Figure 1.
(
a) Map of the Kutná Hora ore district with major ore lodes, adapted from Malec and Pauliš [
25]. Each lode (“pásmo” in Czech, “Zug” in German) consists of several veins. (
b) map of Anthony of Padua mine, Kutná Hora, adapted from Koutek and Kutina [
26]. The blue-marked sections are ore-mineralized.
Figure 1.
(
a) Map of the Kutná Hora ore district with major ore lodes, adapted from Malec and Pauliš [
25]. Each lode (“pásmo” in Czech, “Zug” in German) consists of several veins. (
b) map of Anthony of Padua mine, Kutná Hora, adapted from Koutek and Kutina [
26]. The blue-marked sections are ore-mineralized.
Figure 2.
(a) Black ore (i) association (from the earliest to the latest mineral): galena (Gn), boulangerite (Bou), freieslebenite (Frs), diaphorite (Dia), pyrargyrite (Prg); (b) example of black ore (i) association with the general succession from the Pb-richest to Pb-poorer phases: galena (Gn) –boulangerite (Bou) – freieslebenite (Frs) – owyheeite (Ow) – fizélyite (Fiz) – Ag-excess fizélyite (Aef) – diaphorite (Dia); (c) a later-stage replacement of galena of black ore (i) by Ag-richer minerals following the succession: galena (white) – freieslebenite (Frs) – diaphorite (Dia) – freibergite (Frg) –miargyrite (Mia) – jamesonite (Jms); (d) needles of owyheeite (Ow) replaced by diaphorite (Dia) and Ag-excess fizélyite (Aef); all minerals are subsequently being replaced by miargyrite (Mia); (e) five Ag-minerals in one image: galena (Gn) replaced by freislebenite (Frs), diaphorite (Dia) and Ag-excess fizélyite (Aef), all replaced by miargyrite (Mia). Stephanite (Ste) is the latest mineral. (f) typical example of ore (iii) with prevailing miargyrite (Mia) in quartz gangue, remnants of galena (white) are replaced by diaphorite (Dia) which is subsequently replaced by miargyrite, locally with pyraragyrite inclusions (Prg); freibergite (Frg) is also present. All back-scattered electron images.
Figure 2.
(a) Black ore (i) association (from the earliest to the latest mineral): galena (Gn), boulangerite (Bou), freieslebenite (Frs), diaphorite (Dia), pyrargyrite (Prg); (b) example of black ore (i) association with the general succession from the Pb-richest to Pb-poorer phases: galena (Gn) –boulangerite (Bou) – freieslebenite (Frs) – owyheeite (Ow) – fizélyite (Fiz) – Ag-excess fizélyite (Aef) – diaphorite (Dia); (c) a later-stage replacement of galena of black ore (i) by Ag-richer minerals following the succession: galena (white) – freieslebenite (Frs) – diaphorite (Dia) – freibergite (Frg) –miargyrite (Mia) – jamesonite (Jms); (d) needles of owyheeite (Ow) replaced by diaphorite (Dia) and Ag-excess fizélyite (Aef); all minerals are subsequently being replaced by miargyrite (Mia); (e) five Ag-minerals in one image: galena (Gn) replaced by freislebenite (Frs), diaphorite (Dia) and Ag-excess fizélyite (Aef), all replaced by miargyrite (Mia). Stephanite (Ste) is the latest mineral. (f) typical example of ore (iii) with prevailing miargyrite (Mia) in quartz gangue, remnants of galena (white) are replaced by diaphorite (Dia) which is subsequently replaced by miargyrite, locally with pyraragyrite inclusions (Prg); freibergite (Frg) is also present. All back-scattered electron images.
Figure 3.
Graph Nchem value vs%and substitution (L%) for andorite group minerals.
Figure 3.
Graph Nchem value vs%and substitution (L%) for andorite group minerals.
Figure 4.
An exceptionally large grain of Se-rich Ag-excess fizélyite (Aef), 1500 μm across, with a variable Se content (0.31–1.23 wt.% of Se). Ag-excess fizélyite replaces earliest galena (Gn) and is replaced by freieslebenite (Frs).
Figure 4.
An exceptionally large grain of Se-rich Ag-excess fizélyite (Aef), 1500 μm across, with a variable Se content (0.31–1.23 wt.% of Se). Ag-excess fizélyite replaces earliest galena (Gn) and is replaced by freieslebenite (Frs).
Figure 5.
(a) Andorite IV (Ad4) replaces Ag-excess fizélyite (Aef); (b) grain of Ag-excess fizélyite (Aef) in kutnohorite of black ore (i) is replaced by andorite IV (Ad4), which is subsequently replaced by andorite VI (Ad6; ragged edges). Ag-excess fizélyite is further replaced by freieslebenite (Frs; right side of the grain); (c) galena (Gn) replaced by boulangerite (Bou) and owyheeite (Ow), both minerals subsequently replaced by Ag-excess fizélyite (Aef);(d) earliest galena (Gn) replaced by owyheeite (Ow), Ag-excess fizélyite (Aef) and diaphorite (Dia). All back-scattered electron images.
Figure 5.
(a) Andorite IV (Ad4) replaces Ag-excess fizélyite (Aef); (b) grain of Ag-excess fizélyite (Aef) in kutnohorite of black ore (i) is replaced by andorite IV (Ad4), which is subsequently replaced by andorite VI (Ad6; ragged edges). Ag-excess fizélyite is further replaced by freieslebenite (Frs; right side of the grain); (c) galena (Gn) replaced by boulangerite (Bou) and owyheeite (Ow), both minerals subsequently replaced by Ag-excess fizélyite (Aef);(d) earliest galena (Gn) replaced by owyheeite (Ow), Ag-excess fizélyite (Aef) and diaphorite (Dia). All back-scattered electron images.
Figure 6.
Graph Se/(S + Se) vs Ag (at.%) for andorite group minerals.
Figure 6.
Graph Se/(S + Se) vs Ag (at.%) for andorite group minerals.
Figure 7.
Graph Ag + Cu vs Sb + As (apfu) (a) and Ag + Cu vs Pb + Fe (apfu) (b) for owyheeite.
Figure 7.
Graph Ag + Cu vs Sb + As (apfu) (a) and Ag + Cu vs Pb + Fe (apfu) (b) for owyheeite.
Figure 8.
Grain of Ag-poor Ag-Pb-Sb sulfosalt (Aps, 3.3 wt.% Ag) in boulangerite (Bou) in association with jamesonite (Jms), Ag-excess fizélyite (Aef) and galena (Gn). The succession runs as: galena – boulangerite – jamesonite – Ag-poor Ag-Pb-Sb sulfosalt – Ag-excess fizélyite.
Figure 8.
Grain of Ag-poor Ag-Pb-Sb sulfosalt (Aps, 3.3 wt.% Ag) in boulangerite (Bou) in association with jamesonite (Jms), Ag-excess fizélyite (Aef) and galena (Gn). The succession runs as: galena – boulangerite – jamesonite – Ag-poor Ag-Pb-Sb sulfosalt – Ag-excess fizélyite.
Figure 9.
(
a) Graph Ag + Cu vs Pb + Fe (at.%) for Ag-poor Ag-Pb-Sb sulfosalts and owyheeite; boulangerite ideal composition Pb
5Sb
4S
11; T-tubulite ideal composition Ag
2Pb
22Sb
20S
53 [
47]; unnamed M3—Příbram [
48]; unnamed M2—Příbram [
48]; UM1979-14—Primorye [
49,
50]; UM1990-32; zoubekite ideal composition AgPb
4Sb
4S
10 [
46].(
b) graph Ag + Cu vs. Sb + As (at.%) for Ag-poor Ag-Pb-Sb sulfosalts and owyheeite; boulangerite ideal composition Pb
5Sb
4S
11; T-tubulite ideal composition Ag
2Pb
22Sb
20S
53 [
47]; unnamed M3—Příbram [
48]; unnamed M2—Příbram [
48]; UM1979-14—Primorye [
49]; UM1990-32 [
50]; zoubekite ideal composition AgPb
4Sb
4S
10 [
46].
Figure 9.
(
a) Graph Ag + Cu vs Pb + Fe (at.%) for Ag-poor Ag-Pb-Sb sulfosalts and owyheeite; boulangerite ideal composition Pb
5Sb
4S
11; T-tubulite ideal composition Ag
2Pb
22Sb
20S
53 [
47]; unnamed M3—Příbram [
48]; unnamed M2—Příbram [
48]; UM1979-14—Primorye [
49,
50]; UM1990-32; zoubekite ideal composition AgPb
4Sb
4S
10 [
46].(
b) graph Ag + Cu vs. Sb + As (at.%) for Ag-poor Ag-Pb-Sb sulfosalts and owyheeite; boulangerite ideal composition Pb
5Sb
4S
11; T-tubulite ideal composition Ag
2Pb
22Sb
20S
53 [
47]; unnamed M3—Příbram [
48]; unnamed M2—Příbram [
48]; UM1979-14—Primorye [
49]; UM1990-32 [
50]; zoubekite ideal composition AgPb
4Sb
4S
10 [
46].
Figure 10.
(a) Ag-excess fizélyite (Aef) replaces boulangerite (Bou) of black ore (i). (b) earliest galena (Gn) replaced by boulangerite (Bou) and semseyite (Sms); semseyite was subsequently replaced by freieslebenite (Frs) and diaphorite (Dia). Both back-scattered electron (BSE) images.
Figure 10.
(a) Ag-excess fizélyite (Aef) replaces boulangerite (Bou) of black ore (i). (b) earliest galena (Gn) replaced by boulangerite (Bou) and semseyite (Sms); semseyite was subsequently replaced by freieslebenite (Frs) and diaphorite (Dia). Both back-scattered electron (BSE) images.
Figure 11.
Graph Se/(Se + S) (apfu) vs Pb/total apfu for Pb-Sb sulfosalts.
Figure 11.
Graph Se/(Se + S) (apfu) vs Pb/total apfu for Pb-Sb sulfosalts.
Figure 12.
(a) Galena (Gn)—the earliest mineral in the association—is replaced by diaphorite (Dia), which is subsequently replaced by Ag-excess fizélyite (Aef). Both minerals are replaced by miargyrite (Mia), whereas miargyrite with1 wt.% Se (darker) is replaced by the the second-generation Se-rich miargyrite (lighter, 5% Se). (b) miargyrite (Mia) embedded in sphalerite (Sp). An argyrodite (Agd) inclusion is on the boundary between sphalerite and pyrite (Py), both minerals (miargyrite and argyrodite) replace sphalerite. Both back-scattered electron (BSE) images.
Figure 12.
(a) Galena (Gn)—the earliest mineral in the association—is replaced by diaphorite (Dia), which is subsequently replaced by Ag-excess fizélyite (Aef). Both minerals are replaced by miargyrite (Mia), whereas miargyrite with1 wt.% Se (darker) is replaced by the the second-generation Se-rich miargyrite (lighter, 5% Se). (b) miargyrite (Mia) embedded in sphalerite (Sp). An argyrodite (Agd) inclusion is on the boundary between sphalerite and pyrite (Py), both minerals (miargyrite and argyrodite) replace sphalerite. Both back-scattered electron (BSE) images.
Figure 13.
(a) Graph S vs Se (apfu) for two types of miargyrite. (b) graph Se/(S + Se) vs Ag (at.%) for Ag-Sb-S mineral phases.
