69.954 | 0.338 | 0.015 | 0.326 | 0.116 | 0.104 | 1.065 | 21.359 | 93.349 | 65.7 | 0.78 | 0.119 |
KR-24_03_obsz-01_fot-1.3 | 70.587 | 0.261 | 0.025 | 0.43 | 0.119 | 0.07 | 0.303 | 20.985 | 92.817 | 233.0 | 0.81 | 0.095 |
KR-24_03_obsz-01_fot-1.4 | 69.974 | 0.402 | 0.052 | 0.453 | 0.175 | 0.109 | 0.468 | 21.108 | 92.783 | 149.5 | 1.03 | 0.161 |
KR-24_03_obsz-03_fot-6.6 | 69.5 | 0.241 | 0.026 | 0.452 | 0.282 | 0.056 | 1.089 | 21.271 | 93.042 | 63.8 | 0.975 | 0.082 |
KR-24_03_obsz-03_fot-6.7 | 69.64 | 0.238 | 0.019 | 0.377 | 0.258 | 0.046 | 1.055 | 21.224 | 92.959 | 66.0 | 0.873 | 0.065 |
KR-24_03_obsz-03_fot-6.8 | 70.639 | 0.334 | 0.033 | 0.477 | 0.112 | 0.066 | 0.31 | 21.1 | 93.165 | 227.9 | 0.923 | 0.099 |
KR-24_03_obsz-03_fot-6.9 | 70.027 | 0.35 | 0.014 | 0.433 | 0.118 | 0.077 | 0.377 | 20.954 | 92.398 | 185.7 | 0.901 | 0.091 |
KR-24_03_obsz-03_fot-6.10 | 70.611 | 0.328 | 0.014 | 0.494 | 0.135 | 0.082 | 0.527 | 21.26 | 93.567 | 134.0 | 0.957 | 0.096 |
KRZ-56_02_obsz-01_fot-1.1 | 70.011 | 0.487 | 0.033 | 0.58 | 0.156 | 0.06 | 0.357 | 21.152 | 92.935 | 196.1 | 1.223 | 0.093 |
KRZ-56_02_obsz-01_fot-1.2 | 70.66 | 0.276 | b.d.l. | 0.481 | 0.125 | 0.039 | 0.144 | 20.912 | 92.676 | 490.7 | 0.882 | 0.039 |
KRZ-56_02_obsz-01_fot-1.3 | 70.883 | 0.51 | 0.011 | 0.498 | 0.116 | 0.075 | 0.162 | 21.26 | 93.683 | 437.5 | 1.124 | 0.086 |
KRZ-56_02_obsz-01_fot-2.6 | 72.198 | 0.238 | 0.005 | 0.55 | 0.09 | 0.021 | 0.074 | 21.272 | 94.483 | 975.6 | 0.878 | 0.026 |
KRZ-56_02_obsz-01_fot-2.7 | 72.164 | 0.186 | b.d.l. | 0.505 | 0.125 | 0.025 | 0.261 | 21.373 | 94.863 | 276.5 | 0.816 | 0.025 |
KRZ-56_02_obsz-01_fot-2.8 | 72.002 | 0.229 | 0.014 | 0.515 | 0.142 | 0.033 | 0.145 | 21.289 | 94.442 | 496.6 | 0.886 | 0.047 |
KRZ-56_02_obsz-01_fot-2.9 | 71.958 | 0.24 | 0.035 | 0.507 | 0.106 | 0.03 | 0.296 | 21.392 | 94.734 | 243.1 | 0.853 | 0.065 |
KRZ-56_02_obsz-01_fot-2.10 | 71.627 | 0.48 | 0.037 | 0.542 | 0.091 | 0.075 | 0.163 | 21.443 | 94.527 | 439.4 | 1.113 | 0.112 |
KR-63_05_obsz-02_fot-1.3 | 71.136 | 0.252 | 0.018 | 0.572 | 0.159 | 0.053 | 0.249 | 21.169 | 93.675 | 285.7 | 0.983 | 0.071 |
KR-63_05_obsz-02_fot-1.4 | 71.634 | 0.18 | 0.012 | 0.584 | 0.122 | 0.025 | 0.116 | 21.139 | 93.927 | 617.5 | 0.886 | 0.037 |
KR-63_05_obsz-03_fot-1.1 | 71.659 | 0.161 | 0.008 | 0.579 | 0.147 | 0.07 | 0.161 | 21.179 | 94.007 | 445.1 | 0.887 | 0.078 |
KR-63_05_obsz-03_fot-1.2 | 70.406 | 0.484 | 0.016 | 0.576 | 0.126 | 0.157 | 0.485 | 21.372 | 93.649 | 145.2 | 1.186 | 0.173 |
KR-63_05_obsz-03_fot-1.3 | 71.237 | 0.175 | 0.001 | 0.557 | 0.125 | 0.048 | 0.238 | 21.091 | 93.54 | 299.3 | 0.857 | 0.049 |
KR-63_05_obsz-04_fot-1.5 | 68.297 | 1.903 | 0.051 | 0.557 | 0.145 | 0.534 | 0.416 | 22.244 | 94.19 | 164.2 | 2.605 | 0.585 |
KR-63_05_obsz-04_fot-1.6 | 70.304 | 0.619 | 0.019 | 0.57 | 0.169 | 0.219 | 0.525 | 21.568 | 94.126 | 133.9 | 1.358 | 0.238 |
KR-63_05_obsz-05_fot-1.10 | 71.631 | 0.231 | 0.034 | 0.583 | 0.135 | 0.088 | 0.15 | 21.268 | 94.269 | 477.5 | 0.949 | 0.122 |
KR-63_05_obsz-05_fot-1.11 | 70.069 | 0.573 | 0.007 | 0.556 | 0.129 | 0.194 | 0.381 | 21.309 | 93.287 | 183.9 | 1.258 | 0.201 |
KR-63_05_obsz-05_fot-1.12 | 70.988 | 0.458 | b.d.l. | 0.532 | 0.159 | 0.154 | 0.164 | 21.297 | 93.789 | 432.9 | 1.149 | 0.154 |
KR-63_05_obsz-08_fot-1.5 | 71.235 | 0.197 | 0.017 | 0.588 | 0.129 | 0.061 | 0.185 | 21.117 | 93.649 | 385.1 | 0.914 | 0.078 |
KR-63_05_obsz-08_fot-1.6 | 70.437 | 0.446 | 0.015 | 0.569 | 0.103 | 0.15 | 0.263 | 21.19 | 93.223 | 267.8 | 1.118 | 0.165 |
KR-63_05_obsz-08_fot-1.7 | 71.57 | 0.266 | 0.013 | 0.57 | 0.154 | 0.092 | 0.189 | 21.318 | 94.304 | 378.7 | 0.99 | 0.105 |
UDR-7_01_obsz-01_fot-1.1 | 69.137 | 0.465 | 0.062 | 0.448 | 0.451 | 0.081 | 1.233 | 21.564 | 93.523 | 56.1 | 1.364 | 0.143 |
UDR-7_01_obsz-01_fot-1.2 | 69.962 | 0.294 | 0.027 | 0.416 | 0.456 | 0.038 | 1 | 21.434 | 93.719 | 70.0 | 1.166 | 0.065 |
UDR-7_01_obsz-01_fot-1.3 | 69.586 | 0.405 | 0.028 | 0.498 | 0.441 | 0.068 | 1.036 | 21.499 | 93.642 | 67.2 | 1.344 | 0.096 |
UDR-7_01_obsz-01_fot-1.4 | 69.769 | 0.498 | 0.019 | 0.523 | 0.442 | 0.092 | 0.916 | 21.582 | 93.934 | 76.2 | 1.463 | 0.111 |
UDR-7_01_obsz-01_fot-1.5 | 69.595 | 0.481 | 0.019 | 0.485 | 0.439 | 0.063 | 0.829 | 21.411 | 93.392 | 84.0 | 1.405 | 0.082 |
UDR-7_01_obsz-01_fot-1.6 | 69.702 | 0.412 | 0.075 | 0.471 | 0.488 | 0.072 | 1.216 | 21.688 | 94.174 | 57.3 | 1.371 | 0.147 |
UDR-7_01_obsz-01_fot-1.7 | 67.557 | 0.746 | 0.102 | 0.52 | 0.427 | 0.118 | 2.31 | 22.134 | 93.98 | 29.2 | 1.693 | 0.22 |
UDR-7_01_obsz-01_fot-1.8 | 68.033 | 0.593 | 0.08 | 0.495 | 0.449 | 0.076 | 2.268 | 22.082 | 94.222 | 30.0 | 1.537 | 0.156 |
UDR-7_01_obsz-01_fot-1.9 | 68.621 | 0.783 | 0.075 | 0.48 | 0.426 | 0.152 | 1.767 | 22.096 | 94.457 | 38.8 | 1.689 | 0.227 |
UDR-7_01_obsz-01_fot-1.10 | 69.937 | 0.425 | 0.048 | 0.465 | 0.444 | 0.068 | 0.892 | 21.517 | 93.883 | 78.4 | 1.334 | 0.116 |
UDR-7_01_obsz-02_fot-1.1 | 69.115 | 0.448 | 0.066 | 0.452 | 0.451 | 0.091 | 1.432 | 21.673 | 93.805 | 48.3 | 1.351 | 0.157 |
UDR-7_01_obsz-02_fot-1.2 | 68.396 | 0.914 | 0.051 | 0.516 | 0.472 | 0.21 | 1.627 | 22.121 | 94.356 | 42.0 | 1.902 | 0.261 |
UDR-7_01_obsz-02_fot-1.3 | 66.203 | 1.216 | 0.128 | 0.512 | 0.517 | 0.28 | 2.652 | 22.543 | 94.139 | 25.0 | 2.245 | 0.408 |
UDR-7_01_obsz-03_fot-1.1 | 68.706 | 0.415 | 0.053 | 0.475 | 0.439 | 0.084 | 1.484 | 21.56 | 93.246 | 46.3 | 1.329 | 0.137 |
UDR-7_01_obsz-03_fot-1.2 | 67.921 | 0.639 | 0.094 | 0.497 | 0.473 | 0.122 | 1.86 | 21.862 | 93.551 | 36.5 | 1.609 | 0.216 |
UDR-7_01_obsz-03_fot-1.3 | 67.283 | 0.656 | 0.1 | 0.462 | 0.453 | 0.123 | 2.297 | 21.946 | 93.363 | 29.3 | 1.571 | 0.223 |
UDR-10_3_obsz-03_fot-2.5 | 69.72 | 0.4 | 0.069 | 0.412 | 0.2 | 0.081 | 1.717 | 21.865 | 94.515 | 40.6 | 1.012 | 0.15 |
UDR-10_3_obsz-03_fot-2.6 | 67.932 | 0.686 | 0.1 | 0.459 | 0.235 | 0.219 | 2.552 | 22.293 | 94.551 | 26.6 | 1.38 | 0.319 |
UDR-10_3_obsz-03_fot-2.7 | 69.483 | 0.4 | 0.076 | 0.392 | 0.144 | 0.135 | 1.586 | 21.691 | 93.932 | 43.8 | 0.936 | 0.211 |
UDR-10_3_obsz-03_fot-2.8 | 69.964 | 0.44 | 0.1 | 0.458 | 0.236 | 0.149 | 1.426 | 21.851 | 94.682 | 49.1 | 1.134 | 0.249 |
UDR-10_3_obsz-03_fot-2.9 | 71.984 | 0.01 | b.d.l. | 0.006 | 0.006 | b.d.l. | 0.387 | 20.916 | 93.349 | 186.0 | 0.022 | b.d.l. |
DR-10_4_obsz-03_fot-1.5 | 69.612 | 0.272 | b.d.l. | 0.492 | 1.262 | 0.05 | 0.185 | 21.183 | 93.166 | 376.3 | 2.026 | 0.05 |
UDR-10_4_obsz-03_fot-1.6 | 69.668 | 0.428 | 0.031 | 0.462 | 0.744 | 0.058 | 0.285 | 21.156 | 92.868 | 244.4 | 1.634 | 0.089 |
UDR-10_4_obsz-04_fot-1.5 | 70.716 | 0.336 | 0.004 | 0.563 | 0.712 | 0.063 | 0.261 | 21.378 | 94.063 | 270.9 | 1.611 | 0.067 |
UDR-11_05_obsz-04_fot-1.5 | 71.428 | 0.198 | 0.009 | 0.245 | 0.016 | 0.038 | 0.059 | 20.856 | 92.907 | 1210.6 | 0.459 | 0.047 |
