3.1. Design, Simulation, and Manufacturing
The designed part (
Figure 2a) has a rounded geometry to avoid draft angles and to obtain a proper pattern removal without damaging the sand mould. When making the mould using the 3DP technique, it is unnecessary to consider these constraints due to the design freedom of the process. The part shape has a sufficient area-to-volume ratio to compare changes in the internal morphology due to cooling and solidification rates. The volume and weight of the part were 0.6 Kg and 223.4 cm
3, respectively.
The sand mould (
Figure 2b) was designed following standard rules [
20]. The mould incorporates a pouring cup, followed by a tapered sprue ending in a well. The runner distributes the molten material horizontally and is connected to the mould cavity by two vertical gates. The cross-section of the runner decreases linearly to distribute the flow uniformly. Finally, a top riser was placed in order to supply additional molten metal as it shrinks during solidification and to prevent porosity. The total volume of the sand mould was 1073 cm
3, and the metallic yield was 20.8%. In addition, the mould was contained in a box. A large volume of sand, weighing approximately 25 kg, was needed.
The 3DP technique makes it possible to optimize the filling system in the ceramic mould. The 3DP mould is a shell of 10-mm thickness, enough to withstand the pressure of the poured metal. The filling system consisted of a single duct with a smaller filling cup. This reduction was possible thanks to the placement of an open riser that allowed the pressure to decrease. In addition, the sprue was designed with a decreasing circular section that described an arc shape sufficiently large to avoid cavitation or turbulence [
21,
22]. Two cylindrical gates were connected to the part cavity [
23]. Due to this improvement, it was possible to eliminate the well and to decrease the dimensions of the filling system, as shown in
Figure 2c. The total volume of the 3DP mould was 449 cm
3, the metallic yield was 49.75%, and the weight of the mould was 0.55 kg. Compared to the sand casting, the metallic yield was optimized by 29% and the weight of the mould was 95% lower.
Table 3 shows a summary of the principal parameters of the casting parts and moulds.
The gating speed is the main factor considered to avoid metal turbulence, gas entrainment, and oxide films. Campbell [
24] indicated that the maximum gating speed should be 0.5 m/s during the filling process.
Figure 5 shows the filling speed field for both moulds during the filling process.
At the beginning of the filling process in the sand mould (
Figure 5a), the velocity of the liquid metal entering the part cavity through the gates was faster than the runner. This increase of speed produced a fountain effect. The speed in the ingates was above 0.5 m/s, producing severe turbulence. This increased the probability of gas entrainment and oxide films occurring [
25]. The bigger cross-section into the cavity made the velocity decrease. Although the turbulence decreased, a chaotic field was created. Finally, while the filling process was taking place, as the metal filled the mould, the metallostatic pressure was balanced due to the weight of the metal flow decreasing the velocity on the gates. In contrast, in the 3DP mould filling process (
Figure 5b), the liquid metal came into the part cavity through the gates at a lower speed than in the runner. This avoided the fountain effect inside the part cavity. The speed in the area of the gates remained stable at around 0.5 m/s throughout the filling cycle. This speed generated a moderate turbulence and minimized the risk of gas entrainment. Due to the optimization of the design and the placing of an open riser, the filling of the 3DP mould was progressive and homogeneous.
The gating speed at the cross-section of the ingate area was measured with the software during the filling process for both moulds.
Figure 6 indicates different velocities at the cutting plane in the centre of the ingates. This process was divided into four steps.
Stage I: A high input speed was generated for both techniques, reaching up to 1.10 m/s in sand casting and 0.55 m/s in 3DP casting.
Stage II: The speed decreased and remained constant during most of the filling process at around 0.90 m/s in sand casting and around 0.48 m/s in 3DP casting.
Stage III: The speed continued to decrease to 0.63 m/s in the sand casting technique. In 3DP casting, the speed remained constant at around 0.48 m/s.
Stage IV: For both techniques, the speed remained constant with regard to the previous values and drastically diminished on completing the filling process.
During Stage I, the ingate speed was higher than 0.50 m/s for both techniques. An input speed higher than 0.5 m/s creates turbulences in the surface of the metal, causing gas entrainment in this type of process. The fountain effect generated in the sand mould gave a maximum speed of 1.10 m/s. Sanitas et al. [
26] found that a high-pressure ratio along with a larger section area results in higher gate speed. Therefore, the risk of gas entrainment is very high. In contrast, the 3DP technique did not generate the fountain effect. The input speed in stage I of the filling process of the 3DP mould was 0.55 m/s, which was at the limit. It quickly descended and then became constant. Therefore, there was a very low risk of gas entrainment. The speed in the sand casting technique simulation remained at around 0.90 m/s during Stage II. In Stages III and IV, the speeds decreased with a moderate slope to 0.63 m/s. In these stages, the fountain effect disappeared but the filling was chaotic and the turbulence generated waves that overlapped each other. Bifilms, inclusion, and gas entrainment could be produced in the casting part for these turbulences. On the other hand, during the simulation of the 3DP technique, the speed in Stages II, III, and IV remained constant at around 0.5 m/s. This generated homogeneous filling with a moderate turbulence, minimizing the probability of generating gas entrainment, inclusions, or oxides. These simulations were in accordance with the porosity analysis of the manufactured parts.
The high-speed profile presented in the moulds during the filling process could generate erosion in different areas of the moulds. These areas of the moulds are ripped off, generating slag that could be trapped in the flow of molten metal. In the sand casting, the gate has a high probability of erosion due to the fountain effect (
Figure 7a). However, with the 3DP mould (
Figure 7b), the probability of erosion has been minimized due to better control of the velocity profile. On the other hand, in
Figure 7d, a slight probability of erosion appears at the base of the gate due to the homogeneous filling rate, which does not exist for the traditional mould (
Figure 7c). These simulations were in accordance with the inclusions found in the manufactured sand casting part.