Figure 13.
(a) Graph S vs Se (apfu) for two types of miargyrite. (b) graph Se/(S + Se) vs Ag (at.%) for Ag-Sb-S mineral phases.
Figure 14.
(a) An inclusion in pyrite (Py) of red ore (ii): stephanite (Ste), which is a prevailing mineral in the inclusion replaces pyrargyrite (Prg). Remnants of original galena (white spots) which was later replaced by pyrargyrite are visible at the bottom part of the grain. (b) euhedral crystal in pyrite (Py) of red ore (ii) formed by two Ag-rich mineral phases: naumannite (Nau) is replaced by stephanite (Ste). Both back-scattered electron (BSE) images.
Figure 14.
(a) An inclusion in pyrite (Py) of red ore (ii): stephanite (Ste), which is a prevailing mineral in the inclusion replaces pyrargyrite (Prg). Remnants of original galena (white spots) which was later replaced by pyrargyrite are visible at the bottom part of the grain. (b) euhedral crystal in pyrite (Py) of red ore (ii) formed by two Ag-rich mineral phases: naumannite (Nau) is replaced by stephanite (Ste). Both back-scattered electron (BSE) images.
Figure 15.
(a) Euhedral tabular crystal of polybasite (Plb) associated with Se-rich acanthite (Aca). Both minerals replace galena (Gn). (b) euhedral tabular crystal of polybasite (Plb) growing across galena, which occurs as anhedral inclusions up to several tens of μm in pyrite (Py) of red ore (ii). Both back-scattered electron (BSE) images.
Figure 15.
(a) Euhedral tabular crystal of polybasite (Plb) associated with Se-rich acanthite (Aca). Both minerals replace galena (Gn). (b) euhedral tabular crystal of polybasite (Plb) growing across galena, which occurs as anhedral inclusions up to several tens of μm in pyrite (Py) of red ore (ii). Both back-scattered electron (BSE) images.
Figure 16.
(a) Fractured mass of porous sphalerite (dark grey) contains fissures filled by veinlets of freibergite (medium grey) with exsolutions of Se-rich miargyrite (15 wt.% of Se, light grey) and members of galena–clausthalite solid solution (white) from Gal70–Claus30 (15 wt.% of Se) to Claus78–Gal22 (20 wt.% of Se). (b) freibergite (Frg) in quartz of red ore (ii) containing inclusions of clausthalite (Clh, 21.5% of Se) or members of galena-clausthalite solid solution (Gn, 14.2% of Se) and argyrodite (Agd, 9.8% of Se). Both back-scattered electron (BSE) images.
Figure 16.
(a) Fractured mass of porous sphalerite (dark grey) contains fissures filled by veinlets of freibergite (medium grey) with exsolutions of Se-rich miargyrite (15 wt.% of Se, light grey) and members of galena–clausthalite solid solution (white) from Gal70–Claus30 (15 wt.% of Se) to Claus78–Gal22 (20 wt.% of Se). (b) freibergite (Frg) in quartz of red ore (ii) containing inclusions of clausthalite (Clh, 21.5% of Se) or members of galena-clausthalite solid solution (Gn, 14.2% of Se) and argyrodite (Agd, 9.8% of Se). Both back-scattered electron (BSE) images.
Figure 17.
(a) Graph of Ag vs. Cu (apfu) for freibergite; (b) graph of Fe vs. Zn (apfu) for freibergite.
Figure 17.
(a) Graph of Ag vs. Cu (apfu) for freibergite; (b) graph of Fe vs. Zn (apfu) for freibergite.
Figure 18.
(a) Mass and veinlets of allargentum (Ala) and Sb-rich silver (Slv*); veinlets thicken up to form grains of pure Sb-free silver (Slv). Pyragyrite (Prg) forms euhedral masses and acanthite (Aca) forms veinlets and fillings around allargentum. Residues of original galena (Gn) are visible at the right side of the grain, the mineral is replaced by acanthite. (b) aguilarite (Agu, 18 wt.% of Se) replacing galena (Gn) in one of plentiful galena inclusions in pyrite of red ore (ii). Some of the inclusions are fully replaced by Se-rich acanthite (Aca*, 4 wt.% of Se), which forms a nearly continuous solid solution from acanthite with no Se (Aca) through Se-rich acanthite to aguilarite and naumannite. (c) diversity of inclusions in pyrite of red ore (ii); the larger inclusion shows the replacement of galena (white) by acanthite (dark grey). The smaller inclusion below is argyrodite. d) large inclusion of Se-rich acanthite (Aca), inclusion of galena (Gn) and an inclusion of an unnamed Ag-Cu-S phase (Acs) in pyrite (Py) of red ore (ii).
Figure 18.
(a) Mass and veinlets of allargentum (Ala) and Sb-rich silver (Slv*); veinlets thicken up to form grains of pure Sb-free silver (Slv). Pyragyrite (Prg) forms euhedral masses and acanthite (Aca) forms veinlets and fillings around allargentum. Residues of original galena (Gn) are visible at the right side of the grain, the mineral is replaced by acanthite. (b) aguilarite (Agu, 18 wt.% of Se) replacing galena (Gn) in one of plentiful galena inclusions in pyrite of red ore (ii). Some of the inclusions are fully replaced by Se-rich acanthite (Aca*, 4 wt.% of Se), which forms a nearly continuous solid solution from acanthite with no Se (Aca) through Se-rich acanthite to aguilarite and naumannite. (c) diversity of inclusions in pyrite of red ore (ii); the larger inclusion shows the replacement of galena (white) by acanthite (dark grey). The smaller inclusion below is argyrodite. d) large inclusion of Se-rich acanthite (Aca), inclusion of galena (Gn) and an inclusion of an unnamed Ag-Cu-S phase (Acs) in pyrite (Py) of red ore (ii).
Figure 19.
Graph Se vs. S (at.%) for acanthite, aguilarite and naumannite.
Figure 19.
Graph Se vs. S (at.%) for acanthite, aguilarite and naumannite.
Figure 20.
(a) Larger inclusion in pyrite of red ore (ii): clausthalite (Clh, 19.6% of Se) and naumannite (Nau, 23.9 wt.% of Se) replace selenian miargyrite (Mia, 8.7 wt.% of Se). Smaller inclusion: naumannite and selenian stephanite (Ste, 9.8 wt.% of Se) replace an intermediate member of galena–clausthalite solid solution (Gn, 13.9% of Se, 5.3% of S). (b) Se-rich argyrodite (Agd, 4.9 wt.% of Se) bordering on freibergite (Frg) in a galena (Gn) inclusion in pyrite of red ore (ii). Argyrodite and freibergite replace galena, both minerals are rimmed by pyrite (Py).
Figure 20.
(a) Larger inclusion in pyrite of red ore (ii): clausthalite (Clh, 19.6% of Se) and naumannite (Nau, 23.9 wt.% of Se) replace selenian miargyrite (Mia, 8.7 wt.% of Se). Smaller inclusion: naumannite and selenian stephanite (Ste, 9.8 wt.% of Se) replace an intermediate member of galena–clausthalite solid solution (Gn, 13.9% of Se, 5.3% of S). (b) Se-rich argyrodite (Agd, 4.9 wt.% of Se) bordering on freibergite (Frg) in a galena (Gn) inclusion in pyrite of red ore (ii). Argyrodite and freibergite replace galena, both minerals are rimmed by pyrite (Py).
Figure 21.
(a) Oval inclusion of unnamed Ag-Cu-(S,Se) phase (Acs) in pyrite (Py) of red ore (ii). (b) bubble-shaped inclusions in pyrite of red ore (ii). Plentiful small inclusions in pyrite are formed—apart from predominant galena and occasional acanthite—by argyrodite, freibergite (Ge,Se)-rich acanthite, clausthalite, naumannite, polybasite, pyrargyrite and unnamed Ag-Cu-S phases. Both back-scattered electron (BSE) images.
Figure 21.
(a) Oval inclusion of unnamed Ag-Cu-(S,Se) phase (Acs) in pyrite (Py) of red ore (ii). (b) bubble-shaped inclusions in pyrite of red ore (ii). Plentiful small inclusions in pyrite are formed—apart from predominant galena and occasional acanthite—by argyrodite, freibergite (Ge,Se)-rich acanthite, clausthalite, naumannite, polybasite, pyrargyrite and unnamed Ag-Cu-S phases. Both back-scattered electron (BSE) images.
Figure 22.
(
a) Graph Ag vs. Cu (at.%) for Ag-Cu-S mineral phases; composition range for mckinstryite are given from [
70]; (
b) graph Cu/Ag vs. S + Se (at.%) for Ag-Cu-S mineral; composition range for mckinstryite are given from [
70].
Figure 22.
(
a) Graph Ag vs. Cu (at.%) for Ag-Cu-S mineral phases; composition range for mckinstryite are given from [
70]; (
b) graph Cu/Ag vs. S + Se (at.%) for Ag-Cu-S mineral; composition range for mckinstryite are given from [
70].
Figure 23.
Graph Ag + Au vs. Sb (at.%) for Ag-Sb minerals.
Figure 23.
Graph Ag + Au vs. Sb (at.%) for Ag-Sb minerals.
Figure 24.
(a) Two grains of Au-rich silver (white) in miargyrite (Mia) show signs of crystal shape. Veinlets in miargyrite are filled in by stephanite (Ste); (b) Au-rich silver (white) associated with freibergite (Frg) in sphalerite (Sp) of red ore (ii). This (semi-euhedral) grain is the largest individual grain (40 mm across) and also a grain with the highest Au content (56.0 wt.%, i.e., 42.5 at.% of Au). Both back-scattered electron (BSE) images.
Figure 24.
(a) Two grains of Au-rich silver (white) in miargyrite (Mia) show signs of crystal shape. Veinlets in miargyrite are filled in by stephanite (Ste); (b) Au-rich silver (white) associated with freibergite (Frg) in sphalerite (Sp) of red ore (ii). This (semi-euhedral) grain is the largest individual grain (40 mm across) and also a grain with the highest Au content (56.0 wt.%, i.e., 42.5 at.% of Au). Both back-scattered electron (BSE) images.
Figure 25.
(a) Grain of uytenbogaardtite (Uyt) in miargyrite (Mia), inclusions of Au rich silver (white) are visible at the left edge of the grain. (b) grain of Au-rich dyscrasite (Dys) in quartz of red ore (ii). Au-rich dycrasite (3.7–4.1 wt.% of Au) replaces acanthite (Aca). Both back-scattered electron (BSE) images.
Figure 25.
(a) Grain of uytenbogaardtite (Uyt) in miargyrite (Mia), inclusions of Au rich silver (white) are visible at the left edge of the grain. (b) grain of Au-rich dyscrasite (Dys) in quartz of red ore (ii). Au-rich dycrasite (3.7–4.1 wt.% of Au) replaces acanthite (Aca). Both back-scattered electron (BSE) images.
Figure 26.
(a) Graph Ag vs Sb (apfu) for members of galena – clausthalite solid solution. (b) graph Se vs S (apfu) for members of galena – clausthalite solid solution.
Figure 26.
(a) Graph Ag vs Sb (apfu) for members of galena – clausthalite solid solution. (b) graph Se vs S (apfu) for members of galena – clausthalite solid solution.
Figure 27.