UDR-11_05_obsz-04_fot-1.6 | 71.334 | 0.171 | 0.014 | 0.22 | 0.025 | 0.028 | 0.22 | 20.924 | 93.078 | 324.2 | 0.416 | 0.042 |
UDR-11_06_obsz-02_fot-1.7 | 71.689 | 0.118 | b.d.l. | 0.153 | 0.023 | 0.033 | 0.094 | 20.851 | 93.049 | 762.6 | 0.294 | 0.033 |
UDR-11_06_obsz-02_fot-1.8 | 71.301 | 0.139 | 0.002 | 0.211 | 0.028 | 0.039 | 0.059 | 20.77 | 92.684 | 1208.5 | 0.378 | 0.041 |
UDR-11_06_obsz-02_fot-1.9 | 71.372 | 0.118 | 0.026 | 0.218 | 0.021 | 0.038 | 0.057 | 20.788 | 92.786 | 1252.1 | 0.357 | 0.064 |
UDR-11_06_obsz-02_fot-1.10 | 71.334 | 0.175 | b.d.l. | 0.188 | 0.061 | 0.048 | 0.066 | 20.84 | 92.88 | 1080.8 | 0.424 | 0.048 |
UDR-11_06_obsz-02_fot-1.11 | 70.858 | 0.232 | 0.041 | 0.2 | 0.034 | 0.042 | 0.102 | 20.766 | 92.39 | 694.7 | 0.466 | 0.083 |
UDR-11_06_obsz-04_fot-1.1 | 71.036 | 0.231 | 0.013 | 0.231 | 0.042 | 0.005 | 0.069 | 20.781 | 92.515 | 1029.5 | 0.504 | 0.018 |
UDR-11_06_obsz-04_fot-1.2 | 71.3 | 0.141 | b.d.l. | 0.225 | 0.018 | 0.037 | 0.026 | 20.76 | 92.65 | 2742.3 | 0.384 | 0.037 |
UDR-11_06_obsz-04_fot-1.3 | 71.144 | 0.21 | 0.006 | 0.21 | 0.051 | 0.041 | 0.064 | 20.825 | 92.697 | 1111.6 | 0.471 | 0.047 |
UDR-11_06_obsz-04_fot-1.4 | 71.397 | 0.123 | 0.002 | 0.262 | 0.033 | 0.016 | 0.056 | 20.791 | 92.855 | 1274.9 | 0.418 | 0.018 |
UDR-11_06_obsz-06_fot-1.1 | 70.791 | 0.172 | 0.013 | 0.214 | 0.051 | 0.028 | 0.062 | 20.659 | 92.072 | 1141.8 | 0.437 | 0.041 |
UDR-11_06_obsz-06_fot-1.2 | 71.377 | 0.166 | 0.023 | 0.232 | 0.048 | 0.011 | 0.113 | 20.858 | 92.937 | 631.7 | 0.446 | 0.034 |
Appendix B
Analytical Point | Fe | Al | Mn | V | Cr | Mg | Ti | O | Total | Fe/Ti | Al + V + Cr | Mn + Mg |
---|---|---|---|---|---|---|---|---|---|---|---|---|
KR-24_03_obsz-01_fot-1.5 | 34.816 | 0.023 | 0.687 | 0.151 | 0.027 | 1.029 | 31.097 | 31.771 | 99.727 | 1.12 | 0.201 | 1.716 |
KR-24_03_obsz-03_fot-6.11 | 33.898 | 0.03 | 1.179 | 0.16 | 0.006 | 0.897 | 31.864 | 32.056 | 100.191 | 1.06 | 0.196 | 2.076 |
KR-24_03_obsz-03_fot-6.12 | 34.182 | 0.017 | 0.832 | 0.147 | 0.037 | 1.053 | 31.891 | 32.162 | 100.388 | 1.07 | 0.201 | 1.885 |
KR-24_03_obsz-03_fot-6.13 | 34.43 | 0.026 | 0.72 | 0.149 | b.d.l. | 1.038 | 31.324 | 31.782 | 99.477 | 1.10 | 0.175 | 1.758 |
KRZ-56_02_obsz-01_fot-1.4 | 33.751 | 2.994 | 0.785 | 0.111 | 0.125 | 1.115 | 28.613 | 32.547 | 100.156 | 1.18 | 3.23 | 1.9 |
KRZ-56_02_obsz-01_fot-1.5 | 35.652 | 0.02 | 0.87 | 0.155 | 0.041 | 0.234 | 31.475 | 31.793 | 100.391 | 1.13 | 0.216 | 1.104 |
KRZ-56_02_obsz-01_fot-2.1 | 35.859 | 0.025 | 0.709 | 0.123 | 0.043 | 0.47 | 29.858 | 30.845 | 97.982 | 1.20 | 0.191 | 1.179 |
KRZ-56_02_obsz-01_fot-2.2 | 35.583 | 0.003 | 0.76 | 0.118 | 0.018 | 0.507 | 31.219 | 31.716 | 100.081 | 1.14 | 0.139 | 1.267 |
KR-63_05_obsz-02_fot-1.7 | 33.15 | 2.163 | 0.91 | 0.161 | 0.067 | 1.375 | 29.353 | 32.331 | 99.599 | 1.13 | 2.391 | 2.285 |
KR-63_05_obsz-02_fot-1.8 | 34.189 | 1.378 | 0.866 | 0.177 | 0.074 | 1.075 | 30.45 | 32.457 | 100.688 | 1.12 | 1.629 | 1.941 |
KR-63_05_obsz-03_fot-1.4 | 34.242 | 0.017 | 0.741 | 0.117 | b.d.l. | 1.284 | 31.416 | 31.95 | 99.839 | 1.09 | 0.134 | 2.025 |
KR-63_05_obsz-03_fot-1.5 | 35.033 | 0.027 | 0.645 | 0.111 | 0.022 | 1.226 | 31.196 | 31.984 | 100.332 | 1.12 | 0.16 | 1.871 |
KR-63_05_obsz-04_fot-1.4 | 34.668 | 0.026 | 0.719 | 0.091 | 0.036 | 1.194 | 31.272 | 31.932 | 100.062 | 1.11 | 0.153 | 1.913 |
KR-63_05_obsz-05_fot-1.6 | 33.937 | 1.186 | 0.896 | 0.166 | 0.082 | 1.352 | 29.661 | 31.888 | 99.261 | 1.14 | 1.434 | 2.248 |
KR-63_05_obsz-05_fot-1.7 | 34.769 | 0.038 | 0.813 | 0.143 | 0.042 | 1.037 | 30.583 | 31.45 | 98.931 | 1.14 | 0.223 | 1.85 |
KR-63_05_obsz-05_fot-1.8 | 34.142 | 0.017 | 0.727 | 0.081 | 0.033 | 1.366 | 31.603 | 32.076 | 100.058 | 1.08 | 0.131 | 2.093 |
KR-63_05_obsz-05_fot-1.9 | 33.966 | 0.025 | 0.722 | 0.113 | 0.019 | 1.3 | 31.214 | 31.753 | 99.173 | 1.09 | 0.157 | 2.022 |
KR-63_05_obsz-08_fot-1.1 | 35.008 | 0.024 | 0.66 | 0.125 | 0.003 | 1.127 | 30.302 | 31.318 | 98.699 | 1.16 | 0.152 | 1.787 |
KR-63_05_obsz-08_fot-1.2 | 34.613 | 0.015 | 0.718 | 0.12 | 0.012 | 1.168 | 31.365 | 31.953 | 100.038 | 1.10 | 0.147 | 1.886 |
KR-63_05_obsz-08_fot-1.3 | 35.232 | 0.018 | 0.703 | 0.141 | 0.016 | 1.208 | 30.875 | 31.818 | 100.052 | 1.14 | 0.175 | 1.911 |
KR-63_05_obsz-08_fot-1.4 | 35.008 | 0.032 | 0.661 | 0.132 | 0.019 | 1.211 | 30.839 | 31.755 | 99.77 | 1.14 | 0.183 | 1.872 |
UDR-7_01_obsz-02_fot-1.4 | 35.119 | b.d.l. | 0.712 | 0.113 | b.d.l | 0.803 | 31.191 | 31.721 | 99.782 | 1.13 | 0.113 | 1.515 |
UDR-7_01_obsz-02_fot-1.5 | 35.459 | 0.007 | 0.592 | 0.086 | 0.025 | 0.737 | 30.943 | 31.577 | 99.564 | 1.15 | 0.118 | 1.329 |
UDR-7_01_obsz-02_fot-1.6 | 35.309 | b.d.l. | 0.654 | 0.125 | b.d.l. | 0.651 | 31.45 | 31.848 | 100.177 | 1.12 | 0.125 | 1.305 |
UDR-7_01_obsz-02_fot-1.7 | 35.122 | 0.051 | 0.639 | 0.049 | 0.005 | 0.689 | 31.568 | 31.883 | 100.1 | 1.11 | 0.105 | 1.328 |
UDR-7_01_obsz-03_fot-1.4 | 35.19 | 0.038 | 0.974 | 0.152 | 0.051 | 0.373 | 30.946 | 31.439 | 99.259 | 1.14 | 0.241 | 1.347 |
UDR-7_01_obsz-03_fot-1.5 | 35.495 | 0.019 | 0.951 | 0.149 | 0.027 | 0.336 | 31.009 | 31.505 | 99.582 | 1.14 | 0.195 | 1.287 |
UDR-7_01_obsz-03_fot-1.6 | 35.526 | 0.011 | 1 | 0.083 | 0.028 | 0.369 | 31.096 | 31.561 | 99.733 | 1.14 | 0.122 | 1.369 |
UDR-10_3_obsz-03_fot-2.1 | 34.103 | 0.025 | 0.641 | 0.1 | 0.04 | 1.63 | 31.384 | 32.11 | 100.084 | 1.09 | 0.165 | 2.271 |
UDR-10_3_obsz-03_fot-2.2 | 33.651 | 0.017 | 0.641 | 0.122 | 0.007 | 1.603 | 31.745 | 32.176 | 100.029 | 1.06 | 0.146 | 2.244 |
UDR-10_3_obsz-03_fot-2.3 | 34.205 | 0.045 | 0.596 | 0.13 | b.d.l. | 1.631 | 31.516 | 32.21 | 100.379 | 1.09 | 0.175 | 2.227 |
UDR-10_3_obsz-03_fot-2.4 | 33.959 | 0.02 | 0.685 | 0.072 | 0.015 | 1.659 | 31.636 | 32.245 | 100.436 | 1.07 | 0.107 | 2.344 |
UDR-10_4_obsz-03_fot-1.3 | 35.145 | 0.026 | 0.763 | 0.164 | 0.033 | 0.56 | 31.681 | 31.941 | 100.318 | 1.11 | 0.223 | 1.323 |
UDR-10_4_obsz-03_fot-1.4 | 34.935 | 0.202 | 0.724 | 0.138 | 0.082 | 0.631 | 31.478 | 31.96 | 100.21 | 1.11 | 0.422 | 1.355 |
UDR-10_4_obsz-04_fot-1.9 | 35.536 | 0.119 | 0.954 | 0.172 | 0.073 | 0.411 | 31.27 | 31.854 | 100.448 | 1.14 | 0.364 | 1.365 |
UDR-10_4_obsz-04_fot-1.10 | 34.149 | 4.388 | 0.81 | 0.122 | 0.586 | 1.189 | 26.678 | 32.885 | 100.889 | 1.28 | 5.096 | 1.999 |
UDR-10_4_obsz-01_fot-1.5 | 35.32 | 0.01 | 0.776 | 0.141 | 0.027 | 0.392 | 31.523 | 31.764 | 99.999 | 1.12 | 0.178 | 1.168 |
UDR-10_4_obsz-01_fot-1.6 | 35.792 | 0.018 | 0.688 | 0.112 | b.d.l. | 0.52 | 31.344 | 31.822 | 100.358 | 1.14 | 0.13 | 1.208 |
UDR-11_04_obsz-02_fot-2.11 | 36.507 | 0.03 | 0.928 | 0.18 | 0.027 | 0.646 | 30.642 | 31.789 | 100.875 | 1.19 | 0.237 | 1.574 |
UDR-11_04_obsz-01_fot-4.11 | 37.156 | 0.02 | 0.881 | 0.181 | b.d.l. | 0.736 | 30.086 | 31.624 | 100.793 | 1.23 | 0.201 | 1.617 |
