Mineralogical and Microstructure Analysis for Characterization and Provenance of Ceramic Artifacts from Late Helladic Kastrouli Settlement, Delphi (Central Greece)

The present study deals with the characterization of a ceramic assemblage from the Late Mycenaean (Late Helladic III) settlement of Kastrouli, at Desfina near Delphi, Central Greece using various analytical techniques. Kastrouli is located in a strategic position supervising the Mesokampos plateau and the entire peninsula and is related to other nearby coeval settlements. In total 40 ceramic sherds and 8 clay raw materials were analyzed through mineralogical, petrographic and microstructural techniques. Experimental briquettes (DS) made from clayey raw materials collected in the vicinity of Kastrouli, were fired under temperatures (900 and 1050 °C) in oxidizing conditions for comparison with the ancient ceramics. The petrographic analysis performed on thin sections prepared from the sherds has permitted the identification of six main fabric groups and a couple of loners. The aplastic inclusions recognized in all fabric groups but one confirmed the local provenance since they are related to the local geology. Fresh fractures of representative sherds were further examined under a scanning electron microscope (SEM/EDS) helping us to classify them into calcareous (CaO > 6%) and non-calcareous (CaO < 6%) samples (low and high calcium was noted in earlier pXRF data). Here, the ceramic sherds with broad calcium separation are explored on a one-to-one comparison on the basis of detailed mineralogical microstructure. Moreover, their microstructure was studied, aiming to estimate their vitrification stage. The mineralogy of all studied samples was determined by means of X-ray powder diffraction (XRPD), permitting us to test the validity of the firing temperatures revealed by the SEM analysis. The results obtained through the various analytical techniques employed are jointly assessed in order to reveal potters’ technological choices.