The general succession in Se-enriched black ore (i); clausthalite (Clh—16 wt.% of Se) and Se-rich galena (Gn, 2% Se) replaced by freieslebenite (Frs, 0.3% Se) and diaforite (Dia, 3.5% of Se). Back-scattered electron (BSE) image.
Figure 27.
The general succession in Se-enriched black ore (i); clausthalite (Clh—16 wt.% of Se) and Se-rich galena (Gn, 2% Se) replaced by freieslebenite (Frs, 0.3% Se) and diaforite (Dia, 3.5% of Se). Back-scattered electron (BSE) image.
Figure 28.
Graph Se/(Se + S) vs. (Ag + Sb)/(Ag + Sb + Pb) (apfu) for members of galena – clausthalite solid solution.
Figure 28.
Graph Se/(Se + S) vs. (Ag + Sb)/(Ag + Sb + Pb) (apfu) for members of galena – clausthalite solid solution.
Table 1.
EPMA data for diaphorite.
Table 1.
EPMA data for diaphorite.
Analyses | wt.% | apfu Ʃ16 Atoms |
---|
Ag | Pb | Sb | As | Se | S | Total | Ag | Pb | Sb | As | Se | S |
---|
477 | 24.21 | 29.15 | 26.95 | 0.05 | 0.27 | 18.86 | 99.48 | 3.04 | 1.91 | 3.00 | 0.01 | 0.05 | 7.97 |
1107 | 23.63 | 28.95 | 27.22 | 0.09 | 0.42 | 18.73 | 99.03 | 2.98 | 1.90 | 3.05 | 0.02 | 0.07 | 7.96 |
1106 | 23.96 | 28.74 | 27.60 | 0.03 | 0.45 | 18.55 | 99.33 | 3.03 | 1.89 | 3.09 | 0.01 | 0.08 | 7.89 |
1733 | 23.84 | 28.99 | 27.36 | 0.18 | 0.46 | 18.49 | 99.32 | 3.02 | 1.91 | 3.07 | 0.03 | 0.08 | 7.87 |
1850 | 23.43 | 29.41 | 27.34 | 0.15 | 0.53 | 18.75 | 99.60 | 2.95 | 1.93 | 3.05 | 0.03 | 0.09 | 7.93 |
727 | 24.01 | 28.87 | 27.02 | 0.10 | 0.56 | 18.82 | 99.38 | 3.01 | 1.89 | 3.01 | 0.02 | 0.10 | 7.95 |
1660 | 24.23 | 29.38 | 27.55 | 0.17 | 0.65 | 18.59 | 100.56 | 3.03 | 1.91 | 3.06 | 0.03 | 0.11 | 7.83 |
1223 | 24.31 | 28.52 | 27.23 | 0.09 | 0.99 | 18.47 | 99.61 | 3.05 | 1.86 | 3.03 | 0.02 | 0.17 | 7.80 |
2116 | 23.53 | 29.30 | 27.21 | 0.00 | 1.08 | 18.37 | 99.49 | 2.98 | 1.93 | 3.05 | 0.00 | 0.19 | 7.83 |
1886 | 24.24 | 29.53 | 27.49 | 0.00 | 1.29 | 18.71 | 101.25 | 3.01 | 1.91 | 3.02 | 0.01 | 0.22 | 7.82 |
799 | 24.08 | 29.20 | 27.61 | 0.06 | 1.64 | 18.37 | 100.97 | 3.01 | 1.90 | 3.06 | 0.01 | 0.28 | 7.72 |
800 | 24.42 | 29.31 | 27.83 | 0.05 | 1.71 | 18.44 | 101.76 | 3.03 | 1.89 | 3.06 | 0.01 | 0.29 | 7.69 |
Table 2.
EPMA data for freieslebenite.
Table 2.
EPMA data for freieslebenite.
Analyses | wt.% | apfu Ʃ6 Atoms |
---|
Ag | Pb | Sb | As | Se | S | Total | Ag | Pb | Sb | As | Se | S |
---|
569 | 20.50 | 37.96 | 23.61 | 0.08 | 0.28 | 18.39 | 100.82 | 0.99 | 0.96 | 1.01 | 0.01 | 0.02 | 3.00 |
1737 | 20.17 | 38.44 | 23.19 | 0.13 | 0.38 | 17.99 | 100.30 | 0.99 | 0.98 | 1.01 | 0.01 | 0.03 | 2.97 |
1861 | 20.14 | 38.57 | 23.33 | 0.15 | 0.40 | 18.21 | 100.80 | 0.98 | 0.98 | 1.01 | 0.01 | 0.03 | 2.99 |
1205 | 20.18 | 38.14 | 23.31 | 0.09 | 0.41 | 17.91 | 100.03 | 0.99 | 0.98 | 1.02 | 0.01 | 0.03 | 2.97 |
610 | 20.59 | 37.90 | 23.27 | 0.06 | 0.42 | 17.90 | 100.14 | 1.01 | 0.97 | 1.01 | 0.00 | 0.03 | 2.96 |
429 | 20.37 | 38.21 | 23.06 | 0.12 | 0.44 | 18.03 | 100.24 | 1.00 | 0.97 | 1.00 | 0.01 | 0.03 | 2.97 |
713 | 20.37 | 38.41 | 23.14 | 0.06 | 0.45 | 17.98 | 100.41 | 1.00 | 0.98 | 1.00 | 0.00 | 0.03 | 2.96 |
430 | 20.50 | 37.94 | 22.89 | 0.16 | 0.55 | 17.89 | 99.93 | 1.01 | 0.97 | 1.00 | 0.01 | 0.04 | 2.96 |
2149 | 20.13 | 37.90 | 23.15 | 0.00 | 0.66 | 17.83 | 99.67 | 0.99 | 0.97 | 1.01 | 0.00 | 0.04 | 2.96 |
2152 | 20.33 | 37.75 | 22.89 | 0.00 | 0.71 | 17.49 | 99.17 | 1.01 | 0.98 | 1.01 | 0.00 | 0.05 | 2.93 |
Table 3.
EPMA data for of Ag-excess fizélyite.
Table 3.
EPMA data for of Ag-excess fizélyite.
Analyses | wt.% | apfu Ʃ88 Atoms |
---|
Ag | Pb | Fe | Cd | Mn | Sb | Se | S | Total | Ag | Pb | Fe | Cd | Mn | Sb | Se | S | N | L% |
---|
1868 | 7.86 | 37.19 | 0.49 | 0.00 | 0.12 | 33.51 | 0.06 | 20.70 | 100.12 | 5.39 | 13.29 | 0.65 | 0.00 | 0.16 | 20.38 | 0.05 | 47.80 | 4.29 | 62.36 |
1496 | 8.63 | 37.28 | 0.10 | 0.00 | 0.05 | 33.12 | 0.28 | 20.22 | 99.86 | 6.01 | 13.51 | 0.13 | 0.00 | 0.07 | 20.43 | 0.27 | 47.35 | 4.50 | 65.88 |
767 | 8.37 | 37.46 | 0.14 | 0.21 | 0.05 | 32.74 | 0.35 | 20.24 | 99.67 | 5.82 | 13.56 | 0.19 | 0.14 | 0.06 | 20.16 | 0.33 | 47.34 | 4.58 | 62.68 |
1392 | 7.84 | 38.31 | 0.13 | 0.00 | 0.20 | 32.23 | 0.46 | 20.07 | 99.36 | 5.50 | 13.99 | 0.17 | 0.00 | 0.27 | 20.03 | 0.44 | 47.35 | 4.54 | 60.74 |
1955 | 8.20 | 37.20 | 0.11 | 0.00 | 0.05 | 33.77 | 0.70 | 20.24 | 100.33 | 5.68 | 13.42 | 0.15 | 0.00 | 0.07 | 20.73 | 0.66 | 47.18 | 4.31 | 65.29 |
594 | 8.51 | 35.97 | 0.46 | 0.02 | 0.14 | 34.03 | 0.75 | 20.13 | 100.10 | 5.86 | 12.89 | 0.62 | 0.01 | 0.19 | 20.76 | 0.71 | 46.60 | 4.45 | 64.55 |
647 | 8.79 | 38.52 | 0.08 | 0.00 | 0.04 | 32.45 | 0.85 | 20.07 | 100.86 | 6.10 | 13.93 | 0.11 | 0.00 | 0.05 | 19.97 | 0.80 | 46.88 | 4.83 | 63.19 |
1920 | 7.99 | 37.65 | 0.71 | 0.00 | 0.03 | 32.84 | 0.96 | 19.79 | 100.03 | 5.57 | 13.67 | 0.95 | 0.00 | 0.05 | 20.29 | 0.91 | 46.43 | 4.50 | 60.53 |
781 | 8.52 | 36.31 | 0.21 | 0.00 | 0.06 | 33.38 | 1.26 | 20.01 | 99.84 | 5.91 | 13.11 | 0.29 | 0.00 | 0.09 | 20.52 | 1.19 | 46.71 | 4.49 | 65.84 |
641 | 8.29 | 37.58 | 0.11 | 0.00 | 0.04 | 32.86 | 1.66 | 19.65 | 100.19 | 5.80 | 13.70 | 0.14 | 0.00 | 0.06 | 20.39 | 1.59 | 46.29 | 4.50 | 63.74 |
783 | 8.86 | 36.07 | 0.19 | 0.00 | 0.05 | 33.39 | 1.87 | 19.70 | 100.33 | 6.14 | 13.02 | 0.25 | 0.00 | 0.07 | 20.51 | 1.77 | 45.95 | 4.63 | 67.05 |
784 | 8.76 | 36.52 | 0.11 | 0.00 | 0.05 | 33.03 | 2.05 | 19.57 | 100.31 | 6.09 | 13.23 | 0.15 | 0.00 | 0.07 | 20.37 | 1.95 | 45.82 | 4.70 | 66.34 |
1148 | 8.71 | 36.68 | 0.05 | 0.00 | 0.02 | 31.99 | 2.86 | 19.14 | 99.47 | 6.14 | 13.47 | 0.06 | 0.00 | 0.03 | 19.99 | 2.75 | 45.42 | 4.73 | 64.83 |
1144 | 8.72 | 36.93 | 0.02 | 0.00 | 0.00 | 32.71 | 3.50 | 18.84 | 100.75 | 6.13 | 13.50 | 0.03 | 0.00 | 0.00 | 20.35 | 3.36 | 44.51 | 4.64 | 65.70 |
1145 | 8.82 | 36.93 | 0.03 | 0.00 | 0.00 | 32.61 | 3.49 | 18.63 | 100.53 | 6.23 | 13.58 | 0.03 | 0.00 | 0.00 | 20.41 | 3.37 | 44.27 | 4.70 | 65.69 |
1143 | 9.07 | 37.30 | 0.02 | 0.00 | 0.01 | 33.11 | 4.69 | 18.63 | 102.91 | 6.28 | 13.43 | 0.03 | 0.00 | 0.01 | 20.29 | 4.43 | 43.34 | 4.73 | 65.98 |
Table 4.
EPMA data for fizélyite.
Table 4.
EPMA data for fizélyite.