UDR-11_04_obsz-01_fot-4.12 | 38.197 | 0.03 | 0.867 | 0.174 | 0.016 | 0.697 | 28.812 | 31.05 | 99.937 | 1.33 | 0.22 | 1.564 |
UDR-11_05_obsz-01_fot-1.7 | 37.282 | 0.026 | 0.851 | 0.15 | 0.026 | 0.647 | 29.766 | 31.396 | 100.29 | 1.25 | 0.202 | 1.498 |
UDR-11_05_obsz-01_fot-1.8 | 36.302 | 0.011 | 0.798 | 0.114 | b.d.l. | 0.797 | 30.146 | 31.38 | 99.615 | 1.20 | 0.125 | 1.595 |
UDR-11_06_obsz-02_fot-1.2 | 36.005 | 0.027 | 0.941 | 0.177 | 0 | 0.845 | 30.63 | 31.787 | 100.611 | 1.18 | 0.204 | 1.786 |
UDR-11_06_obsz-02_fot-1.3 | 36.247 | 0.026 | 0.935 | 0.075 | 0.028 | 0.804 | 30.118 | 31.434 | 99.863 | 1.20 | 0.129 | 1.739 |
UDR-11_06_obsz-02_fot-1.4 | 38.566 | 0.025 | 0.811 | 0.141 | 0.003 | 0.786 | 28.496 | 30.989 | 99.985 | 1.35 | 0.169 | 1.597 |
UDR-11_06_obsz-02_fot-1.5 | 39.905 | 0.031 | 0.663 | 0.176 | 0.037 | 0.717 | 26.826 | 30.172 | 98.608 | 1.49 | 0.244 | 1.38 |
UDR-11_06_obsz-02_fot-1.6 | 39.352 | 0.023 | 0.762 | 0.103 | 0.061 | 0.743 | 28.445 | 31.145 | 100.82 | 1.38 | 0.187 | 1.505 |
UDR-11_06_obsz-04_fot-1.5 | 36.368 | 0.017 | 0.89 | 0.183 | 0.035 | 0.821 | 30.057 | 31.46 | 99.967 | 1.21 | 0.235 | 1.711 |
UDR-11_06_obsz-04_fot-1.6 | 36.796 | 0.024 | 0.858 | 0.171 | b.d.l. | 0.808 | 29.522 | 31.206 | 99.514 | 1.25 | 0.195 | 1.666 |
UDR-11_06_obsz-04_fot-1.7 | 36.502 | 0.023 | 0.858 | 0.229 | b.d.l. | 0.806 | 30.188 | 31.606 | 100.415 | 1.21 | 0.252 | 1.664 |
UDR-11_06_obsz-06_fot-1.3 | 35.281 | 0.093 | 1.009 | 0.117 | 0.024 | 0.295 | 31.791 | 32.033 | 100.78 | 1.11 | 0.234 | 1.304 |
UDR-11_05_obsz-03_fot-1.7 | 36.408 | 0.029 | 0.889 | 0.147 | 0.031 | 0.745 | 30.365 | 31.612 | 100.376 | 1.20 | 0.207 | 1.634 |
UDR-11_05_obsz-03_fot-1.8 | 37.015 | 0.021 | 0.878 | 0.179 | b.d.l. | 0.818 | 29.643 | 31.372 | 100.097 | 1.25 | 0.2 | 1.696 |
UDR-11_05_obsz-04_fot-1.7 | 34.846 | 0.017 | 1.045 | 0.161 | 0.039 | 0.703 | 31.466 | 31.913 | 100.3 | 1.11 | 0.217 | 1.748 |
UDR-11_05_obsz-04_fot-1.8 | 34.359 | 0.02 | 0.999 | 0.149 | 0.011 | 0.771 | 31.327 | 31.705 | 99.431 | 1.10 | 0.18 | 1.77 |
UDR-11_05_obsz-04_fot-1.9 | 33.303 | 0.348 | 1.117 | 0.113 | 0.001 | 0.853 | 31.636 | 31.976 | 99.537 | 1.05 | 0.462 | 1.97 |
UDR-11_06_obsz-02_fot-1.1 | 39.206 | 0.071 | 0.759 | 0.225 | 0.019 | 0.772 | 27.528 | 30.563 | 99.24 | 1.42 | 0.315 | 1.531 |
Appendix C
Analytical Point | Fe | Al | Mn | V | Cr | Mg | Ti | Zn | O | Total | Fe/Ti | Al + V + Cr | Mn + Mg |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
KR-24_03_obsz-01_fot-1.6 | 17.956 | 32.652 | 0.128 | 0.029 | 0.172 | 7.44 | 0.179 | 2.254 | 39.913 | 100.782 | 100.3 | 32.853 | 7.568 |
KR-24_03_obsz-01_fot-1.7 | 17.446 | 32.675 | 0.157 | 0.031 | 0.199 | 7.301 | 0.244 | 2.163 | 39.737 | 100.031 | 71.5 | 32.905 | 7.458 |
KR-24_03_obsz-03_fot-6.1 | 15.136 | 33.091 | 0.131 | 0.023 | 0.274 | 8.223 | 0.317 | 2.217 | 40.127 | 99.559 | 47.7 | 33.388 | 8.354 |
KR-24_03_obsz-03_fot-6.2 | 15.922 | 32.714 | 0.127 | 0.046 | 0.294 | 7.955 | 0.427 | 2.084 | 39.896 | 99.479 | 37.3 | 33.054 | 8.082 |
KR-24_03_obsz-03_fot-6.3 | 15.281 | 33.157 | 0.113 | 0.001 | 0.242 | 8.111 | 0.313 | 2.197 | 40.121 | 99.605 | 48.8 | 33.4 | 8.224 |
KR-24_03_obsz-03_fot-6.4 | 16.837 | 32.689 | 0.116 | 0.033 | 0.143 | 7.717 | 0.069 | 2.246 | 39.711 | 99.617 | 244.0 | 32.865 | 7.833 |
KR-24_03_obsz-03_fot-6.5 | 17.716 | 32.332 | 0.136 | 0.041 | 0.157 | 7.119 | 0.026 | 2.141 | 39.202 | 98.9 | 681.4 | 32.53 | 7.255 |
KRZ-56_02_obsz-01_fot-1.6 | 22.707 | 31.653 | 0.157 | 0.041 | 0.094 | 5.144 | 0.02 | 1.69 | 38.612 | 100.184 | 1135.4 | 31.788 | 5.301 |
KRZ-56_02_obsz-01_fot-1.7 | 22.74 | 31.296 | 0.196 | 0.065 | 0.088 | 4.852 | 0.009 | 1.467 | 38.045 | 98.775 | 2526.7 | 31.449 | 5.048 |
KRZ-56_02_obsz-01_fot-2.3 | 21.653 | 32.146 | 0.132 | 0.028 | 0.13 | 5.584 | 0.519 | 1.42 | 39.288 | 100.916 | 41.7 | 32.304 | 5.716 |
KRZ-56_02_obsz-01_fot-2.4 | 21.852 | 31.73 | 0.172 | 0.038 | 0.13 | 5.556 | 0.61 | 1.286 | 38.998 | 100.39 | 35.8 | 31.898 | 5.728 |
KRZ-56_02_obsz-01_fot-2.5 | 22.833 | 31.003 | 0.136 | 0.06 | 0.109 | 5.18 | 0.023 | 1.773 | 38.097 | 99.225 | 992.7 | 31.172 | 5.316 |
KR-63_05_obsz-02_fot-1.5 | 18.734 | 31.2 | 0.131 | 0.063 | 0.137 | 7.849 | 0.029 | 0.946 | 38.678 | 97.781 | 646.0 | 31.4 | 7.98 |
KR-63_05_obsz-04_fot-1.2 | 17.419 | 32.533 | 0.079 | 0.017 | 0.166 | 8.368 | 0.179 | 0.95 | 39.917 | 99.719 | 97.3 | 32.716 | 8.447 |
KR-63_05_obsz-04_fot-1.3 | 16.769 | 32.971 | 0.111 | 0.054 | 0.15 | 8.439 | 0.28 | 0.855 | 40.231 | 99.901 | 59.9 | 33.175 | 8.55 |
KR-63_05_obsz-05_fot-1.1 | 15.522 | 33.757 | 0.076 | 0.057 | 0.186 | 9.205 | 0.078 | 0.387 | 40.826 | 100.185 | 199.0 | 34 | 9.281 |
KR-63_05_obsz-05_fot-1.2 | 15.406 | 33.842 | 0.098 | 0.052 | 0.204 | 9.352 | 0.092 | 0.413 | 40.993 | 100.513 | 167.5 | 34.098 | 9.45 |
KR-63_05_obsz-05_fot-1.3 | 14.822 | 34.099 | 0.075 | 0.055 | 0.16 | 9.441 | 0.066 | 0.431 | 41.082 | 100.288 | 224.6 | 34.314 | 9.516 |
KR-63_05_obsz-05_fot-1.4 | 18.37 | 32.113 | 0.12 | 0.042 | 0.131 | 7.931 | 0.019 | 0.902 | 39.406 | 99.051 | 966.8 | 32.286 | 8.051 |
KR-63_05_obsz-05_fot-1.5 | 18.331 | 31.976 | 0.117 | 0.072 | 0.118 | 8.062 | 0.032 | 0.941 | 39.399 | 99.131 | 572.8 | 32.166 | 8.179 |
KR-63_05_obsz-08_fot-1.8 | 17.23 | 32.582 | 0.124 | 0.032 | 0.17 | 8.36 | 0.244 | 0.859 | 39.952 | 99.667 | 70.6 | 32.784 | 8.484 |
KR-63_05_obsz-08_fot-1.9 | 17.483 | 32.697 | 0.113 | 0.054 | 0.138 | 8.264 | 0.213 | 0.916 | 40.028 | 99.93 | 82.1 | 32.889 | 8.377 |
UDR-7_01_obsz-01_fot-1.11 | 21.062 | 31.72 | 0.139 | 0.05 | 0.585 | 6.315 | 0.035 | 1.432 | 39.13 | 100.516 | 601.8 | 32.355 | 6.454 |
UDR-7_01_obsz-01_fot-1.12 | 20.479 | 32.037 | 0.145 | 0.043 | 0.561 | 6.419 | 0.024 | 1.461 | 39.302 | 100.523 | 853.3 | 32.641 | 6.564 |
UDR-10_4_obsz-03_fot-1.1 | 23.269 | 30.323 | 0.142 | 0.055 | 1.206 | 5.678 | 0.342 | 0.865 | 38.461 | 100.443 | 68.0 | 31.584 | 5.82 |
UDR-10_4_obsz-03_fot-1.2 | 22.083 | 31.074 | 0.155 | 0.047 | 1.449 | 5.378 | 0.459 | 0.705 | 38.732 | 100.121 | 48.1 | 32.57 | 5.533 |
UDR-10_4_obsz-04_fot-1.1 | 24.015 | 29.755 | 0.147 | 0.064 | 0.761 | 5.562 | 0.035 | 0.957 | 37.696 | 99.007 | 686.1 | 30.58 | 5.709 |
UDR-10_4_obsz-04_fot-1.2 | 22.769 | 30.63 | 0.121 | 0.04 | 0.851 | 5.761 | 0.016 | 1.109 | 38.298 | 99.621 | 1423.1 | 31.521 | 5.882 |
UDR-10_4_obsz-04_fot-1.3 | 22.656 | 31.383 | 0.137 | 0.06 | 0.924 | 5.501 | 0.049 | 0.369 | 38.661 | 99.8 | 462.4 | 32.367 | 5.638 |
UDR-10_4_obsz-04_fot-1.4 | 22.583 | 30.658 | 0.173 | 0.052 | 0.871 | 5.478 | 0.121 | 0.362 | 38.037 | 98.486 | 186.6 | 31.581 | 5.651 |
Appendix D
Analytical Point | S | Ni | Co | Fe | Total | Analytical Point | S | Ni | Co | Fe | Total |
---|---|---|---|---|---|---|---|---|---|---|---|
