Effect of pH on Stress Corrosion Cracking of 6082 Al Alloy
Abstract
:1. Introduction
2. Materials and Methods
3. Results and Discussion
4. Conclusions
- The pH of the NaCl solution had a strong influence on the ultimate tensile strength and ductility of T6 treated 6082 Al alloy. In particular, a drop in the ultimate tensile strength and ductility was recorded in the alkaline pH, followed by the acidic. In the neutral pH, the influence was minimal when compared to the reference sample (experiments in air).
- Different stress corrosion cracking mechanisms occurred in the different pHs. In particular, a brittle and intergranular mode was observed on the outer layers of the alloy in the acidic pH, galvanic corrosion together with hydrogen embrittlement in the alkaline pH and mild intergranular corrosion along with ductile fracture in the neutral pH.
- The thickness of the brittle layer was observed to be dependent on the pH conditions, as it was thicker in the alkaline environment, followed by the acidic, whereas it was very limited in the neutral pH.
- In all examined SCC cases, an aluminum oxide (Al2O3) film was detected on the surface of T6 treated 6082 Al aluminum.
Author Contributions
Funding
Conflicts of Interest
References
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Material | Enviroment | pH | UTS (MPa) | ε (%) |
---|---|---|---|---|
6082-T6 Al alloy | 0.3 M NaCl | 3 | 341 ± 2 | 9.2 ± 0.42 |
6082-T6 Al alloy | 0.3 M NaCl | 7 | 349 ± 4 | 11.3 ± 0.57 |
6082-T6 Al alloy | 0.3 M NaCl | 10 | 312 ± 2 | 8.4 ± 0.46 |
6082-T6 Al alloy | air | - | 350 ± 3 | 12.1 ± 0.61 |
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Panagopoulos, C.N.; Georgiou, E.; Giannakopoulos, K.I.; Orfanos, P.G. Effect of pH on Stress Corrosion Cracking of 6082 Al Alloy. Metals 2018, 8, 578. https://doi.org/10.3390/met8080578
Panagopoulos CN, Georgiou E, Giannakopoulos KI, Orfanos PG. Effect of pH on Stress Corrosion Cracking of 6082 Al Alloy. Metals. 2018; 8(8):578. https://doi.org/10.3390/met8080578
Chicago/Turabian StylePanagopoulos, C. N., Emmanuel Georgiou, K. I. Giannakopoulos, and P. G. Orfanos. 2018. "Effect of pH on Stress Corrosion Cracking of 6082 Al Alloy" Metals 8, no. 8: 578. https://doi.org/10.3390/met8080578