Analyses | wt.% | apfu Ʃ88 Atoms |
---|
Ag | Pb | Fe | Cd | Mn | Sb | Se | S | Total | Ag | Pb | Fe | Cd | Mn | Sb | Se | S | N | L% |
---|
556 | 6.90 | 37.65 | 0.65 | 0.36 | 0.07 | 33.84 | 0.21 | 20.84 | 100.57 | 4.72 | 13.39 | 0.86 | 0.24 | 0.09 | 20.49 | 0.20 | 47.91 | 4.05 | 58.51 |
479 | 6.98 | 37.56 | 0.53 | 0.04 | 0.07 | 33.30 | 0.23 | 19.93 | 98.62 | 4.93 | 13.80 | 0.72 | 0.02 | 0.10 | 20.83 | 0.23 | 47.32 | 4.08 | 59.54 |
1172 | 7.46 | 37.95 | 0.38 | 0.00 | 0.09 | 33.92 | 0.25 | 20.63 | 100.74 | 5.12 | 13.57 | 0.50 | 0.00 | 0.12 | 20.64 | 0.24 | 47.68 | 4.15 | 61.58 |
729 | 6.71 | 37.18 | 0.94 | 0.01 | 0.06 | 33.33 | 0.32 | 20.42 | 99.03 | 4.65 | 13.43 | 1.26 | 0.01 | 0.08 | 20.49 | 0.30 | 47.65 | 4.02 | 58.00 |
1903 | 7.43 | 37.71 | 0.45 | 0.00 | 0.01 | 34.19 | 0.72 | 20.44 | 101.05 | 5.10 | 13.48 | 0.60 | 0.00 | 0.02 | 20.79 | 0.68 | 47.19 | 4.10 | 62.23 |
2062 | 7.11 | 36.56 | 0.57 | 0.00 | 0.03 | 33.33 | 1.20 | 19.25 | 98.06 | 5.07 | 13.58 | 0.79 | 0.00 | 0.04 | 21.07 | 1.17 | 46.22 | 4.06 | 61.44 |
Table 5.
EPMA data for andorite IV.
Table 5.
EPMA data for andorite IV.
Analyses | wt.% | apfu Ʃ88 Atoms |
---|
Ag | Pb | Fe | Sb | As | Se | S | Total | Ag | Pb | Fe | Sb | As | Se | S | N | L% |
---|
947 | 11.28 | 25.41 | 0.13 | 40.50 | 0.00 | 0.22 | 21.77 | 99.31 | 3.69 | 4.33 | 0.08 | 11.75 | 0.01 | 0.10 | 23.97 | 3.95 | 94.65 |
1160 | 11.54 | 25.95 | 0.19 | 40.72 | 0.07 | 0.30 | 22.03 | 100.79 | 3.72 | 4.36 | 0.12 | 11.64 | 0.03 | 0.13 | 23.92 | 4.02 | 93.28 |
1899 | 11.29 | 26.58 | 0.16 | 40.80 | 0.08 | 0.36 | 21.62 | 100.87 | 3.68 | 4.51 | 0.10 | 11.77 | 0.04 | 0.16 | 23.69 | 3.96 | 92.96 |
953 | 10.99 | 25.94 | 0.06 | 40.02 | 0.00 | 0.37 | 21.34 | 98.71 | 3.65 | 4.48 | 0.04 | 11.76 | 0.02 | 0.17 | 23.81 | 3.93 | 93.79 |
1742 | 11.28 | 26.02 | 0.11 | 40.57 | 0.14 | 0.45 | 21.60 | 100.18 | 3.69 | 4.43 | 0.07 | 11.75 | 0.07 | 0.20 | 23.75 | 3.95 | 94.22 |
1743 | 11.21 | 26.06 | 0.12 | 40.06 | 0.17 | 0.45 | 21.45 | 99.52 | 3.69 | 4.47 | 0.08 | 11.68 | 0.08 | 0.20 | 23.75 | 3.97 | 93.31 |
950 | 11.16 | 25.48 | 0.12 | 40.40 | 0.06 | 0.46 | 21.47 | 99.14 | 3.68 | 4.37 | 0.07 | 11.79 | 0.03 | 0.21 | 23.79 | 3.92 | 94.78 |
1722 | 11.05 | 26.62 | 0.07 | 40.34 | 0.12 | 0.52 | 21.29 | 100.00 | 3.64 | 4.57 | 0.05 | 11.78 | 0.05 | 0.23 | 23.61 | 3.92 | 93.13 |
1586 | 11.07 | 27.03 | 0.14 | 39.41 | 0.17 | 0.61 | 20.99 | 99.42 | 3.69 | 4.69 | 0.09 | 11.62 | 0.08 | 0.28 | 23.51 | 4.01 | 91.59 |
1587 | 11.18 | 26.91 | 0.06 | 40.35 | 0.13 | 0.62 | 21.25 | 100.49 | 3.68 | 4.61 | 0.04 | 11.76 | 0.06 | 0.28 | 23.51 | 3.94 | 93.21 |
2146 | 11.44 | 25.55 | 0.12 | 39.72 | 0.00 | 0.90 | 20.92 | 98.65 | 3.81 | 4.44 | 0.08 | 11.73 | 0.00 | 0.41 | 23.47 | 4.07 | 92.95 |
2156 | 11.37 | 25.36 | 0.13 | 39.71 | 0.00 | 1.20 | 20.64 | 98.41 | 3.81 | 4.43 | 0.08 | 11.80 | 0.00 | 0.55 | 23.29 | 4.04 | 93.40 |
2155 | 11.46 | 25.34 | 0.10 | 39.71 | 0.00 | 1.76 | 20.26 | 98.63 | 3.86 | 4.44 | 0.07 | 11.84 | 0.00 | 0.81 | 22.95 | 4.07 | 93.54 |
Table 6.
EPMA data for andorite VI.
Table 6.
EPMA data for andorite VI.
Analyses | wt.% | apfu Ʃ11 Atoms |
---|
Ag | Pb | Fe | Sb | As | Se | S | Total | Ag | Pb | Fe | Sb | As | Se | S | N | L% |
---|
1273 | 11.75 | 24.02 | 0.07 | 41.89 | 0.08 | 0.14 | 22.08 | 100.02 | 0.95 | 1.01 | 0.01 | 3.00 | 0.01 | 0.02 | 6.00 | 3.86 | 100.07 |
1300 | 11.84 | 23.07 | 0.09 | 41.32 | 0.05 | 0.21 | 22.12 | 98.70 | 0.96 | 0.98 | 0.01 | 2.97 | 0.01 | 0.02 | 6.04 | 3.90 | 100.67 |
2075 | 11.99 | 23.36 | 0.07 | 41.56 | 0.00 | 0.22 | 21.27 | 98.47 | 0.99 | 1.01 | 0.01 | 3.04 | 0.00 | 0.02 | 5.91 | 3.92 | 100.50 |
1299 | 12.11 | 23.64 | 0.06 | 42.03 | 0.07 | 0.23 | 22.10 | 100.22 | 0.97 | 0.99 | 0.01 | 3.00 | 0.01 | 0.02 | 5.98 | 3.93 | 100.36 |
2076 | 11.88 | 23.15 | 0.06 | 41.68 | 0.00 | 0.24 | 21.42 | 98.43 | 0.98 | 0.99 | 0.01 | 3.04 | 0.00 | 0.03 | 5.94 | 3.87 | 101.52 |
1291 | 11.89 | 23.48 | 0.10 | 41.88 | 0.02 | 0.26 | 22.12 | 99.75 | 0.96 | 0.99 | 0.02 | 2.99 | 0.00 | 0.03 | 6.00 | 3.89 | 100.69 |
1769 | 11.95 | 24.51 | 0.08 | 41.89 | 0.15 | 0.32 | 21.93 | 100.83 | 0.96 | 1.03 | 0.01 | 2.99 | 0.02 | 0.03 | 5.94 | 3.91 | 98.87 |
1745 | 12.08 | 23.78 | 0.07 | 41.83 | 0.17 | 0.34 | 21.83 | 100.09 | 0.98 | 1.00 | 0.01 | 3.00 | 0.02 | 0.04 | 5.94 | 3.92 | 100.30 |
2065 | 12.03 | 23.45 | 0.07 | 41.67 | 0.00 | 0.88 | 20.97 | 99.07 | 0.99 | 1.01 | 0.01 | 3.05 | 0.00 | 0.10 | 5.83 | 3.93 | 100.42 |
2164 | 11.91 | 23.25 | 0.05 | 41.53 | 0.00 | 0.94 | 21.02 | 98.70 | 0.98 | 1.00 | 0.01 | 3.04 | 0.00 | 0.11 | 5.84 | 3.90 | 100.86 |
2166 | 11.80 | 23.69 | 0.07 | 40.92 | 0.00 | 1.31 | 20.47 | 98.26 | 0.99 | 1.03 | 0.01 | 3.04 | 0.00 | 0.15 | 5.77 | 3.95 | 98.91 |
Table 7.
EPMA data for owyeeite.
Table 7.
EPMA data for owyeeite.
Analyses | wt.% | apfu Ʃ52 Atoms |
---|
Ag | Pb | Fe | Sb | As | Se | S | Total | Ag | Cu | Pb | Fe | Sb | As | Se | S |
---|
822 | 6.70 | 44.08 | 0.09 | 28.90 | 0.00 | 0.21 | 19.34 | 99.32 | 2.88 | 0.03 | 9.86 | 0.08 | 11.00 | 0.03 | 0.12 | 27.95 |
1004 | 6.81 | 43.21 | 0.00 | 29.59 | 0.07 | 0.54 | 19.50 | 99.72 | 2.90 | 0.01 | 9.56 | 0.03 | 11.15 | 0.04 | 0.31 | 27.89 |
1193 | 6.87 | 43.79 | 0.05 | 29.42 | 0.00 | 1.14 | 19.45 | 100.72 | 2.90 | 0.02 | 9.63 | 0.04 | 11.01 | 0.02 | 0.66 | 27.65 |
1190 | 6.92 | 43.69 | 0.11 | 29.51 | 0.00 | 0.93 | 19.36 | 100.51 | 2.93 | 0.03 | 9.64 | 0.09 | 11.09 | 0.01 | 0.54 | 27.61 |
1195 | 6.98 | 44.06 | 0.00 | 29.80 | 0.07 | 0.96 | 19.45 | 101.32 | 2.94 | 0.02 | 9.67 | 0.02 | 11.13 | 0.04 | 0.55 | 27.58 |
1192 | 6.97 | 43.36 | 0.05 | 29.55 | 0.08 | 1.09 | 19.26 | 100.35 | 2.96 | 0.01 | 9.59 | 0.04 | 11.12 | 0.05 | 0.63 | 27.53 |
1191 | 6.98 | 43.51 | 0.00 | 29.50 | 0.06 | 1.04 | 19.30 | 100.38 | 2.96 | 0.01 | 9.62 | 0.03 | 11.10 | 0.04 | 0.60 | 27.58 |
1194 | 7.06 | 43.39 | 0.00 | 29.51 | 0.07 | 1.11 | 19.26 | 100.41 | 3.00 | 0.02 | 9.59 | 0.03 | 11.10 | 0.04 | 0.64 | 27.51 |
1188 | 7.10 | 43.64 | 0.08 | 29.76 | 0.00 | 0.97 | 19.31 | 100.87 | 3.01 | 0.02 | 9.62 | 0.07 | 11.16 | 0.02 | 0.56 | 27.50 |
712 | 7.19 | 43.18 | 0.26 | 29.58 | 0.07 | 0.93 | 19.29 | 100.51 | 3.04 | 0.03 | 9.52 | 0.21 | 11.09 | 0.04 | 0.54 | 27.47 |
1511 | 7.14 | 43.05 | 0.00 | 29.52 | 0.12 | 1.09 | 18.95 | 99.86 | 3.06 | 0.03 | 9.60 | 0.02 | 11.20 | 0.07 | 0.64 | 27.31 |
1698 | 7.23 | 44.14 | 0.00 | 28.86 | 0.16 | 0.42 | 19.40 | 100.20 | 3.08 | 0.06 | 9.78 | 0.01 | 10.89 | 0.10 | 0.24 | 27.79 |
1503 | 7.24 | 42.30 | 0.07 | 29.70 | 0.09 | 0.93 | 19.10 | 99.43 | 3.09 | 0.03 | 9.41 | 0.06 | 11.24 | 0.06 | 0.55 | 27.45 |
1512 | 7.24 | 42.51 | 0.00 | 29.69 | 0.19 | 1.63 | 18.79 | 100.03 | 3.10 | 0.01 | 9.47 | 0.00 | 11.26 | 0.12 | 0.95 | 27.05 |
2095 | 7.47 | 42.21 | 0.00 | 30.38 | 0.00 | 0.44 | 19.35 | 99.85 | 3.18 | 0.02 | 9.35 | 0.03 | 11.45 | 0.00 | 0.26 | 27.69 |
Table 8.