10/1 | 39.45 | 0.55 | 0.23 | 59.12 | 99.35 | 4/1 | 38.87 | 0.79 | 0.17 | 59.82 | 99.65 |
11/1 | 39.5 | 0.46 | 0.21 | 58.85 | 99.02 | 6/1 | 39.3 | 1.01 | 0.16 | 59.32 | 99.79 |
11/1 | 39 | 0.66 | 0.18 | 59.53 | 99.37 | 8/1 | 38.55 | 1.02 | 0.2 | 59.33 | 99.1 |
12/1 | 39.27 | 0.76 | 0.12 | 59.22 | 99.37 | 9/1 | 38.61 | 0.99 | 0.14 | 59.4 | 99.14 |
6/1 | 38.72 | 0.67 | 0.12 | 59.68 | 99.19 | 10/1 | 38.99 | 0.97 | 0.08 | 59.12 | 99.16 |
7/1 | 38.72 | 0.75 | 0.13 | 59.57 | 99.17 | 8/1 | 38.82 | 1 | 0.14 | 59.48 | 99.44 |
8/1 | 38.65 | 0.72 | 0.13 | 59.37 | 98.87 | 12/1 | 39.1 | 1 | 0.13 | 59.25 | 99.48 |
3/1 | 39.41 | 0.62 | 0.1 | 59.74 | 99.87 | 1/1 | 39.052 | 0.223 | 0.115 | 60.038 | 99.428 |
4/1 | 39.74 | 0.62 | 0.11 | 59.69 | 100.16 | 2/1 | 38.991 | 0.249 | 0.136 | 59.738 | 99.114 |
9/1 | 38.58 | 0.76 | 0.16 | 59.61 | 99.11 | 7/1 | 39.117 | 0.258 | 0.099 | 59.08 | 98.554 |
10/1 | 39.36 | 0.77 | 0.13 | 59.56 | 99.82 | 5/1 | 38.627 | 0.392 | 0.178 | 60.288 | 99.485 |
11/1 | 39.21 | 0.37 | 0.05 | 59.58 | 99.21 | 6/1 | 38.742 | 0.347 | 0.134 | 60.183 | 99.406 |
6/1 | 39.23 | 0.6 | 0.16 | 59.56 | 99.55 | 7/1 | 38.883 | 0.303 | 0.171 | 60.215 | 99.572 |
7/1 | 39.34 | 0.6 | 0.18 | 59.79 | 99.91 | 3/1 | 39.73 | 0.275 | 0.098 | 59.715 | 99.818 |
7/1 | 38.55 | 0.87 | 0.18 | 59.6 | 99.2 | 4/1 | 39.42 | 0.246 | 0.186 | 59.794 | 99.646 |
3/1 | 39.02 | 0.65 | 0.12 | 59.36 | 99.15 | 3/1 | 39.685 | 0.635 | 0.109 | 59.315 | 99.744 |
4/1 | 39.29 | 0.61 | 0.15 | 59.74 | 99.79 | 1/1 | 39.028 | 0.227 | 0.185 | 59.493 | 98.933 |
10/1 | 38.49 | 1 | 0.13 | 59.94 | 99.56 | 2/1 | 39.093 | 0.277 | 0.221 | 59.403 | 98.994 |
11/1 | 38.75 | 1.03 | 0.16 | 59.9 | 99.84 | 3/1 | 38.891 | 0.272 | 0.193 | 59.794 | 99.15 |
2/1 | 38.34 | 1.6 | 0.15 | 59.02 | 99.11 | 1/1 | 39.478 | 0.26 | 0.179 | 59.396 | 99.313 |
3/1 | 38.76 | 4 | 0.09 | 56.13 | 98.98 | 2/1 | 39.542 | 0.225 | 0.264 | 59.564 | 99.595 |
10/1 | 38.77 | 0.6 | 0.14 | 59.71 | 99.22 | 1/1 | 39.459 | 0.201 | 0.266 | 59.151 | 99.077 |
6/1 | 39.25 | 0.44 | 0.13 | 59.44 | 99.26 | 2/1 | 39.054 | 0.196 | 0.245 | 59.589 | 99.084 |
7/1 | 39.22 | 0.31 | 0.11 | 59.75 | 99.39 | 1/1 | 38.969 | 0.243 | 0.116 | 60.198 | 99.526 |
9/1 | 39.01 | 0.23 | 0.15 | 59.56 | 98.95 | 2/1 | 38.689 | 0.232 | 0.179 | 60.526 | 99.626 |
10/1 | 39.14 | 0.24 | 0.12 | 59.76 | 99.26 | 1/1 | 39.699 | 0.19 | 0.201 | 59.761 | 99.851 |
1/1 | 39.04 | 0.46 | 0.15 | 59.26 | 98.91 | 2/1 | 39.751 | 0.213 | 0.21 | 59.684 | 99.858 |
2/1 | 39.04 | 0.39 | 0.13 | 59.48 | 99.04 | 9/1 | 38.914 | 0.214 | 0.237 | 60.323 | 99.688 |
5/1 | 38.97 | 0.94 | 0.19 | 59.41 | 99.51 | 5/1 | 38.952 | 0.202 | 0.239 | 59.41 | 98.803 |
6/1 | 38.76 | 0.94 | 0.16 | 59.26 | 99.12 | 6/1 | 38.996 | 0.217 | 0.278 | 59.065 | 98.556 |
3/1 | 39.11 | 0.97 | 0.14 | 59.62 | 99.84 |
Appendix E
Analytical Point | S | Cu | Ni | Co | Fe | Total | Analytical Point | S | Cu | Ni | Co | Fe | Total |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
5/1 | 33.51 | 0.07 | 26.06 | 6.93 | 32.57 | 99.14 | 3/1 | 33.22 | 0.09 | 34.45 | 6.71 | 26.1 | 100.57 |
6/1 | 32.15 | 0.09 | 29.24 | 15.3 | 22.74 | 99.52 | 4/1 | 33.44 | 4.38 | 30.33 | 5.97 | 26.62 | 100.74 |
7/1 | 32.95 | 0.09 | 29.08 | 15.23 | 22.26 | 99.61 | 5/1 | 33.61 | 0.21 | 33.94 | 7.04 | 25.86 | 100.66 |
5/1 | 32.96 | 0.21 | 35.78 | 2.57 | 28.2 | 99.72 | 2/1 | 32.74 | 0.12 | 37.4 | 2.18 | 27.58 | 100.02 |
6/1 | 33.21 | 3.2 | 33.01 | 2.44 | 27.95 | 99.81 | 3/1 | 32.73 | 0.07 | 36.95 | 3.38 | 26.99 | 100.12 |
1/1 | 32.8 | 0.11 | 36.76 | 1.4 | 28.54 | 99.61 | 4/1 | 32.91 | 0.05 | 36.79 | 3.02 | 26.99 | 99.76 |
2/1 | 33.09 | 0.06 | 37.19 | 1.39 | 28.9 | 100.63 | 1/1 | 33.08 | 0.11 | 35.92 | 2.65 | 26.37 | 98.13 |
3/1 | 33.2 | 0.11 | 36.33 | 1.22 | 28.19 | 99.05 | 2/1 | 33.25 | 0.01 | 36.11 | 2.74 | 27.1 | 99.21 |
4/1 | 35.26 | 0.23 | 26.59 | 1.12 | 37.35 | 100.55 | 3/1 | 33.41 | 0.41 | 36.41 | 2.56 | 27.11 | 99.9 |
8/1 | 33.82 | 0.06 | 33.58 | 6.89 | 26.7 | 101.05 | 4/1 | 33.22 | 0.05 | 36.58 | 3.32 | 26.96 | 100.13 |
9/1 | 33.5 | 0.03 | 33.49 | 6.94 | 26.64 | 100.6 | 3/1 | 33.03 | 0.19 | 39.22 | 2.82 | 27.12 | 102.38 |
1/1 | 32.24 | 0.13 | 33.92 | 7.15 | 26.73 | 100.17 | 4/1 | 33.02 | 0.05 | 38.35 | 3.67 | 27.37 | 102.46 |
4/1 | 32.89 | 0.11 | 36.33 | 3.16 | 27.23 | 99.72 | 12/1 | 32.93 | 0.05 | 38.08 | 3.72 | 27.28 | 102.06 |
5/1 | 32.7 | 0.07 | 36.42 | 3.09 | 27.14 | 99.42 | 13/1 | 32.72 | 0.07 | 38.42 | 3.73 | 26.95 | 101.89 |
6/1 | 32.43 | 0.05 | 36.65 | 2.96 | 27.27 | 99.36 | 5/1 | 33.01 | 0.11 | 36.14 | 3.6 | 27.06 | 99.92 |
1/1 | 33.01 | 0.36 | 39.23 | 1.43 | 26.47 | 100.5 | 6/1 | 33.09 | 0.11 | 36.36 | 3.19 | 27.57 | 100.32 |
2/1 | 32.74 | 1.05 | 38.06 | 1.55 | 26.28 | 99.68 | 7/1 | 41.19 | 0.08 | 27.63 | 3.6 | 27.22 | 99.72 |
3/1 | 32.96 | 2.5 | 36.54 | 1.56 | 26.57 | 100.13 | 3/1 | 32.88 | 0.11 | 36.89 | 2.76 | 27.29 | 99.93 |
1/1 | 32.54 | 0.07 | 35.25 | 6.86 | 25.88 | 100.6 | 4/1 | 32.83 | 0.03 | 36.73 | 3.16 | 27.3 | 100.05 |
2/1 | 32.5 | 0.16 | 35.14 | 6.8 | 25.77 | 100.37 | 5/1 | 32.81 | 0.04 | 36.71 | 2.99 | 27.33 | 99.88 |
3/1 | 32.59 | 0.13 | 35.78 | 5.67 | 26.22 | 100.39 | 6/1 | 33 | 0.09 | 36.67 | 3.11 | 27.31 | 100.18 |
6/1 | 32.32 | 0.11 | 35.25 | 6.31 | 26.34 | 100.33 | 7/1 | 39.03 | 0 | 23.7 | 7.67 | 29.29 | 99.69 |
7/1 | 32.14 | 0.12 | 34.71 | 6.94 | 25.7 | 99.61 |
Appendix F
Analytical Point | S | Cu | Ni | Co | Fe | Total |
---|---|---|---|---|---|---|
2/1 | 42.1 | 0.19 | 25.05 | 20.82 | 12.52 | 100.68 |
3/1 | 41.59 | 0.03 | 25.1 | 20.9 | 12.77 | 100.39 |
4/1 | 41.57 | 0.17 | 25.51 | 19.57 | 14.34 | 101.16 |
3/1 | 37.71 | 0.2 | 33.22 | 19.63 | 4.33 | 95.09 |
4/1 | 40.37 | 0.16 | 32.13 | 18.84 | 7.28 | 98.78 |
1/1 | 40.72 | 0.09 | 25.15 | 23.2 | 10.39 | 99.55 |
2/1 | 40.88 | 0.09 | 25.4 | 22.4 | 10.84 | 99.61 |
3/1 | 40.86 | 0.05 | 25.47 | 23.04 | 10.23 | 99.65 |
1/1 | 41.87 | 0.08 | 25.89 | 21.6 | 10.65 | 100.09 |
2/1 | 42.09 | 0.15 | 25.67 | 21.54 | 10.75 | 100.2 |
5/1 | 41.44 | b.d.l. | 27.05 | 23.61 | 10.84 | 102.94 |
6/1 | 41.54 | b.d.l. | 26.64 | 23.29 | 11.37 | 102.84 |
7/1 | 41.84 | 0.05 | 26.63 | 23.31 | 11.39 | 103.22 |
1/1 | 42.04 | 0.04 | 25.49 | 21.94 | 11.05 | 100.56 |
2/1 | 41.56 | 0.13 | 25.2 | 22.34 | 11.05 | 100.28 |
8/1 | 41.53 | 0.07 | 27.85 | 13.84 | 17.21 | 100.5 |
8/1 | 40.61 | 0.07 | 22.89 | 29.67 | 6.75 | 99.99 |
9/1 | 40.19 | 0.02 | 23.15 | 27.03 | 9.78 | 100.17 |
Appendix G
Analytical Point | S | Zn | Cu | Ni | Co | Fe | Total | Analytical Point | S | Zn | Cu | Ni | Co | Fe | Total |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
4/1 | 34.65 | 0.08 | 34.24 | 0.45 | 0.51 | 30.05 | 99.98 | 2/1 | 34.54 | 0.03 | 34.49 | 0.15 | 0.13 | 30.42 | 99.76 |
7/1 | 34.52 | 0.1 | 34.26 | 0.24 | 0.2 | 30.26 | 99.58 | 1/1 | 34.6 | 0.05 | 34.96 | 0.05 | 0.05 | 30.24 | 99.95 |