Once the filling process of the moulds was complete, the parts solidified.
Figure 8 shows the temperature distribution calculated for both parts, immediately after the filling process. The liquid temperature at this moment was lower than the pouring temperature. The sand-casting temperature remained uniform in the part cavity at about 710 °C (
Figure 8a). However, the 3DP mould temperature was about 675 °C (
Figure 8b). The real temperature distribution measured in the moulds is shown in
Figure 9. The mould temperature increased during the filling process and decreased during the solidification process. The real measured temperature confirmed the results of the simulation for both moulds. A lower cooling rate was obtained in the sand mould due to the low thermal conductivity of the sand and the greater thickness of the mould. In contrast, the lower thickness and higher thermal conductivity of the 3DP mould facilitated the flow of heat.
The filling time and the solidification were very different between the two simulations due to the differences in the volumes of each cavity, in heat transmission, and in the thickness of the moulds. The filling time for the sand mould was 5.24 s and the solidification time was 541 s. For the 3DP mould, the filling time was 2.20 s and the solidification time was 378 s. A lower solidification time means a faster cooling ratio, resulting in higher productivity and better mechanical properties of castings.
Table 4 shows the manufacturing time of the parts. Manufacture of the sand casting part took 23.5 h, equivalent to approximately three working days. In contrast, manufacture of the 3DP casting part took 10 h or only two working days. To manufacture the sand mould, it was necessary to design and manufacture a two-part pattern and to smooth the surface of the pattern (
Figure 10a). In contrast, to manufacture the 3DP mould, it was necessary to prepare the file, print and clean the mould, and apply the heat treatment before pouring the metal (
Figure 10b).
AM is advantageous for manufacturing unique parts or short series.
Table 4 shows the time taken to perform each stage in detail. In addition, the 3DP mould preparation is more advantageous due to the free-form design and the reduction of manufacturing time, avoiding the human factor and the pattern manufacture.
3.4. Surface Porosity and Defects
To analyse the reason for the porosity in the castings, a longitudinal cut was made in the parts. The sectioned surfaces provided useful information on the formation of defects in the casting, such as inclusions, porosity, or shrinkage.
The sand casting part had two types of porosity: (i) gas entrapment, with full spherical pores resulting from a turbulent filling; most of the porosity in this part is featured by this morphology, and (ii) bifilms due to the folding in the layers of oxides contained in the molten metal.
(i) A speed greater than 0.5 m/s generated turbulence and, consequently, gas entrapment. In addition, the high filling speed with turbulence in the liquid metal increased the speed of air drag, causing porosity in the casting parts [
25]. The pores shown in
Figure 13a correspond to a typical spherical bubble morphology. The partial evaporation of the binder in the ceramic mould and the severe turbulence probably generated this kind of porosity. When the local pressure of gas in a mould exceeds the local metallostatic pressure of the liquid metal, a bubble is formed. These bubbles will ascend to areas of less pressure. Most of the pores due to gas entrapment in the sand casting part occurred in the upper areas. (ii) On the other hand, entrainment of oxide films is always surrounded by a thin layer of air. The folded oxide films may come from the furnace, liquid metal transport, or turbulence during the filling process [
31]. Bifilms have irregular and elongated shapes due to a repeated folding of the metal surface (
Figure 13b). The porosity was due to severe turbulence generated inside the mould as a consequence of the fountain effect.
In the case of the 3DP moulded part, two major types of pores were found: (i) a mixture between gas entrapment and shrinkage and (ii) shrinkage. Upadhyay et al. [
10] reaffirmed that the binder used in the 3DP technique is around 8%. The amount of volatile elements is higher than in traditional processes (1.4%). To eliminate moisture and volatile elements, heat treatment was applied. It consisted of heating the ceramic mould to a temperature of 250 °C during 1.5 h. These values were chosen based on previous studies, so that the main sources of gas were almost supressed. However, when the mould was exposed to the pouring temperature, the pressure at the metal–mould interface increased. The air contained in the mould cavity was heated and the binder vaporized, decomposed, and heated up [
32]. The open riser design helped the majority of the gas to escape. The ratio of generated gas during the filling process was very high. Therefore, the mould impeded the immediate release of gas pressure and may have caused gas entrapment. On the other hand, the design of the mould provided a very fast cooling. As pouring stopped, the metal continued to solidify and the pressure of the remaining liquid metal decreased. Nucleation points were formed due to the lower temperature of entrainment gas. In this way, pores may be formed by shrinkage and a mixture of shrinkage and gas entrainment (
Figure 13c,d).
Finally, the area occupied by the pores in the sand casting had an average surface porosity of 0.95%. On the other hand, the 3DP moulded part had a higher surface porosity with an average value of 1.63%. This difference may be due to the greater gas generation produced by reactions within the 3DP mould and faster solidification of the 3DP part. This phenomenon impeded the gas evacuation and created porosity.
Surface defects were observed only in the part manufactured with the sand mould (
Figure 14). One of the defects that could be found was the inclusion of sand, as can be observed in
Figure 14a. Sand areas were torn off by the metal stream, floated to the surface, and were then trapped by the molten metal. The main cause of this defect was attributed to an uneven compaction of the mould or a high liquid speed capable of damaging the mould. Another defect was flow marks (
Figure 14b). They were produced on the part surfaces and the defect appeared as lines which trace the flow stream of liquid metal. It could be produced by oxide films lodged at the surface. One of the advantages of manufacturing shell moulds by the 3DP technique is that mismatch errors disappear, and no joining lines are detected as occurs in the traditional sand casting technique.