EPMA data for Ag-poor Ag-Pb-Sb sulfosalts.
Table 8.
EPMA data for Ag-poor Ag-Pb-Sb sulfosalts.
Analyses | wt% | apfu Ʃ52 Atoms |
---|
Ag | Pb | Fe | Sb | As | Se | S | Total | Ag | Cu | Pb | Fe | Sb | As | Se | S |
---|
495 | 0.87 | 49.27 | 1.95 | 27.19 | 0.00 | 0.32 | 19.84 | 99.43 | 0.37 | 0.01 | 10.93 | 1.60 | 10.27 | 0.02 | 0.19 | 28.44 |
1513 | 1.05 | 52.45 | 0.09 | 27.14 | 0.10 | 0.95 | 18.81 | 100.59 | 0.46 | 0.01 | 12.01 | 0.08 | 10.58 | 0.06 | 0.57 | 27.83 |
1325 | 1.17 | 52.47 | 0.46 | 26.70 | 0.00 | 0.55 | 18.94 | 100.29 | 0.52 | 0.02 | 12.06 | 0.39 | 10.45 | 0.02 | 0.33 | 28.14 |
904 | 1.18 | 51.61 | 0.00 | 28.04 | 0.00 | 0.44 | 18.37 | 99.63 | 0.53 | 0.01 | 12.10 | 0.03 | 11.18 | 0.00 | 0.27 | 27.82 |
1559 | 2.02 | 51.78 | 0.00 | 27.01 | 0.09 | 0.37 | 18.33 | 99.60 | 0.91 | 0.02 | 12.15 | 0.02 | 10.78 | 0.06 | 0.23 | 27.78 |
323 | 2.03 | 50.64 | 0.00 | 27.45 | 0.05 | 0.25 | 18.53 | 98.95 | 0.91 | 0.01 | 11.84 | 0.03 | 10.92 | 0.03 | 0.16 | 28.00 |
991 | 2.21 | 50.36 | 0.00 | 27.19 | 0.00 | 0.91 | 18.82 | 99.49 | 0.98 | 0.00 | 11.62 | 0.02 | 10.68 | 0.03 | 0.55 | 28.07 |
490 | 2.36 | 47.86 | 0.94 | 28.64 | 0.05 | 0.36 | 19.53 | 99.73 | 1.01 | 0.01 | 10.69 | 0.78 | 10.89 | 0.03 | 0.21 | 28.19 |
321 | 2.26 | 48.55 | 0.07 | 27.80 | 0.10 | 0.18 | 18.68 | 97.64 | 1.01 | 0.00 | 11.36 | 0.06 | 11.07 | 0.06 | 0.11 | 28.24 |
1502 | 2.48 | 50.13 | 0.12 | 28.26 | 0.10 | 1.35 | 18.87 | 101.30 | 1.08 | 0.00 | 11.32 | 0.10 | 10.86 | 0.06 | 0.80 | 27.53 |
580 | 2.71 | 48.99 | 0.06 | 28.36 | 0.00 | 0.70 | 19.12 | 99.95 | 1.19 | 0.00 | 11.15 | 0.05 | 10.98 | 0.02 | 0.42 | 28.11 |
2227 | 2.69 | 50.88 | 0.06 | 26.61 | 0.00 | 0.20 | 18.81 | 99.25 | 1.20 | 0.02 | 11.81 | 0.05 | 10.51 | 0.00 | 0.12 | 28.22 |
891 | 2.87 | 47.51 | 0.12 | 29.17 | 0.00 | 0.48 | 19.37 | 99.52 | 1.25 | 0.01 | 10.75 | 0.10 | 11.23 | 0.00 | 0.29 | 28.32 |
2774 | 3.31 | 47.97 | 0.00 | 27.86 | 0.00 | 0.27 | 18.82 | 98.23 | 1.47 | 0.06 | 11.11 | 0.01 | 10.98 | 0.02 | 0.17 | 28.17 |
2775 | 3.53 | 47.84 | 0.00 | 28.02 | 0.07 | 0.29 | 18.66 | 98.41 | 1.57 | 0.08 | 11.09 | 0.00 | 11.05 | 0.05 | 0.18 | 27.95 |
578 | 3.92 | 46.80 | 0.00 | 29.39 | 0.05 | 0.42 | 18.77 | 99.34 | 1.72 | 0.01 | 10.71 | 0.04 | 11.44 | 0.03 | 0.25 | 27.75 |
895 | 4.29 | 45.97 | 0.00 | 28.46 | 0.00 | 0.51 | 18.90 | 98.12 | 1.89 | 0.02 | 10.55 | 0.02 | 11.12 | 0.01 | 0.31 | 28.04 |
1003 | 5.08 | 44.78 | 0.00 | 28.62 | 0.06 | 0.52 | 19.22 | 98.27 | 2.21 | 0.03 | 10.14 | 0.03 | 11.03 | 0.03 | 0.31 | 28.13 |
992 | 5.12 | 43.91 | 0.06 | 30.87 | 0.06 | 0.89 | 19.28 | 100.18 | 2.18 | 0.05 | 9.76 | 0.05 | 11.67 | 0.04 | 0.52 | 27.69 |
1389 | 5.16 | 43.81 | 0.09 | 30.32 | 0.00 | 0.39 | 20.05 | 99.82 | 2.18 | 0.00 | 9.63 | 0.07 | 11.34 | 0.02 | 0.22 | 28.47 |
909 | 5.20 | 44.51 | 0.00 | 28.46 | 0.00 | 0.55 | 18.90 | 97.62 | 2.29 | 0.01 | 10.20 | 0.01 | 11.09 | 0.02 | 0.33 | 27.98 |
Table 9.
EPMA data for boulangerite.
Table 9.
EPMA data for boulangerite.
Analyses | wt.% | apfu Ʃ20 Atoms |
---|
Ag | Pb | Fe | Mn | Sb | As | Se | S | Total | Ag | Pb | Fe | Mn | Sb | As | Se | S |
---|
2468 | 0.00 | 55.00 | 0.16 | 0.15 | 25.47 | 0.00 | 0.00 | 18.50 | 99.28 | 0.00 | 5.02 | 0.05 | 0.05 | 3.96 | 0.00 | 0.00 | 10.91 |
2475 | 0.00 | 54.56 | 0.00 | 0.06 | 26.35 | 0.00 | 0.04 | 18.89 | 99.90 | 0.00 | 4.92 | 0.01 | 0.02 | 4.04 | 0.00 | 0.01 | 11.00 |
2226 | 0.25 | 54.29 | 0.11 | 0.06 | 26.35 | 0.00 | 0.09 | 18.71 | 99.86 | 0.04 | 4.90 | 0.04 | 0.02 | 4.05 | 0.00 | 0.02 | 10.92 |
368 | 0.00 | 54.52 | 0.00 | 0.00 | 26.17 | 0.09 | 0.24 | 18.74 | 99.76 | 0.01 | 4.92 | 0.00 | 0.01 | 4.02 | 0.02 | 0.06 | 10.93 |
1644 | 0.12 | 55.08 | 0.00 | 0.00 | 25.10 | 0.10 | 0.31 | 18.54 | 99.24 | 0.02 | 5.03 | 0.00 | 0.01 | 3.90 | 0.02 | 0.07 | 10.94 |
1855 | 0.00 | 54.74 | 0.00 | 0.00 | 26.35 | 0.08 | 0.59 | 18.64 | 100.39 | 0.00 | 4.93 | 0.00 | 0.00 | 4.04 | 0.02 | 0.14 | 10.85 |
1940 | 0.00 | 54.80 | 0.00 | 0.05 | 26.81 | 0.05 | 0.61 | 18.90 | 101.21 | 0.00 | 4.88 | 0.01 | 0.02 | 4.06 | 0.01 | 0.14 | 10.87 |
718 | 0.05 | 53.97 | 0.00 | 0.00 | 26.04 | 0.00 | 0.85 | 18.73 | 99.64 | 0.01 | 4.86 | 0.01 | 0.01 | 3.99 | 0.01 | 0.20 | 10.90 |
581 | 0.00 | 55.21 | 0.00 | 0.00 | 26.12 | 0.00 | 1.07 | 18.59 | 101.00 | 0.00 | 4.95 | 0.00 | 0.01 | 3.99 | 0.01 | 0.25 | 10.78 |
757 | 0.00 | 54.13 | 0.17 | 0.00 | 25.62 | 0.00 | 1.93 | 18.25 | 100.09 | 0.00 | 4.89 | 0.06 | 0.01 | 3.93 | 0.00 | 0.46 | 10.64 |
1515 | 0.00 | 54.01 | 0.10 | 0.09 | 26.29 | 0.06 | 2.21 | 18.07 | 100.84 | 0.00 | 4.85 | 0.03 | 0.03 | 4.01 | 0.02 | 0.52 | 10.48 |
748 | 0.00 | 54.27 | 0.06 | 0.00 | 26.17 | 0.00 | 2.69 | 18.12 | 101.30 | 0.01 | 4.86 | 0.02 | 0.01 | 3.99 | 0.00 | 0.63 | 10.48 |
Table 10.
EPMA data for semseyite.
Table 10.
EPMA data for semseyite.
Analyses | wt.% | apfu Ʃ38 Atoms |
---|
Ag | Pb | Sb | S | Total | Ag | Pb | Sb | S |
---|
2462 | 0.00 | 52.82 | 27.46 | 19.53 | 99.92 | 0.00 | 8.89 | 7.87 | 21.24 |
2482 | 0.57 | 50.70 | 27.18 | 19.18 | 97.63 | 0.19 | 8.68 | 7.92 | 21.22 |
2483 | 0.00 | 52.41 | 27.04 | 18.81 | 98.42 | 0.00 | 9.05 | 7.95 | 21.00 |
2463 | 0.00 | 52.71 | 27.72 | 18.85 | 99.46 | 0.00 | 9.02 | 8.07 | 20.84 |
Table 11.
EPMA data for jamesonite.
Table 11.
EPMA data for jamesonite.