8/1 | 34.57 | b.d.l. | 34.65 | 0.08 | 0.09 | 30.25 | 99.64 | 2/1 | 34.57 | 0.16 | 34.7 | 0.04 | 0.04 | 30.43 | 99.94 |
9/1 | 34.8 | b.d.l. | 34.38 | 0.04 | 0.09 | 30.85 | 100.16 | 4/1 | 34.34 | 0.05 | 34.66 | 0.01 | 0.1 | 30.38 | 99.54 |
9/1 | 33.83 | 0.06 | 33.73 | 0.12 | 0.08 | 31.17 | 98.99 | 5/1 | 34.32 | 1.01 | 33.92 | 0.11 | 0.24 | 30.46 | 100.06 |
10/1 | 33.89 | 0.11 | 34.5 | 0.01 | 0.06 | 30.75 | 99.32 | 5/1 | 34.71 | 0.08 | 34.53 | 0.01 | 0.08 | 30.32 | 99.73 |
1/1 | 34.43 | 0.09 | 34.87 | 0.01 | 0.06 | 30.95 | 100.41 | 6/1 | 34.61 | 0.13 | 34.63 | 0.01 | 0.07 | 30.38 | 99.83 |
2/1 | 34.32 | 0.15 | 34.22 | 0.03 | 0.08 | 30.83 | 99.63 | 7/1 | 34.55 | b.d.l. | 34.71 | 0.01 | 0.08 | 30.52 | 99.87 |
10/1 | 34.38 | 0.07 | 34.75 | 0.08 | 0.07 | 30.6 | 99.95 | 5/1 | 34.31 | 0.02 | 34.6 | 0.14 | 0.19 | 30.46 | 99.72 |
11/1 | 34.58 | 0.02 | 35.11 | 0.1 | 0.12 | 30.31 | 100.24 | 1/1 | 34.19 | 0.13 | 35.37 | 0.05 | 0.07 | 30.46 | 100.27 |
2/1 | 34.28 | 0.02 | 34.37 | 0.25 | 0.17 | 30.68 | 99.77 | 2/1 | 34.22 | 0.01 | 35.12 | 0.04 | 0.15 | 30.27 | 99.81 |
6/1 | 34.74 | 0.03 | 34.69 | 0.04 | 0.12 | 30.05 | 99.67 | 11/1 | 34.15 | 0.01 | 35.17 | 0.16 | 0.17 | 30.09 | 99.75 |
7/1 | 34.54 | 0.06 | 34.05 | 0.39 | 0.55 | 30.05 | 99.64 | 3/1 | 34.27 | 0.12 | 34.64 | 0.33 | 0.14 | 30.71 | 100.21 |
7/1 | 34.07 | 0.05 | 34.23 | 0.02 | 0.03 | 30.65 | 99.05 | 4/1 | 34.22 | 0.02 | 34.47 | 0.14 | 0.08 | 30.96 | 99.89 |
8/1 | 34.15 | 0.1 | 34.37 | 0.02 | 0.05 | 30.5 | 99.19 | 1/1 | 34.2 | 0.05 | 34.61 | 0.42 | 0.16 | 30.44 | 99.88 |
9/1 | 34.56 | 0.01 | 34.97 | 0.04 | 0.08 | 30.36 | 100.02 | 2/1 | 34.05 | 0.1 | 34.59 | 0.56 | 0.26 | 30.07 | 99.63 |
1/1 | 33.87 | 0.13 | 34.38 | 0.07 | 0.06 | 31.35 | 99.86 | 4/1 | 33.995 | 0.055 | 34.321 | 0.006 | 0.047 | 30.455 | 98.879 |
4/1 | 34.03 | 0.03 | 34.94 | 0.19 | 0.03 | 30.47 | 99.69 | 6/1 | 34.265 | 0.031 | 34.158 | 0.047 | 0.074 | 30.76 | 99.335 |
5/1 | 34.13 | 0.11 | 35.22 | 0.07 | 0.07 | 30.4 | 100 | 8/1 | 34.443 | 0.114 | 34.55 | 0.01 | 0.071 | 30.491 | 99.679 |
4/1 | 33.97 | 0.06 | 34.83 | 0.18 | 0.07 | 30.4 | 99.51 | 9/1 | 34.692 | 0.011 | 34.194 | 0.01 | 0.117 | 30.724 | 99.748 |
5/1 | 34.01 | b.d.l. | 34.7 | 0.1 | 0.09 | 30.64 | 99.54 | 4/1 | 34.482 | b.d.l. | 34.051 | 0.075 | 0.063 | 29.875 | 98.546 |
6/1 | 34.17 | 0.13 | 34.63 | 0.08 | 0.05 | 30.22 | 99.28 | 3/1 | 34.523 | 0.125 | 34.495 | 0.049 | 0.065 | 30.407 | 99.664 |
1/1 | 34.34 | b.d.l. | 34.34 | 0.03 | 0.05 | 31.18 | 99.94 | 3/1 | 34.698 | 0.104 | 34.452 | 0.018 | 0.058 | 30.417 | 99.747 |
2/1 | 34.39 | 0.1 | 34.14 | 0.04 | 0.05 | 30.51 | 99.23 | 3/1 | 34.871 | b.d.l. | 34.3 | 0.042 | 0.02 | 30.705 | 99.938 |
1/1 | 34.59 | 0.15 | 34.12 | 0.17 | 0.16 | 30.35 | 99.54 | 7/1 | 34.451 | b.d.l. | 33.651 | 0.074 | 0.053 | 30.864 | 99.093 |
Appendix H
Analytical Point | S | Zn | Cu | Ni | Co | Fe | Total |
---|---|---|---|---|---|---|---|
4/1 | 35.11 | 0.13 | 23.22 | 0.14 | 0.14 | 40.79 | 99.53 |
5/1 | 35.19 | 0.01 | 23.63 | 0.06 | 0.06 | 40.34 | 99.29 |
8/1 | 34.82 | 0.01 | 23.23 | 0.08 | 0.1 | 40.97 | 99.21 |
9/1 | 34.95 | 0.01 | 22.24 | 0.09 | 0.1 | 41.98 | 99.37 |
3/1 | 35.1 | 0.01 | 23.56 | 0.01 | 0.11 | 41.03 | 99.82 |
6/1 | 34.72 | 0.01 | 23.31 | 0.05 | 0.05 | 40.85 | 98.99 |
7/1 | 34.9 | 0.06 | 23.21 | 0.01 | 0.09 | 40.96 | 99.23 |
8/1 | 34.89 | 0.03 | 22.81 | 0.04 | 0.05 | 40.88 | 98.7 |
3/1 | 35 | 0.04 | 23.4 | 0.01 | 0.04 | 40.76 | 99.25 |
4/1 | 35.44 | 0.06 | 23.24 | 0.01 | 0.04 | 41.12 | 99.91 |
Appendix I
Analytical Point | S | Zn | Cu | Ni | Co | Fe | Total | Analytical Point | S | Zn | Cu | Ni | Co | Fe | Total |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
13/1 | 52.87 | 0.07 | 0.03 | 1.22 | 1.95 | 43.99 | 100.29 | 1/1 | 52.201 | b.d.l. | 0.01 | 0.005 | 1.268 | 46.165 | 99.74 |
14/1 | 51.96 | 0.03 | 0.18 | 3.45 | 0.6 | 42.81 | 100.35 | 2/1 | 52.639 | b.d.l. | 0.031 | 0.071 | 1.902 | 45.437 | 100.105 |
11/1 | 53.13 | 0.01 | 0.1 | 0.06 | 0.12 | 47.12 | 100.64 | 3/1 | 52.292 | 0.074 | 0.01 | 0.01 | 1.552 | 45.972 | 99.964 |
12/1 | 52.8 | b.d.l. | 0.2 | 5.49 | 0.22 | 41.88 | 100.77 | 4/1 | 52.006 | 0.027 | 0.01 | 0.081 | 1.815 | 46.01 | 100.052 |
5/1 | 53.11 | 0.03 | 0.09 | 3.61 | 0.2 | 43.21 | 100.37 | 5/1 | 53.069 | 0.039 | 0.047 | 1.192 | 3.314 | 42.133 | 99.957 |
6/1 | 53.18 | b.d.l. | 0.02 | 0.48 | 0.13 | 46.83 | 100.67 | 6/1 | 53.099 | 0.028 | 0.01 | 1.23 | 0.113 | 45.376 | 99.897 |
1/1 | 52.33 | b.d.l. | 0.01 | 4.98 | 0.37 | 41.68 | 99.45 | 1/1 | 53.001 | 0.01 | 0.074 | 0.022 | 1.054 | 45.853 | 100.05 |
2/1 | 52.79 | 0.06 | 0.01 | 1.96 | 0.22 | 44.88 | 100 | 2/1 | 53.492 | 0.124 | 0.033 | 0.28 | 0.128 | 45.97 | 100.085 |
8/1 | 52.27 | 0.03 | 0.01 | 1.5 | 0.25 | 44.74 | 99.28 | 4/1 | 53.323 | b.d.l. | 0.056 | 0.062 | 7.063 | 39.434 | 100.05 |
12/1 | 53.09 | b.d.l. | 0.08 | 0.01 | 4.59 | 42.04 | 100 | 5/1 | 52.962 | 0.046 | 0.016 | 0.049 | 4.594 | 42.067 | 99.93 |
6/1 | 53.56 | 0.05 | 0.18 | 0.09 | 0.13 | 46.07 | 100.15 | 6/1 | 52.846 | 0.003 | 0.03 | 0.009 | 8.608 | 38.347 | 99.911 |
7/1 | 53.46 | b.d.l. | 0.21 | 0.1 | 0.11 | 46.04 | 99.96 | 7/1 | 52.794 | 0.045 | 0.042 | 0.04 | 7.059 | 39.602 | 99.724 |
7/1 | 53.73 | 0.03 | 0.13 | 0.3 | 0.09 | 45.84 | 100.24 | 3/1 | 53.136 | 0.036 | 0.052 | 1.215 | 0.089 | 45.618 | 100.283 |
8/1 | 53.57 | 0.02 | 0.08 | 0.22 | 0.08 | 45.81 | 99.87 | 10/1 | 53.418 | 0.127 | 0.003 | 0.024 | 0.288 | 46.37 | 100.321 |
9/1 | 53.17 | 0.07 | 0.2 | 0.86 | 0.07 | 45.62 | 100.17 | 1/1 | 53.977 | 0.01 | 0.017 | 0.112 | 0.123 | 45.972 | 100.394 |
8/1 | 53 | 0.06 | 0.06 | 8.72 | 0.14 | 38.02 | 100.1 | 2/1 | 53.927 | 0.084 | 0.001 | 0.301 | 0.064 | 45.56 | 100.073 |
9/1 | 53.21 | 0.03 | 0.01 | 0.78 | 3.26 | 43.53 | 100.91 | 3/1 | 53.453 | 0.073 | 0.01 | 0.046 | 0.127 | 45.435 | 99.575 |
5/1 | 52.678 | b.d.l. | 0.066 | 0.02 | 1.122 | 45.388 | 99.345 | 4/1 | 52.871 | 0.042 | 0.087 | 0.062 | 0.13 | 45.448 | 99.253 |
3/1 | 52.451 | 0.038 | 0.062 | 0.082 | 6.373 | 40.552 | 99.67 |
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WDS-XRF [ppm] | ||||||||||||
As | Ba | Bi | Br | Cd | Ce | Co | Cr | Cu | Ga | Hf | La | Mo |
3 | 10 | 3 | 1 | 3 | 5 | 3 | 5 | 5 | 3 | 3 | 5 | 2 |
Nb | Ni | Pb | Rb | Sn | Sr | Th | U | V | Y | Zn | Zr | |
2 | 3 | 3 | 3 | 2 | 2 | 3 | 2 | 5 | 3 | 2 | 3 | |
ICP-MS [ppm] | GF AAS [ppm] | |||||||||||
Sc | Y | La | Ce | Pr | Nd | Eu | Sm | Au | Pd | Pt | ||
0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.05 | 0.05 | 0.001 | 0.005 | 0.01 | ||
Gd | Tb | Dy | Ho | Er | Tm | Yb | Lu | |||||
0.05 | 0.05 | 0.05 | 0.05 | 0.05 | 0.05 | 0.05 | 0.05 | |||||
ICP-MS [ppm] | ||||||||||||
Ag | Cd | In | Mn | Re | Sb | Se | Sn | Ta | V | Te | Tl | W |
0.1 | 0.5 | 0.05 | 1 | 0.05 | 0.5 | 2 | 1 | 0.05 | 5 | 0.5 | 0.05 | 0.1 |
As | Bi | Co | Cu | Hf | Ni | Nb | Mo | Th | ||||
2 | 0.05 | 0.5 | 0.5 | 0.05 | 0.5 | 0.5 | 0.5 | 0.05 | ||||
WDS-XRF [%] | ||||||||||||
SiO2 | TiO2 | Al2O3 | Fe2O3 | MnO | MgO | CaO | Na2O | K2O | P2O5 | SO3 | Cl | F |
0.1 | 0.01 | 0.05 | 0.01 | 0.001 | 0.01 | 0.01 | 0.01 | 0.01 | 0.001 | 0.01 | 0.001 | 0.01 |
Mineral | Value | Fe | Al | Mn | V | Cr | Mg | Ti | Zn | O |
---|---|---|---|---|---|---|---|---|---|---|
wt% | wt% | wt% | wt% | wt% | wt% | wt% | wt% | wt% | ||
magnetite | arithmetic mean | 70.34 | 0.38 | 0.03 | 0.42 | 0.26 | 0.08 | 0.59 | 0.03 | 21.29 |
Fe2+Fe3+2O4 | standard deviation | 1.25 | 0.33 | 0.03 | 0.14 | 0.25 | 0.09 | 0.68 | 0.02 | 0.43 |
geometric mean | 70.33 | 0.30 | 0.02 | 0.37 | 0.14 | 0.06 | 0.29 | 0.02 | 21.29 | |
median | 70.59 | 0.29 | 0.02 | 0.48 | 0.14 | 0.06 | 0.26 | 0.02 | 21.26 | |
minimum content | 66.20 | 0.01 | b.d.l. | 0.01 | b.d.l. | 0.01 | 0.02 | b.d.l. | 20.46 | |
maximum content | 72.20 | 2.06 | 0.13 | 0.59 | 1.26 | 0.53 | 2.65 | 0.08 | 22.54 | |
number of analyses a.d.l. | 81 | 81 | 69 | 81 | 80 | 80 | 81 | 45 | 81 | |
ilmenite | arithmetic mean | 35.44 | 0.25 | 0.81 | 0.14 | 0.04 | 0.87 | 30.59 | 0.04 | 31.72 |
FeTiO3 | standard deviation | 1.47 | 0.77 | 0.14 | 0.04 | 0.08 | 0.37 | 1.22 | 0.03 | 0.45 |
geometric mean | 35.41 | 0.04 | 0.80 | 0.13 | 0.03 | 0.79 | 30.56 | 0.02 | 31.72 | |
median | 35.19 | 0.03 | 0.80 | 0.14 | 0.03 | 0.80 | 31.10 | 0.03 | 31.78 | |
minimum content | 33.15 | b.d.l. | 0.59 | 0.05 | b.d.l. | 0.16 | 26.68 | b.d.l. | 30.17 | |
maximum content | 39.91 | 4.39 | 1.18 | 0.24 | 0.59 | 1.66 | 31.89 | 0.12 | 32.89 | |
number of analyses a.d.l. | 59 | 57 | 59 | 59 | 47 | 59 | 59 | 31 | 59 | |
Al-spinels | arithmetic mean | 19.24 | 32.08 | 0.13 | 0.04 | 0.36 | 7.05 | 0.17 | 1.26 | 39.35 |
*M2+M3+2O4 | standard deviation | 2.99 | 1.06 | 0.03 | 0.02 | 0.37 | 1.43 | 0.17 | 0.64 | 0.90 |
geometric mean | 19.01 | 32.07 | 0.13 | 0.04 | 0.25 | 6.91 | 0.09 | 1.09 | 39.34 | |
median | 18.35 | 32.13 | 0.13 | 0.05 | 0.17 | 7.37 | 0.09 | 1.03 | 39.35 | |
minimum content | 14.82 | 29.76 | 0.08 | b.d.l. | 0.09 | 4.85 | 0.01 | 0.36 | 37.70 | |
maximum content | 24.02 | 34.10 | 0.20 | 0.07 | 1.45 | 9.44 | 0.61 | 2.25 | 41.08 | |
number of analyses a.d.l. | 30 | 30 | 30 | 30 | 30 | 30 | 30 | 30 | 30 |
Mineral | Value | Fe | S | Ni | Co | Cu | Zn |
wt% | wt% | wt% | wt% | wt% | wt% | ||
pyrrhotite | arithmetic mean | 59.53 | 39.06 | 0.61 | 0.16 | 0.04 | 0.03 |
(FeS) | standard deviation | 0.56 | 0.34 | 0.54 | 0.05 | 0.03 | 0.04 |
geometric mean | 59.53 | 39.06 | 0.48 | 0.15 | 0.51 (n = 46) | 0.38 (n = 42) | |
median | 59.56 | 39.03 | 0.55 | 0.15 | 0.04 | 0.03 | |
(n = 61) | minimum content | 56.13 | 38.34 | 0.19 | 0.05 | b.d.l. | b.d.l. |
maximum content | 60.53 | 39.75 | 4.00 | 0.28 | 0.14 | 0.16 | |
pyrite | arithmetic mean | 44.13 | 53.00 | 1.05 | 1.60 | 0.06 | 0.04 |
FeS2 | standard deviation | 2.49 | 0.50 | 1.90 | 2.36 | 0.06 | 0.03 |
geometric mean | 44.06 | 52.99 | 0.20 | 0.49 | 0.03 | 0.03 | |
median | 45.44 | 53.07 | 0.11 | 0.25 | 0.04 | 0.03 | |
(n = 37) | minimum content | 38.02 | 51.96 | 0.01 | 0.06 | b.d.l. | b.d.l. |
maximum content | 47.12 | 53.98 | 8.72 | 8.61 | 0.21 | 0.13 | |
Mineral | Value | Cu | Fe | S | Ni | Co | Zn |
wt% | wt% | wt% | wt% | wt% | wt% | ||
chalcopyrite | arithmetic mean | 34.52 | 30.50 | 34.36 | 0.11 | 0.11 | 0.08 |
CuFeS2 | standard deviation | 0.37 | 0.31 | 0.26 | 0.13 | 0.10 | 0.14 |
geometric mean | 34.52 | 30.50 | 34.36 | 0.06 | 0.09 | 0.06 (n = 42) | |
median | 34.52 | 30.46 | 34.36 | 0.06 | 0.08 | 0.06 | |
(n = 50) | minimum content | 33.65 | 29.88 | 33.83 | 0.01 | 0.02 | b.d.l. |
maximum content | 35.37 | 31.35 | 34.87 | 0.56 | 0.55 | 1.01 | |
cubanite | arithmetic mean | 23.19 | 40.97 | 35.01 | 0.05 | 0.08 | 0.04 |
CuFe2S3 | standard deviation | 0.40 | 0.41 | 0.21 | 0.04 | 0.035 | 0.04 |
geometric mean | 23.18 | 40.97 | 35.01 | 0.03 | 0.07 | 0.02 | |
median | 23.24 | 40.92 | 34.98 | 0.05 | 0.08 | 0.02 | |
(n = 10) | minimum content | 22.24 | 40.34 | 34.72 | 0.01 | 0.04 | 0.01 |
maximum content | 23.63 | 41.98 | 35.44 | 0.14 | 0.14 | 0.13 | |
talnakhite | arithmetic mean | 27.09 | 29.05 | 35.00 | 4.20 | 3.94 | 0.30 |
Cu9(Fe,Ni)8S3 | standard deviation | 0.47 | 0.80 | 0.71 | 0.93 | 1.20 | 0.16 |
geometric mean | 27.09 | 29.04 | 35.00 | 4.15 | 3.84 | 0.27 | |
median | 27.09 | 29.05 | 35.00 | 4.20 | 3.94 | 0.30 | |
(n = 3) | minimum content | 26.76 | 28.48 | 34.50 | 3.54 | 3.09 | 0.18 |
maximum content | 27.42 | 29.61 | 35.50 | 4.86 | 4.78 | 0.41 |
Mineral | Value | Ni | Fe | Co | Cu | Zn | S |
---|---|---|---|---|---|---|---|
wt% | wt% | wt% | wt% | wt% | wt% | ||
pentlandite | arithmetic mean | 34.89 | 27.21 | 4.41 | 0.35 | 0.05 | 33.30 |
(Fe,Ni)9S8 | standard deviation | 3.58 | 2.15 | 3.09 | 0.85 | 0.04 | 1.59 |
geometric mean | 34.69 | 27.13 | 3.63 | 0.12 (n = 42) | 0.04 | 33.27 | |
median | 36.33 | 27.10 | 3.19 | 0.11 | 0.05 | 32.96 | |
(n = 45) | minimum content | 23.70 | 22.26 | 1.12 | b.d.l. | b.d.l. | 32.14 |
maximum content | 39.23 | 37.35 | 15.30 | 4.38 | 0.15 | 41.19 | |
siegenite | arithmetic mean | 26.31 | 10.75 | 22.03 | 0.09 | 0.04 (n = 16) | 41.14 |
(Ni,Co)3S4 | standard deviation | 2.61 | 2.80 | 3.29 | 0.06 | 0.03 | 1.04 |
geometric mean | 26.19 | 10.35 | 21.79 | 0.07 | 0.03 | 41.13 | |
median | 25.50 | 10.84 | 22.14 | 0.08 | 0.04 | 41.54 | |
(n = 18) | minimum content | 22.89 | 4.33 | 13.84 | b.d.l. | b.d.l. | 37.71 |
maximum content | 33.22 | 17.21 | 29.67 | 0.20 | 0.12 | 42.10 | |
bravoite | arithmetic mean | 28.10 | 28.26 | 2.66 | 0.45 | - | 39.38 |
(Fe,Ni,Co)S2 | standard deviation | 2.19 | 2.24 | 1.14 | 0.74 | - | 0.48 |
geometric mean | 28.04 | 28.20 | 2.45 | - | - | 39.38 | |
median | 27.94 | 28.29 | 3.22 | 0.05 | - | 39.12 | |
(n = 7) | minimum content | 25.99 | 26.01 | 1.35 | b.d.l. | b.d.l. | 39.09 |
maximum content | 30.36 | 30.48 | 3.40 | 1.31 | 0.04 | 39.94 |
Mineral | Element | S | Cu | Ni | Co | Fe | Mineral |
---|---|---|---|---|---|---|---|
pentlandite | S | 1.00 | 0.08 | −0.34 | 0.08 | −0.01 | pyrrhotite |
Cu | −0.03 | 1.00 | −0.12 | −0.04 | 0.13 | ||
Ni | −0.62 | −0.13 | 1.00 | −0.31 | −0.76 | ||
Co | −0.02 | −0.09 | −0.54 | 1.00 | 0.10 | ||
Fe | 0.30 | −0.02 | −0.29 | −0.50 | 1.00 | ||
chalcopyrite | S | 1.00 | 0.11 | −0.22 | −0.19 | 0.22 | pyrite |
Cu | −0.08 | 1.00 | 0.18 | −0.20 | 0.01 | ||
Ni | −0.14 | −0.08 | 1.00 | −0.27 | −0.46 | ||
Co | 0.14 | −0.18 | 0.73 | 1.00 | −0.71 | ||
Fe | −0.31 | −0.28 | −0.31 | −0.41 | 1.00 | ||
cubanite | S | 1.00 | −0.39 | −0.78 | 0.16 | 0.73 | siegenite |
Cu | 0.26 | 1.00 | 0.38 | −0.36 | −0.31 | ||
Ni | −0.15 | −0.33 | 1.00 | −0.42 | −0.62 | ||