Analyses | wt.% | apfu Ʃ20 Atoms |
---|
Pb | Fe | Mn | Sb | Se | S | Total | Pb | Fe | Mn | Sb | Se | S |
---|
2450 | 39.14 | 2.55 | 0.09 | 34.95 | 0.00 | 21.77 | 98.50 | 3.92 | 0.95 | 0.03 | 5.96 | 0.00 | 14.10 |
379 | 40.51 | 2.56 | 0.00 | 35.12 | 0.09 | 21.90 | 100.17 | 4.02 | 0.94 | 0.02 | 5.93 | 0.02 | 14.03 |
213 | 39.67 | 2.61 | 0.00 | 35.80 | 0.30 | 21.22 | 99.60 | 3.99 | 0.98 | 0.01 | 6.13 | 0.08 | 13.80 |
864 | 39.45 | 2.47 | 0.06 | 35.44 | 0.41 | 21.70 | 99.53 | 3.93 | 0.91 | 0.02 | 6.01 | 0.11 | 13.98 |
1304 | 39.29 | 2.62 | 0.10 | 35.76 | 0.43 | 21.91 | 100.09 | 3.88 | 0.96 | 0.04 | 6.01 | 0.11 | 13.99 |
863 | 39.69 | 2.41 | 0.10 | 36.12 | 0.44 | 21.74 | 100.49 | 3.93 | 0.89 | 0.04 | 6.08 | 0.11 | 13.90 |
1906 | 39.24 | 2.51 | 0.05 | 36.05 | 0.61 | 21.88 | 100.34 | 3.87 | 0.92 | 0.02 | 6.06 | 0.16 | 13.96 |
2069 | 38.48 | 2.45 | 0.14 | 35.56 | 0.83 | 20.81 | 98.27 | 3.92 | 0.93 | 0.05 | 6.16 | 0.22 | 13.70 |
Table 12.
EPMA data for miargyrite.
Table 12.
EPMA data for miargyrite.
Analyses | wt.% | apfu Ʃ4 Atoms |
---|
Ag | Pb | Fe | Sb | As | Se | S | Total | Ag | Cu | Pb | Fe | Cd | Sb | As | Se | S |
---|
514 | 37.18 | 0.00 | 0.00 | 41.06 | 0.17 | 0.00 | 21.83 | 100.23 | 1.01 | 0.00 | 0.00 | 0.00 | 0.00 | 0.99 | 0.01 | 0.00 | 1.99 |
52 | 36.32 | 0.10 | 0.06 | 41.47 | 0.08 | 0.33 | 21.47 | 99.83 | 0.99 | 0.00 | 0.00 | 0.00 | 0.00 | 1.01 | 0.00 | 0.01 | 1.98 |
57 | 35.95 | 0.23 | 0.07 | 40.80 | 0.13 | 0.51 | 21.65 | 99.34 | 0.98 | 0.00 | 0.00 | 0.00 | 0.00 | 0.99 | 0.01 | 0.02 | 1.99 |
58 | 35.99 | 0.34 | 0.08 | 41.10 | 0.10 | 0.69 | 21.32 | 99.62 | 0.99 | 0.00 | 0.00 | 0.00 | 0.00 | 1.00 | 0.00 | 0.03 | 1.97 |
8 | 36.35 | 0.10 | 0.00 | 41.74 | 0.08 | 0.88 | 21.36 | 100.51 | 0.99 | 0.00 | 0.00 | 0.00 | 0.00 | 1.01 | 0.00 | 0.03 | 1.96 |
1963 | 36.13 | 0.06 | 0.00 | 41.81 | 0.07 | 1.08 | 21.05 | 100.18 | 0.99 | 0.00 | 0.00 | 0.00 | 0.00 | 1.02 | 0.00 | 0.04 | 1.94 |
791 | 35.67 | 0.20 | 0.06 | 40.68 | 0.10 | 1.76 | 20.70 | 99.16 | 0.99 | 0.00 | 0.00 | 0.00 | 0.00 | 1.00 | 0.00 | 0.07 | 1.93 |
539 | 36.42 | 0.08 | 0.00 | 41.05 | 0.07 | 3.46 | 20.09 | 101.18 | 1.00 | 0.00 | 0.00 | 0.00 | 0.00 | 1.00 | 0.00 | 0.13 | 1.86 |
1137 | 35.57 | 0.09 | 0.00 | 40.44 | 0.00 | 4.26 | 19.13 | 99.50 | 1.00 | 0.00 | 0.00 | 0.00 | 0.00 | 1.01 | 0.00 | 0.16 | 1.82 |
1362 | 35.16 | 0.06 | 0.16 | 40.10 | 0.05 | 4.92 | 19.53 | 99.99 | 0.98 | 0.00 | 0.00 | 0.01 | 0.00 | 0.99 | 0.00 | 0.19 | 1.83 |
1138 | 34.97 | 0.40 | 0.00 | 40.01 | 0.00 | 5.63 | 18.40 | 99.40 | 1.00 | 0.00 | 0.01 | 0.00 | 0.00 | 1.01 | 0.00 | 0.22 | 1.76 |
1265 | 35.18 | 0.21 | 0.08 | 40.05 | 0.06 | 6.35 | 18.19 | 100.12 | 1.00 | 0.00 | 0.00 | 0.00 | 0.00 | 1.01 | 0.00 | 0.25 | 1.74 |
2699 | 35.18 | 0.08 | 0.46 | 39.06 | 0.00 | 8.65 | 16.85 | 100.27 | 1.01 | 0.00 | 0.00 | 0.03 | 0.00 | 0.99 | 0.00 | 0.34 | 1.63 |
2700 | 34.83 | 0.06 | 0.40 | 38.93 | 0.00 | 8.79 | 16.34 | 99.34 | 1.01 | 0.00 | 0.00 | 0.02 | 0.00 | 1.00 | 0.00 | 0.35 | 1.60 |
Table 13.
EPMA data for pyrargyrite.
Table 13.
EPMA data for pyrargyrite.
Analyses | wt.% | apfu Ʃ7 Atoms |
---|
Ag | Pb | Cd | Sb | As | Se | S | Total | Ag | Pb | Cd | Sb | As | Se | S |
---|
2329 | 59.10 | 0.00 | 0.00 | 22.77 | 0.00 | 0.00 | 17.51 | 99.38 | 2.99 | 0.00 | 0.00 | 1.02 | 0.00 | 0.00 | 2.98 |
2471 | 59.38 | 0.07 | 0.08 | 22.95 | 0.00 | 0.00 | 18.13 | 100.60 | 2.95 | 0.00 | 0.00 | 1.01 | 0.00 | 0.00 | 3.03 |
2522 | 60.14 | 0.16 | 0.12 | 22.23 | 0.00 | 0.11 | 17.90 | 100.66 | 3.00 | 0.00 | 0.01 | 0.98 | 0.00 | 0.01 | 3.00 |
2528 | 61.11 | 0.00 | 0.00 | 21.94 | 0.00 | 0.15 | 17.63 | 100.83 | 3.02 | 0.00 | 0.00 | 0.96 | 0.00 | 0.01 | 2.93 |
2622 | 59.22 | 0.06 | 0.10 | 22.67 | 0.21 | 0.64 | 16.70 | 99.60 | 3.02 | 0.00 | 0.00 | 1.03 | 0.02 | 0.04 | 2.87 |
2729 | 61.69 | 0.00 | 0.00 | 21.74 | 0.00 | 0.69 | 17.53 | 101.65 | 3.06 | 0.00 | 0.00 | 0.96 | 0.00 | 0.05 | 2.93 |
Table 14.
EPMA data for stephanite.
Table 14.
EPMA data for stephanite.
Analyses | wt.% | apfu Ʃ10 Atoms |
---|
Ag | Cd | Sb | As | Se | S | Total | Ag | Cd | Sb | As | Se | S |
---|
2343 | 68.62 | 0.15 | 16.64 | 0.13 | 0.00 | 16.03 | 101.57 | 4.98 | 0.01 | 1.07 | 0.01 | 0.00 | 3.91 |
2524 | 67.43 | 0.22 | 14.31 | 0.00 | 0.00 | 15.66 | 97.63 | 5.06 | 0.02 | 0.95 | 0.00 | 0.00 | 3.95 |
2525 | 67.76 | 0.13 | 15.00 | 0.02 | 0.00 | 16.18 | 99.10 | 4.99 | 0.01 | 0.98 | 0.00 | 0.00 | 4.01 |
2755 | 68.74 | 0.00 | 14.07 | 0.00 | 0.00 | 15.64 | 98.45 | 5.13 | 0.00 | 0.93 | 0.00 | 0.00 | 3.92 |
2732 | 69.39 | 0.00 | 13.88 | 0.00 | 1.18 | 15.37 | 99.81 | 5.13 | 0.00 | 0.91 | 0.00 | 0.12 | 3.82 |
2747 | 66.97 | 0.00 | 14.43 | 0.03 | 1.70 | 14.31 | 97.44 | 5.14 | 0.00 | 0.98 | 0.00 | 0.18 | 3.69 |
Table 15.
EPMA data for polybasite.
Table 15.
EPMA data for polybasite.
Analyses | wt.% | apfu Ʃ29 Atoms |
---|
Ag | Cu | Pb | Fe | Cd | Sb | As | Se | S | Total | Ag | Cu | Pb | Fe | Cd | Sb | As | Se | S |
---|
2589 | 71.20 | 0.61 | 0.51 | 0.30 | 0.13 | 10.72 | 0.04 | 0.95 | 14.97 | 99.43 | 15.36 | 0.22 | 0.06 | 0.13 | 0.03 | 2.05 | 0.01 | 0.28 | 10.87 |
2587 | 71.45 | 0.69 | 0.74 | 0.54 | 0.17 | 11.85 | 0.03 | 1.01 | 15.96 | 102.43 | 14.82 | 0.24 | 0.08 | 0.22 | 0.03 | 2.18 | 0.01 | 0.29 | 11.14 |
2595 | 70.62 | 1.11 | 0.08 | 0.72 | 0.14 | 9.67 | 0.55 | 2.61 | 14.81 | 100.31 | 14.97 | 0.40 | 0.01 | 0.30 | 0.03 | 1.82 | 0.17 | 0.76 | 10.56 |
Table 16.
EPMA data for freibergite.
Table 16.
EPMA data for freibergite.