Co | −0.08 | −0.13 | 0.62 | 1.00 | −0.34 | ||
Fe | −0.09 | −0.83 | 0.12 | 0.25 | 1.00 |
Sample | K24/01 | K50/05 | K56/06 | U11/05 | K63/06 | U10/04 | K24/03 | U7/03 | K56/05 |
---|---|---|---|---|---|---|---|---|---|
Anorthosite | Norite | Jotunite | Ferrolite | ||||||
SiO2 (%) | 45.39 | 28.37 | 31.32 | 26.72 | 8.27 | 7.27 | 13.53 | 16.34 | 24.16 |
TiO2 | 1.573 | 6.037 | 5.153 | 6.269 | 7.221 | 10.78 | 9.562 | 9.372 | 6.838 |
Al2O3 | 27.28 | 13.88 | 12.2 | 7.53 | 5.74 | 7.87 | 8.94 | 8.95 | 11.3 |
Fe2O3 | 6.4 | 39.34 | 37.1 | 36.64 | 76.23 | 69.78 | 62.47 | 56.38 | 47.38 |
MnO | 0.061 | 0.217 | 0.296 | 0.52 | 0.394 | 0.269 | 0.276 | 0.271 | 0.278 |
MgO | 1.25 | 4.43 | 5.1 | 8.03 | 1.25 | 2.33 | 2.48 | 4.07 | 3.79 |
CaO | 11.98 | 5.02 | 5.11 | 9.77 | 1.29 | 1.57 | 2.55 | 2.77 | 4.47 |
Na2O | 4.58 | 2.28 | 1.84 | 1.47 | 0.62 | 0.69 | 0.97 | 0.89 | 1.51 |
K2O | 0.72 | 0.4 | 0.56 | 0.27 | 0.97 | 0.19 | 0.19 | 0.22 | 0.55 |
P2O5 | 0.332 | 0.054 | 0.177 | 2.388 | 0.027 | 0.028 | 0.009 | 0.022 | 0.364 |
SO3 | 0.06 | 0.44 | 0.03 | 1.49 | 0.2 | <0.01 | <0.01 | 0.03 | <0.01 |
Cl | 0.082 | 0.144 | 0.085 | 0.089 | 0.127 | 0.129 | 0.091 | 0.115 | 0.087 |
LOI | 0.3 | 0.5 | 1 | 0.9 | 2 | 1.3 | 1.1 | 0.2 | 0.9 |
SUM | 99.71 | 99.17 | 99.21 | 99.29 | 98.91 | 98.14 | 99.02 | 98.08 | 99.17 |
Ag ppm | 0.6 | 0.5 | 0.9 | 0.7 | 0.3 | 0.6 | 0.6 | <0.3 | 1.2 |
Au ppb | <1 | 6 | 7 | 2 | 1 | 5 | 4 | 1 | 7 |
Ba | 272 | 171 | 259 | 106 | <10 | <10 | <10 | <10 | 706 |
Cd | 3 | 14 | 9 | 15 | 17 | 17 | 11 | 14 | 8 |
Ce | 26.8 | 12.6 | 38.1 | 285,0 | 6.5 | 6.3 | 2.9 | 4.8 | 35.4 |
Co | 15 | 138 | 205 | 65 | 128 | 144 | 135 | 143 | 161 |
Cr | 2.5 | 362 | 34 | <5 | 133 | 2159 | 218 | 3777 | 217 |
Cu | 38 | 325 | 604 | 117 | 247 | 94 | 231 | 61 | 658 |
Dy | 1.89 | 0.64 | 2.79 | 23.56 | 0.3 | 0.38 | 0.15 | 0.29 | 2.19 |
Er | 0.86 | 0.37 | 1.46 | 11.44 | 0.17 | 0.25 | 0.11 | 0.19 | 1.11 |
Eu | 2.9 | 0.91 | 3.81 | 36.85 | 0.59 | 0.52 | 0.19 | 0.31 | 3.32 |
Ga | 23 | 38 | 31 | 23 | 48 | 70 | 50 | 54 | 43 |
Gd | 2.63 | 0.76 | 3.4 | 32.5 | 0.47 | 0.46 | 0.17 | 0.28 | 3,00 |
Ge | 0.05 | 0.2 | 0.3 | 0.7 | 0.4 | 0.4 | 0.4 | 0.3 | 0.3 |
Hf | <3 | <3 | 6 | 14 | 5 | 12 | 5 | 8 | <3 |
Ho | 0.35 | 0.13 | 0.55 | 4.52 | 0.05 | 0.08 | <0.05 | 0.06 | 0.43 |
In | 0.025 | 0.08 | 0.11 | 0.3 | 0.23 | 0.13 | 0.16 | 0.11 | 0.15 |
La | 12.7 | 6.8 | 19.1 | 114.4 | 3.2 | 3,0 | 1.7 | 2.7 | 18.3 |
Lu | 0.08 | <0.05 | 0.18 | 1.1 | <0.05 | <0.05 | <0.05 | <0.05 | 0.13 |
Nb | 5 | 6 | 9 | 31 | 14 | 7 | 7 | 9 | 8 |
Nd | 14.9 | 5.5 | 19.1 | 182.7 | 2.8 | 2.9 | 1.2 | 2,0 | 17.9 |
Ni | 16 | 398 | 570 | 56 | 401 | 664 | 326 | 646 | 426 |
Pb | 13 | 4 | 8 | 6 | <3 | <3 | <3 | <3 | 8 |
Pd ppb | <5 | <5 | <5 | <5 | 12 | 5 | 5 | <5 | <5 |
Pr | 3.6 | 1.5 | 4.8 | 41.3 | 0.8 | 0.8 | 0.25 | 0.6 | 4.5 |
Pt ppb | <10 | <10 | <10 | <10 | <10 | <10 | 12 | 12 | <10 |
Rb | 6 | 9 | 20 | 11 | 181 | 9 | 7 | 7 | 20 |
Sc | 11.7 | 16.9 | 24.2 | 74.9 | 14.6 | 17.8 | 23.8 | 21.9 | 21.3 |
Sm | 1.62 | 0.62 | 1.29 | 5.08 | 0.14 | 0.22 | 0.29 | 0.38 | 1.39 |
Sn | 2 | 2 | 3 | 5 | 10 | 3 | 4 | 3 | 3 |
Sr | 678 | 383 | 339 | 234 | 86 | 129 | 204 | 198 | 285 |
Ta | 0.16 | 0.12 | 0.39 | 1.77 | 0.6 | 0.2 | 0.18 | 0.18 | 0.25 |
Tb | 0.34 | 0.1 | 0.48 | 4.35 | 0.06 | 0.06 | <0.05 | <0.05 | 0.38 |
Th | 0.56 | 0.77 | 1.36 | 2.59 | 1.31 | 0.27 | 0.07 | 0.18 | 1.05 |
Tm | 0.1 | 0.05 | 0.2 | 1.41 | <0.05 | <0.05 | <0.05 | <0.05 | 0.15 |
V | 104 | 1242 | 860 | 456 | 767 | 1099 | 915 | 980 | 2009 |
W | 0.3 | 0.3 | 0.5 | 0.3 | 2.2 | 0.1 | 0.5 | 0.3 | 1.3 |
Y | 8.3 | 3.2 | 13,00 | 105.6 | 1.4 | 1.8 | 0.8 | 1.5 | 10.3 |
Yb | 0.57 | 0.33 | 1.21 | 7.79 | 0.24 | 0.23 | 0.14 | 0.27 | 0.89 |
Zn | 62 | 324 | 271 | 481 | 641 | 701 | 630 | 519 | 448 |
Zr | 86 | 51 | 99 | 595 | 28 | 46 | 54 | 53 | 110 |
Element/ Compound | Arithmetic Mean | Geometric Mean | Median | Minimum Content | Maximum Content | Standard Deviation |
---|---|---|---|---|---|---|
Fe2O3 total (%) | 48.61 | 44.99 | 51.43 | 6.4 | 76.23 | 15.69 |
TiO2 (%) | 7.56 | 7.11 | 8.05 | 1.57 | 11.44 | 2.26 |
V (ppm) | 960.23 | 861.84 | 977 | 104 | 2208 | 403.57 |
Co | 122.33 | 111.75 | 137 | 15 | 205 | 40.44 |
Ga | 44.33 | 41.98 | 45 | 21 | 84 | 14.46 |
Ge | 0.29 | 0.27 | 0.3 | 0.05 | 0.7 | 0.12 |
Hf | 0.95 | 0.87 | 0.93 | 0.38 | 2.09 | 0.4 |
In | 0.13 | 0.12 | 0.12 | 0.03 | 0.3 | 0.06 |
Nb | 9.38 | 8.27 | 8 | 5 | 32 | 6.42 |
Sc | 24.29 | 21.63 | 19.8 | 10.8 | 74.9 | 15 |
W | 3.59 | 0.46 | 0.3 | 0.1 | 101 | 16.17 |
Y | 11.38 | 3.98 | 3.8 | 0.25 | 105.6 | 25.4 |
La | 15.13 | 7.07 | 6.8 | 0.8 | 118.3 | 28.69 |
Ce | 33.93 | 13.8 | 12.6 | 1.3 | 285 | 71.17 |
Pr | 4.59 | 1.63 | 1.7 | 0.25 | 41.3 | 10.27 |
Nd | 19.36 | 6.51 | 6.8 | 0.5 | 182.7 | 45.06 |
Eu | 3.76 | 1.16 | 1.23 | 0.07 | 36.85 | 8.94 |
Sm | 0.97 | 0.61 | 0.62 | 0.09 | 5.27 | 1.27 |
Gd | 3.3 | 1.03 | 0.92 | 0.07 | 32.5 | 7.8 |
Tb | 0.44 | 0.14 | 0.13 | 0.03 | 4.35 | 1.03 |
Dy | 2.48 | 0.83 | 0.83 | 0.06 | 23.56 | 5.63 |
Ho | 0.48 | 0.16 | 0.16 | 0.03 | 4.52 | 1.07 |
Er | 1.25 | 0.47 | 0.44 | 0.03 | 11.44 | 2.71 |
Yb | 0.94 | 0.42 | 0.38 | 0.03 | 7.79 | 1.83 |
Cr | 678.22 | 219.58 | 171 | 2.5 | 5705 | 1164.87 |
Cu | 328.54 | 226.55 | 231 | 38 | 1756 | 323.94 |
Ni | 436.36 | 302.06 | 421 | 16 | 1370 | 301.16 |
Zn (ppm) | 453 | 415.65 | 481 | 62 | 701 | 152.79 |
Au (ppb) | 6.62 | 3.46 | 4 | <1 | 37 | 8.32 |
Ag (ppm) | 0.66 | 0.5 | 0.6 | <0.30 | 2.5 | 0.54 |
Cd | 13.77 | 12.9 | 14 | 3 | 24 | 4.37 |
Br | 4.64 | 4.55 | 5 | 3 | 7 | 0.93 |
Rb | 16.97 | 11.55 | 9 | 6 | 181 | 29.56 |
Sr | 271.49 | 247.15 | 254 | 86 | 678 | 123.62 |
Sn | 3.15 | 2.96 | 3 | 2 | 10 | 1.41 |
Ta | 0.34 | 0.24 | 0.23 | 0.08 | 1.77 | 0.4 |
Th | 0.75 | 0.52 | 0.5 | 0.07 | 2.83 | 0.68 |
U | 2.9 | 2.55 | 3 | 1 | 5 | 1.29 |
Zr | 105 | 72.31 | 66 | 25 | 737 | 142.92 |
SiO2 (%) | 21.47 | 19.1 | 18.44 | 6.27 | 45.39 | 10.15 |
Al2O3 | 11.27 | 10.72 | 10.35 | 5.74 | 27.28 | 4.14 |
MnO | 0.26 | 0.25 | 0.26 | 0.06 | 0.52 | 0.08 |
MgO | 3.88 | 3.47 | 3.43 | 1.25 | 8.97 | 1.9 |
CaO | 4.46 | 3.77 | 3.69 | 1.29 | 11.98 | 2.75 |
Na2O | 1.62 | 1.45 | 1.51 | 0.62 | 4.58 | 0.84 |
K2O | 0.38 | 0.34 | 0.34 | 0.11 | 1.11 | 0.21 |
P2O5 | 0.23 | 0.07 | 0.05 | 0.01 | 2.39 | 0.54 |
(SO3) | 0.33 | 0.09 | 0.21 | 0.01 | 1.7 | 0.47 |
(Cl) | 0.11 | 0.11 | 0.12 | 0.08 | 0.17 | 0.02 |
SiO2 | TiO2 | Al2O3 | Fe2O3 | MnO | MgO | CaO | Na2O | K2O | P2O5 | SO3 | Ag | Au | Br | Cd | Ce | Co | Cr | Cu | Ga | Ge | Hf | In | La | Nb | Ni | Rb | Sc | Sr | Ta | Th | U | V | Y | Zn | Zr | |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
SiO2 | 1.00 | |||||||||||||||||||||||||||||||||||
TiO2 | 0.90 | 1.00 | ||||||||||||||||||||||||||||||||||
Al2O3 | 0.71 | −0.74 | 1.00 | |||||||||||||||||||||||||||||||||
Fe2O3 | −0.98 | 0.89 | −0.75 | 1.00 | ||||||||||||||||||||||||||||||||
MnO | −0.14 | 0.16 | −0.67 | 0.17 | 1.00 | |||||||||||||||||||||||||||||||
MgO | 0.45 | −0.34 | −0.14 | −0.42 | 0.47 | 1.00 | ||||||||||||||||||||||||||||||
CaO | 0.83 | −0.81 | 0.61 | −0.89 | 0.07 | 0.31 | 1.00 | |||||||||||||||||||||||||||||
Na2O | 0.86 | −0.84 | 0.94 | −0.90 | −0.46 | 0.06 | 0.78 | 1.00 | ||||||||||||||||||||||||||||
K2O | 0.32 | −0.39 | 0.31 | −0.27 | −0.10 | −0.21 | 0.22 | 0.35 | 1.00 | |||||||||||||||||||||||||||
P2O5 | 0.33 | −0.29 | −0.10 | −0.34 | 0.73 | 0.46 | 0.58 | 0.09 | −0.03 | 1.00 | ||||||||||||||||||||||||||
SO3 | 0.02 | 0.00 | −0.11 | −0.05 | 0.30 | 0.20 | 0.11 | −0.01 | −0.14 | 0.26 | 1.00 | |||||||||||||||||||||||||
Ag | −0.11 | 0.17 | −0.06 | 0.07 | 0.02 | −0.11 | −0.08 | −0.05 | 0.06 | −0.04 | 0.50 | 1.00 | ||||||||||||||||||||||||
Au | −0.35 | 0.36 | −0.23 | 0.35 | −0.07 | −0.27 | −0.33 | −0.27 | −0.13 | −0.18 | 0.32 | 0.54 | 1.00 | |||||||||||||||||||||||
Br | −0.59 | 0.56 | −0.44 | 0.56 | 0.09 | −0.21 | −0.46 | −0.51 | −0.26 | −0.12 | −0.04 | 0.18 | 0.53 | 1.00 | ||||||||||||||||||||||
Cd | −0.65 | 0.61 | −0.59 | 0.64 | 0.28 | −0.05 | −0.54 | −0.64 | −0.36 | −0.08 | 0.20 | −0.11 | 0.19 | 0.50 | 1.00 | |||||||||||||||||||||
Ce | 0.35 | −0.30 | −0.10 | −0.36 | 0.72 | 0.46 | 0.58 | 0.10 | −0.01 | 0.99 | 0.22 | −0.05 | −0.19 | −0.13 | −0.08 | 1.00 | ||||||||||||||||||||
Co | −0.64 | 0.61 | −0.53 | 0.69 | 0.00 | −0.21 | −0.75 | −0.67 | −0.21 | −0.50 | −0.05 | 0.14 | 0.39 | 0.41 | 0.42 | −0.50 | 1.00 | |||||||||||||||||||
Cr | −0.25 | 0.29 | −0.08 | 0.23 | −0.13 | −0.14 | −0.25 | −0.21 | −0.25 | −0.18 | −0.28 | −0.23 | −0.12 | 0.18 | 0.20 | −0.18 | 0.21 | 1.00 | ||||||||||||||||||
Cu | −0.28 | 0.29 | −0.25 | 0.30 | −0.02 | −0.20 | −0.33 | −0.28 | 0.01 | −0.18 | 0.41 | 0.65 | 0.85 | 0.41 | 0.14 | −0.19 | 0.48 | −0.28 | 1.00 | |||||||||||||||||
Ga | −0.87 | 0.75 | −0.41 | 0.86 | −0.17 | −0.58 | −0.78 | −0.67 | −0.34 | −0.42 | −0.16 | −0.01 | 0.28 | 0.50 | 0.57 | −0.43 | 0.57 | 0.39 | 0.16 | 1.00 | ||||||||||||||||
Ge | −0.21 | 0.23 | −0.58 | 0.24 | 0.86 | 0.25 | 0.02 | −0.47 | −0.17 | 0.78 | 0.17 | −0.04 | −0.01 | 0.21 | 0.26 | 0.78 | −0.06 | 0.04 | −0.03 | 0.05 | 1.00 | |||||||||||||||
Hf | −0.04 | 0.23 | −0.38 | 0.03 | 0.49 | 0.23 | 0.06 | −0.23 | −0.05 | 0.45 | 0.09 | 0.26 | 0.13 | 0.17 | 0.01 | 0.47 | −0.11 | 0.00 | 0.05 | −0.13 | 0.55 | 1.00 | ||||||||||||||
In | −0.15 | 0.17 | −0.61 | 0.19 | 0.92 | 0.29 | 0.06 | −0.42 | −0.02 | 0.77 | 0.29 | 0.10 | −0.02 | 0.08 | 0.21 | 0.77 | −0.14 | −0.14 | 0.02 | −0.10 | 0.92 | 0.56 | 1.00 | |||||||||||||
La | 0.35 | −0.29 | −0.03 | −0.35 | 0.58 | 0.41 | 0.50 | 0.15 | 0.01 | 0.83 | 0.18 | −0.11 | −0.18 | −0.15 | −0.06 | 0.84 | −0.38 | −0.12 | −0.19 | −0.40 | 0.63 | 0.36 | 0.59 | 1.00 | ||||||||||||
Nb | 0.23 | −0.17 | −0.25 | −0.22 | 0.82 | 0.41 | 0.45 | −0.03 | 0.05 | 0.94 | 0.27 | 0.01 | −0.14 | −0.06 | 0.01 | 0.96 | −0.45 | −0.14 | −0.15 | −0.37 | 0.84 | 0.54 | 0.87 | 0.79 | 1.00 | |||||||||||
Ni | −0.73 | 0.61 | −0.39 | 0.72 | −0.15 | −0.39 | −0.71 | −0.62 | −0.32 | −0.40 | 0.04 | 0.24 | 0.62 | 0.64 | 0.51 | −0.41 | 0.68 | 0.32 | 0.55 | 0.82 | 0.01 | −0.09 | −0.13 | −0.35 | −0.35 | 1.00 | ||||||||||
Rb | −0.19 | 0.01 | −0.24 | 0.28 | 0.24 | −0.24 | −0.22 | −0.21 | 0.70 | −0.07 | −0.10 | −0.04 | −0.08 | 0.06 | 0.07 | −0.06 | 0.05 | −0.13 | 0.02 | 0.02 | 0.13 | −0.05 | 0.30 | −0.08 | 0.12 | −0.03 | 1.00 | |||||||||
Sc | 0.37 | −0.23 | −0.25 | −0.36 | 0.72 | 0.74 | 0.47 | 0.00 | −0.12 | 0.86 | 0.21 | −0.06 | −0.25 | −0.13 | −0.07 | 0.86 | −0.49 | −0.16 | −0.23 | −0.53 | 0.68 | 0.57 | 0.73 | 0.69 | 0.84 | −0.48 | −0.10 | 1.00 | ||||||||
Sr | 0.85 | −0.81 | 0.94 | −0.86 | −0.44 | 0.01 | 0.75 | 0.97 | 0.28 | 0.12 | 0.02 | −0.03 | −0.20 | −0.50 | −0.63 | 0.13 | −0.58 | −0.17 | −0.20 | −0.61 | −0.40 | −0.24 | −0.41 | 0.19 | −0.01 | −0.53 | −0.28 | −0.03 | 1.00 | |||||||
Ta | 0.24 | −0.18 | −0.25 | −0.23 | 0.81 | 0.41 | 0.45 | −0.03 | 0.12 | 0.94 | 0.28 | 0.04 | −0.11 | −0.04 | 0.00 | 0.95 | −0.43 | −0.19 | −0.10 | −0.40 | 0.83 | 0.57 | 0.87 | 0.79 | 0.99 | −0.35 | 0.15 | 0.85 | −0.01 | 1.00 | ||||||
Th | 0.27 | −0.23 | −0.19 | −0.24 | 0.68 | 0.32 | 0.40 | 0.00 | 0.41 | 0.80 | 0.12 | 0.04 | −0.18 | −0.19 | −0.11 | 0.83 | −0.33 | −0.28 | −0.08 | −0.40 | 0.68 | 0.51 | 0.75 | 0.72 | 0.83 | −0.38 | 0.29 | 0.69 | 0.00 | 0.87 | 1.00 | |||||
U | −0.67 | 0.63 | −0.64 | 0.65 | 0.28 | −0.15 | −0.53 | −0.66 | −0.09 | −0.09 | 0.13 | 0.06 | 0.06 | 0.32 | 0.46 | −0.09 | 0.29 | −0.03 | 0.09 | 0.47 | 0.21 | 0.18 | 0.30 | −0.08 | 0.03 | 0.32 | 0.34 | −0.02 | −0.73 | 0.04 | 0.04 | 1.00 | ||||
V | −0.43 | 0.39 | −0.28 | 0.42 | −0.08 | −0.13 | −0.44 | −0.38 | −0.21 | −0.39 | −0.09 | 0.01 | 0.10 | 0.16 | 0.39 | −0.40 | 0.70 | 0.32 | 0.15 | 0.42 | −0.18 | −0.23 | −0.19 | −0.26 | −0.40 | 0.37 | −0.08 | −0.39 | −0.35 | −0.42 | −0.35 | 0.17 | 1.00 | |||
Y | 0.36 | −0.30 | −0.12 | −0.36 | 0.73 | 0.50 | 0.59 | 0.09 | −0.02 | 0.99 | 0.23 | −0.06 | −0.21 | −0.13 | −0.09 | 1.00 | −0.51 | −0.18 | −0.21 | −0.45 | 0.78 | 0.48 | 0.77 | 0.83 | 0.95 | −0.42 | −0.06 | 0.89 | 0.11 | 0.95 | 0.82 | −0.09 | −0.41 | 1.00 | ||
Zn | −0.92 | 0.88 | −0.79 | 0.94 | 0.35 | −0.34 | −0.77 | −0.90 | −0.36 | −0.08 | 0.03 | 0.09 | 0.34 | 0.53 | 0.64 | −0.10 | 0.56 | 0.17 | 0.26 | 0.80 | 0.46 | 0.18 | 0.40 | −0.15 | 0.03 | 0.64 | 0.18 | −0.15 | −0.84 | 0.01 | −0.06 | 0.64 | 0.31 | −0.11 | 1.00 | |
Zr | 0.32 | −0.25 | −0.12 | −0.32 | 0.67 | 0.42 | 0.52 | 0.08 | −0.03 | 0.92 | 0.29 | 0.01 | −0.12 | −0.14 | −0.09 | 0.94 | −0.46 | −0.15 | −0.11 | −0.39 | 0.74 | 0.54 | 0.76 | 0.80 | 0.92 | −0.35 | −0.09 | 0.81 | 0.11 | 0.92 | 0.78 | −0.04 | −0.39 | 0.93 | −0.08 | 1.00 |
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Mikulski, S.Z.; Sadłowska, K.; Wiszniewska, J.; Małek, R. Vanadium and Cobalt Occurrence in the Fe-Ti-V Oxide Deposits Related to Mesoproterozoic AMCG Complex in NE Poland. Appl. Sci. 2022, 12, 6277. https://doi.org/10.3390/app12126277
Mikulski SZ, Sadłowska K, Wiszniewska J, Małek R. Vanadium and Cobalt Occurrence in the Fe-Ti-V Oxide Deposits Related to Mesoproterozoic AMCG Complex in NE Poland. Applied Sciences. 2022; 12(12):6277. https://doi.org/10.3390/app12126277
Chicago/Turabian StyleMikulski, Stanisław Z., Katarzyna Sadłowska, Janina Wiszniewska, and Rafał Małek. 2022. "Vanadium and Cobalt Occurrence in the Fe-Ti-V Oxide Deposits Related to Mesoproterozoic AMCG Complex in NE Poland" Applied Sciences 12, no. 12: 6277. https://doi.org/10.3390/app12126277
APA StyleMikulski, S. Z., Sadłowska, K., Wiszniewska, J., & Małek, R. (2022). Vanadium and Cobalt Occurrence in the Fe-Ti-V Oxide Deposits Related to Mesoproterozoic AMCG Complex in NE Poland. Applied Sciences, 12(12), 6277. https://doi.org/10.3390/app12126277