Analyses | wt.% | apfu Ʃ29 atoms |
---|
Ag | Cu | Fe | Zn | Sb | As | Se | S | Total | Ag | Cu | Fe | Zn | Sb | As | Se | S | Ag/A | Cu/B |
---|
2419 | 23.33 | 20.84 | 4.72 | 1.64 | 26.83 | 0.01 | 0.00 | 22.34 | 99.71 | 3.99 | 6.05 | 1.56 | 0.46 | 4.07 | 0.00 | 0.00 | 12.85 | 3.99 | 4.04 |
2547 | 26.62 | 18.16 | 5.07 | 1.64 | 26.72 | 0.03 | 0.13 | 22.68 | 101.04 | 4.54 | 5.25 | 1.67 | 0.46 | 4.03 | 0.01 | 0.03 | 13.00 | 4.54 | 3.79 |
2548 | 27.49 | 17.76 | 5.15 | 1.90 | 26.65 | 0.08 | 0.12 | 22.50 | 101.66 | 4.68 | 5.13 | 1.69 | 0.53 | 4.02 | 0.02 | 0.03 | 12.88 | 4.68 | 3.81 |
2549 | 27.83 | 17.54 | 4.95 | 1.72 | 26.74 | 0.00 | 0.13 | 22.42 | 101.32 | 4.76 | 5.10 | 1.64 | 0.49 | 4.06 | 0.01 | 0.03 | 12.91 | 4.76 | 3.86 |
2246 | 28.78 | 16.57 | 5.30 | 0.97 | 26.48 | 0.00 | 0.00 | 21.46 | 99.56 | 5.07 | 4.96 | 1.80 | 0.28 | 4.14 | 0.00 | 0.00 | 12.73 | 5.07 | 4.03 |
812 | 29.59 | 14.64 | 5.27 | 1.00 | 26.38 | 0.15 | 0.00 | 21.58 | 98.61 | 5.27 | 4.43 | 1.81 | 0.29 | 4.16 | 0.04 | 0.00 | 12.93 | 5.27 | 3.70 |
63 | 31.22 | 15.18 | 3.41 | 3.16 | 25.69 | 0.19 | 0.00 | 21.09 | 99.94 | 5.56 | 4.59 | 1.17 | 0.93 | 4.05 | 0.05 | 0.00 | 12.63 | 5.56 | 4.15 |
811 | 32.11 | 13.60 | 4.97 | 1.12 | 26.29 | 0.11 | 0.00 | 21.45 | 99.66 | 5.73 | 4.12 | 1.72 | 0.33 | 4.16 | 0.03 | 0.00 | 12.88 | 5.73 | 3.86 |
67 | 33.24 | 14.09 | 3.48 | 2.95 | 25.61 | 0.22 | 0.00 | 21.06 | 100.65 | 5.92 | 4.26 | 1.20 | 0.87 | 4.04 | 0.06 | 0.00 | 12.62 | 5.92 | 4.18 |
1461 | 33.55 | 13.78 | 5.01 | 1.07 | 25.59 | 0.11 | 0.00 | 20.91 | 100.01 | 6.02 | 4.19 | 1.74 | 0.32 | 4.07 | 0.03 | 0.00 | 12.62 | 6.00 | 4.19 |
42 | 33.87 | 13.64 | 3.56 | 2.63 | 25.63 | 0.21 | 0.00 | 20.52 | 100.06 | 6.12 | 4.19 | 1.24 | 0.78 | 4.11 | 0.05 | 0.00 | 12.48 | 6.00 | 4.19 |
36 | 34.60 | 13.45 | 3.75 | 2.30 | 25.69 | 0.23 | 0.00 | 20.65 | 100.67 | 6.22 | 4.11 | 1.30 | 0.68 | 4.09 | 0.06 | 0.00 | 12.50 | 6.00 | 4.11 |
2142 | 34.80 | 13.03 | 5.58 | 0.11 | 26.15 | 0.00 | 0.00 | 20.44 | 100.11 | 6.31 | 4.01 | 1.95 | 0.03 | 4.20 | 0.00 | 0.00 | 12.47 | 6.00 | 4.01 |
2140 | 36.99 | 12.32 | 5.40 | 0.09 | 24.60 | 0.00 | 0.00 | 19.67 | 99.07 | 6.85 | 3.87 | 1.93 | 0.03 | 4.03 | 0.00 | 0.00 | 12.25 | 6.00 | 3.87 |
1120 | 38.61 | 11.96 | 4.32 | 1.15 | 21.94 | 0.10 | 0.00 | 19.51 | 97.57 | 7.25 | 3.81 | 1.57 | 0.36 | 3.65 | 0.03 | 0.01 | 12.32 | 6.00 | 3.81 |
Table 17.
EPMA data for Ag-rich tetrahedrite/freibergite.
Table 17.
EPMA data for Ag-rich tetrahedrite/freibergite.
Analyses | wt.% | apfu Ʃ29 atoms |
---|
Ag | Cu | Fe | Zn | Sb | S | Total | Ag | Cu | Fe | Zn | Sb | S | Ag/A | Cu/B |
---|
2047 | 17.41 | 24.78 | 5.44 | 1.05 | 27.43 | 22.57 | 98.68 | 2.93 | 7.09 | 1.77 | 0.29 | 4.10 | 12.80 | 2.93 | 4.02 |
2045 | 17.84 | 24.41 | 5.50 | 1.08 | 27.64 | 22.65 | 99.12 | 3.00 | 6.97 | 1.78 | 0.30 | 4.12 | 12.81 | 3.00 | 3.97 |
2046 | 18.48 | 23.81 | 5.35 | 1.08 | 27.40 | 22.24 | 98.36 | 3.15 | 6.89 | 1.76 | 0.30 | 4.13 | 12.74 | 3.15 | 4.03 |
Table 18.
EPMA data for acanthite.
Table 18.
EPMA data for acanthite.
Analyses | wt.% | apfu Ʃ3 Atoms |
---|
Ag | Cu | Pb | Fe | Cd | Se | S | Cl | Total | Ag | Cu | Pb | Fe | Cd | Se | S | Cl |
---|
2814 | 86.85 | 0.13 | 0.00 | 0.00 | 0.00 | 0.00 | 12.16 | 0.00 | 99.39 | 2.03 | 0.01 | 0.00 | 0.00 | 0.00 | 0.00 | 0.96 | 0.01 |
2647 | 87.50 | 0.00 | 0.05 | 0.42 | 0.17 | 1.03 | 11.77 | 0.00 | 100.93 | 2.03 | 0.00 | 0.00 | 0.02 | 0.00 | 0.03 | 0.92 | 0.00 |
2646 | 85.66 | 0.00 | 0.09 | 0.47 | 0.22 | 1.21 | 11.06 | 0.00 | 98.71 | 2.04 | 0.00 | 0.00 | 0.02 | 0.00 | 0.04 | 0.89 | 0.00 |
2719 | 84.15 | 0.00 | 0.09 | 1.03 | 0.04 | 1.42 | 11.28 | 0.56 | 98.70 | 1.97 | 0.00 | 0.00 | 0.05 | 0.00 | 0.05 | 0.89 | 0.04 |
2623 | 83.18 | 0.00 | 0.18 | 0.03 | 0.16 | 3.64 | 12.36 | 0.00 | 99.82 | 1.91 | 0.00 | 0.00 | 0.00 | 0.00 | 0.11 | 0.96 | 0.00 |
2579 | 83.95 | 0.00 | 0.00 | 1.62 | 0.23 | 4.01 | 12.45 | 0.00 | 102.31 | 1.87 | 0.00 | 0.00 | 0.07 | 0.00 | 0.12 | 0.93 | 0.00 |
2596 | 84.13 | 0.05 | 0.05 | 0.64 | 0.18 | 3.98 | 11.65 | 0.00 | 100.67 | 1.94 | 0.00 | 0.00 | 0.03 | 0.00 | 0.13 | 0.90 | 0.00 |
2594 | 85.15 | 0.00 | 0.00 | 0.50 | 0.17 | 4.29 | 11.55 | 0.00 | 101.68 | 1.95 | 0.00 | 0.00 | 0.02 | 0.00 | 0.13 | 0.89 | 0.00 |
2601 | 79.66 | 0.33 | 0.77 | 0.05 | 0.06 | 8.83 | 8.29 | 0.00 | 98.27 | 1.97 | 0.01 | 0.01 | 0.00 | 0.00 | 0.30 | 0.69 | 0.00 |
Table 19.
EPMA data for aguilarite.
Table 19.
EPMA data for aguilarite.
| | | | wt.% | | | | | apfu Ʃ6 Atoms | |
---|
Analyses | Ag | Pb | Fe | Cd | Se | S | Total | Ag | Pb | Fe | Cd | Se | S |
---|
2577 | 74.02 | 1.64 | 1.84 | 0.20 | 17.59 | 4.65 | 99.94 | 3.75 | 0.04 | 0.18 | 0.01 | 1.22 | 0.79 |
2578 | 75.50 | 0.16 | 1.77 | 0.19 | 18.16 | 3.62 | 99.41 | 3.90 | 0.00 | 0.18 | 0.01 | 1.28 | 0.63 |
Table 20.
EPMA data for naumannite.
Table 20.
EPMA data for naumannite.
Analyses | wt.% | apfu Ʃ3 atoms |
---|
Ag | Pb | Fe | Cd | Se | S | Total | Ag | Pb | Fe | Cd | Se | S |
---|
2597 | 75.43 | 0.10 | 0.92 | 0.21 | 20.69 | 1.96 | 99.30 | 2.01 | 0.00 | 0.05 | 0.01 | 0.75 | 0.18 |
2696 | 74.20 | 0.00 | 1.06 | 0.17 | 23.94 | 0.31 | 99.66 | 2.02 | 0.00 | 0.06 | 0.00 | 0.89 | 0.03 |
2694 | 74.48 | 0.00 | 0.98 | 0.00 | 23.93 | 0.23 | 99.62 | 2.03 | 0.00 | 0.05 | 0.00 | 0.89 | 0.02 |
2698 | 74.10 | 0.00 | 0.66 | 0.05 | 23.74 | 0.20 | 98.76 | 2.04 | 0.00 | 0.04 | 0.00 | 0.89 | 0.02 |
2697 | 74.06 | 0.00 | 0.56 | 0.05 | 23.83 | 0.21 | 98.69 | 2.05 | 0.00 | 0.03 | 0.00 | 0.90 | 0.02 |
2695 | 73.86 | 0.00 | 0.59 | 0.05 | 23.95 | 0.22 | 98.66 | 2.03 | 0.00 | 0.03 | 0.00 | 0.90 | 0.02 |
Table 21.
EPMA data for argyrodite.
Table 21.
EPMA data for argyrodite.
| | | | | wt.% | | | | | | | | | apfu Ʃ15 atoms | | |
---|
Analyses | Ag | Cu | Pb | Fe | Zn | Ge | Sb | Se | S | Total | Ag | Cu | Pb | Fe | Zn | Ge | Sb | Se | S |
---|
2614 | 78.19 | 0.00 | 0.11 | 1.84 | 0.00 | 5.66 | 0.13 | 0.10 | 17.72 | 103.84 | 7.80 | 0.01 | 0.01 | 0.35 | 0.00 | 0.838 | 0.01 | 0.01 | 5.94 |
2615 | 78.70 | 0.00 | 0.11 | 1.68 | 0.00 | 5.89 | 0.27 | 0.14 | 17.64 | 104.43 | 7.83 | 0.00 | 0.01 | 0.32 | 0.00 | 0.871 | 0.02 | 0.02 | 5.90 |
2616 | 73.91 | 0.00 | 1.11 | 1.40 | 0.00 | 6.95 | 0.60 | 0.70 | 17.05 | 101.81 | 7.57 | 0.00 | 0.06 | 0.28 | 0.00 | 1.06 | 0.05 | 0.10 | 5.87 |
2619 | 73.60 | 0.55 | 0.00 | 1.97 | 0.00 | 6.00 | 0.08 | 1.00 | 17.75 | 101.15 | 7.42 | 0.09 | 0.00 | 0.38 | 0.01 | 0.90 | 0.01 | 0.14 | 6.02 |
2707 | 72.59 | 0.54 | 0.25 | 2.31 | 0.00 | 5.53 | 0.00 | 1.03 | 18.04 | 100.63 | 7.31 | 0.09 | 0.01 | 0.45 | 0.01 | 0.83 | 0.00 | 0.14 | 6.12 |
2708 | 73.73 | 0.05 | 0.00 | 0.90 | 1.07 | 5.91 | 0.31 | 3.58 | 16.26 | 102.06 | 7.56 | 0.01 | 0.00 | 0.18 | 0.18 | 0.90 | 0.03 | 0.50 | 5.61 |
Table 22.
EPMA data for unnamed Ag-Cu-S phases.
Table 22.
EPMA data for unnamed Ag-Cu-S phases.
| | | | wt.% | | | | | | | | | at.% | | |
---|
Analyses | Ag | Cu | Pb | Fe | Cd | Zn | Se | S | Total | Ag | Cu | Pb | Fe | Cd | Zn | Se | S |
---|
2653 | 78.57 | 3.64 | 0.00 | 0.67 | 0.09 | 0.00 | 2.17 | 13.85 | 98.99 | 57.88 | 4.55 | 0.01 | 0.95 | 0.06 | 0.00 | 2.18 | 34.33 |
2670 | 69.06 | 3.79 | 0.00 | 3.50 | 0.00 | 0.53 | 4.51 | 16.29 | 97.69 | 47.92 | 4.47 | 0.00 | 4.70 | 0.00 | 0.60 | 4.28 | 38.03 |
2664 | 75.73 | 4.91 | 0.19 | 0.88 | 0.17 | 0.20 | 4.76 | 12.72 | 99.57 | 55.82 | 6.14 | 0.07 | 1.26 | 0.12 | 0.25 | 4.80 | 31.53 |
2669 | 73.92 | 5.37 | 0.13 | 1.37 | 0.00 | 0.43 | 4.10 | 14.01 | 99.32 | 53.07 | 6.54 | 0.05 | 1.90 | 0.00 | 0.51 | 4.02 | 33.84 |
2668 | 74.92 | 5.41 | 0.11 | 1.46 | 0.05 | 0.41 | 4.39 | 14.14 | 100.88 | 53.03 | 6.50 | 0.04 | 2.00 | 0.03 | 0.48 | 4.24 | 33.66 |
2654 | 76.60 | 6.10 | 0.16 | 0.68 | 0.12 | 0.00 | 1.82 | 14.94 | 100.41 | 54.23 | 7.33 | 0.06 | 0.93 | 0.08 | 0.02 | 1.76 | 35.58 |
2649 | 72.54 | 7.46 | 0.19 | 0.84 | 0.15 | 0.00 | 2.60 | 15.09 | 98.86 | 51.23 | 8.94 | 0.07 | 1.14 | 0.10 | 0.04 | 2.51 | 35.85 |
2648 | 70.46 | 8.47 | 0.10 | 0.74 | 0.13 | 0.00 | 2.24 | 15.92 | 98.06 | 49.22 | 10.05 | 0.04 | 1.00 | 0.08 | 0.00 | 2.14 | 37.41 |
2650 | 68.35 | 8.89 | 0.19 | 1.07 | 0.08 | 0.00 | 3.51 | 15.18 | 97.26 | 48.25 | 10.65 | 0.07 | 1.46 | 0.05 | 0.00 | 3.38 | 36.04 |
2651 | 67.79 | 9.64 | 0.08 | 1.16 | 0.12 | 0.00 | 2.87 | 15.69 | 97.36 | 47.29 | 11.42 | 0.03 | 1.57 | 0.08 | 0.05 | 2.73 | 36.82 |
2734 | 60.24 | 15.60 | 0.22 | 1.45 | 0.10 | 0.00 | 2.21 | 18.11 | 97.92 | 39.15 | 17.21 | 0.07 | 1.82 | 0.06 | 0.00 | 1.96 | 39.59 |
2736 | 57.30 | 15.64 | 0.00 | 2.09 | 0.00 | 0.00 | 2.17 | 18.08 | 95.28 | 37.71 | 17.47 | 0.00 | 2.66 | 0.00 | 0.00 | 1.95 | 40.03 |
Table 23.
EPMA data for Sb-rich silver.
Table 23.
EPMA data for Sb-rich silver.
| | | wt.% | | | | apfu Ʃ1 Atom | |
---|
Analyses | Ag | Au | Sb | As | Cl | Total | Ag | Au | Sb | As | Cl |
---|
2825 | 98.45 | 0.00 | 1.32 | 0.07 | 0.10 | 99.94 | 0.98 | 0.00 | 0.01 | 0.00 | 0.00 |
2827 | 98.49 | 0.00 | 1.89 | 0.00 | 0.11 | 100.49 | 0.98 | 0.00 | 0.02 | 0.00 | 0.00 |
2824 | 98.40 | 0.00 | 1.99 | 0.12 | 0.11 | 100.62 | 0.98 | 0.00 | 0.02 | 0.00 | 0.00 |
2813 | 98.16 | 0.00 | 2.10 | 0.11 | 0.11 | 100.48 | 0.97 | 0.00 | 0.02 | 0.00 | 0.00 |
2829 | 98.09 | 0.00 | 2.61 | 0.12 | 0.10 | 100.92 | 0.97 | 0.00 | 0.02 | 0.00 | 0.00 |
2844 | 97.16 | 0.00 | 2.73 | 0.05 | 0.10 | 100.04 | 0.97 | 0.00 | 0.02 | 0.00 | 0.00 |
2830 | 97.66 | 0.13 | 2.77 | 0.09 | 0.12 | 100.77 | 0.97 | 0.00 | 0.02 | 0.00 | 0.00 |
2838 | 97.17 | 0.09 | 2.92 | 0.09 | 0.13 | 100.40 | 0.97 | 0.00 | 0.03 | 0.00 | 0.00 |
2848 | 97.07 | 0.00 | 2.91 | 0.00 | 0.10 | 100.08 | 0.97 | 0.00 | 0.03 | 0.00 | 0.00 |
2833 | 97.53 | 0.00 | 2.99 | 0.15 | 0.12 | 100.79 | 0.97 | 0.00 | 0.03 | 0.00 | 0.00 |
2839 | 97.73 | 0.00 | 3.11 | 0.09 | 0.10 | 101.03 | 0.97 | 0.00 | 0.03 | 0.00 | 0.00 |
Table 24.
EPMA data for silver.
Table 24.
EPMA data for silver.
Analyses | wt.% | apfu Ʃ1 atom |
---|
Ag | Au | Hg | As | Te | Cl | Total | Ag | Au | Hg | As | Te | Cl |
---|
2865 | 101.59 | 0.00 | 0.10 | 0.16 | 0.11 | 0.13 | 102.09 | 0.99 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 |
2866 | 101.61 | 0.06 | 0.00 | 0.07 | 0.12 | 0.11 | 101.97 | 0.99 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 |
2867 | 101.62 | 0.00 | 0.00 | 0.09 | 0.12 | 0.11 | 101.94 | 0.99 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 |
2868 | 101.53 | 0.00 | 0.20 | 0.10 | 0.10 | 0.13 | 102.06 | 0.99 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 |
2828 | 100.47 | 0.08 | 0.00 | 0.11 | 0.00 | 0.10 | 100.76 | 0.99 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 |
Table 25.
EPMA data for Au-rich silver.
Table 25.
EPMA data for Au-rich silver.
Analyses | wt.% | at% |
---|
Ag | Au | Hg | Sb | Te | S | Total | Ag | Au | Hg | Sb | Te | S |
---|
2686 | 39.80 | 56.50 | 0.00 | 0.00 | 0.07 | 0.12 | 96.49 | 55.90 | 43.46 | 0.00 | 0.00 | 0.08 | 0.56 |
2689 | 40.82 | 56.41 | 0.00 | 0.00 | 0.12 | 0.08 | 97.42 | 56.62 | 42.85 | 0.00 | 0.00 | 0.14 | 0.36 |
2692 | 40.71 | 56.36 | 0.00 | 0.00 | 0.09 | 0.10 | 97.26 | 56.52 | 42.85 | 0.00 | 0.00 | 0.10 | 0.46 |
2684 | 40.73 | 56.06 | 0.00 | 0.00 | 0.09 | 0.08 | 96.95 | 56.76 | 42.79 | 0.00 | 0.00 | 0.10 | 0.35 |
2685 | 40.95 | 56.31 | 0.00 | 0.00 | 0.10 | 0.08 | 97.44 | 56.71 | 42.71 | 0.00 | 0.00 | 0.12 | 0.38 |
2683 | 40.92 | 55.84 | 0.00 | 0.00 | 0.06 | 0.08 | 96.90 | 56.92 | 42.54 | 0.00 | 0.00 | 0.07 | 0.36 |
2690 | 41.15 | 55.88 | 0.00 | 0.00 | 0.12 | 0.12 | 97.26 | 56.94 | 42.34 | 0.00 | 0.02 | 0.13 | 0.54 |
2691 | 41.41 | 55.53 | 0.00 | 0.00 | 0.09 | 0.09 | 97.12 | 57.34 | 42.11 | 0.00 | 0.00 | 0.10 | 0.41 |
2688 | 41.89 | 55.68 | 0.00 | 0.00 | 0.00 | 0.10 | 97.66 | 57.59 | 41.92 | 0.00 | 0.00 | 0.03 | 0.46 |
2687 | 41.86 | 55.59 | 0.00 | 0.00 | 0.12 | 0.09 | 97.66 | 57.58 | 41.87 | 0.00 | 0.00 | 0.14 | 0.41 |
2571 | 48.58 | 47.84 | 0.00 | 0.29 | 0.11 | 0.07 | 96.90 | 64.42 | 34.74 | 0.00 | 0.34 | 0.13 | 0.33 |
2572 | 50.57 | 45.87 | 0.20 | 0.36 | 0.11 | 0.09 | 97.19 | 66.10 | 32.83 | 0.14 | 0.41 | 0.13 | 0.39 |
2630 | 49.52 | 42.53 | 0.97 | 0.85 | 0.00 | 2.87 | 96.73 | 59.11 | 27.80 | 0.62 | 0.90 | 0.02 | 11.52 |
2627 | 56.48 | 39.40 | 0.52 | 0.83 | 0.15 | 0.76 | 98.14 | 69.06 | 26.38 | 0.34 | 0.90 | 0.16 | 3.13 |
2573 | 59.18 | 36.84 | 0.48 | 0.58 | 0.09 | 0.53 | 97.70 | 72.14 | 24.60 | 0.31 | 0.63 | 0.09 | 2.17 |
2574 | 59.43 | 36.62 | 0.00 | 0.74 | 0.10 | 0.57 | 97.46 | 72.35 | 24.41 | 0.00 | 0.80 | 0.11 | 2.33 |
2575 | 62.13 | 33.51 | 0.00 | 1.07 | 0.12 | 0.44 | 97.27 | 74.86 | 22.11 | 0.00 | 1.15 | 0.13 | 1.76 |
2749 | 61.73 | 32.85 | 0.00 | 1.20 | 0.00 | 0.69 | 96.48 | 73.96 | 21.56 | 0.00 | 1.28 | 0.00 | 2.77 |
2629 | 63.97 | 31.35 | 0.30 | 1.69 | 0.14 | 1.18 | 98.64 | 73.60 | 19.75 | 0.18 | 1.73 | 0.14 | 4.57 |
2628 | 66.73 | 27.60 | 0.28 | 2.19 | 0.18 | 1.76 | 98.73 | 74.11 | 16.78 | 0.17 | 2.15 | 0.17 | 6.57 |
Table 26.
EPMA data for uytenbogaardtite.
Table 26.
EPMA data for uytenbogaardtite.
| | wt.% | | | | apfu Ʃ6 atoms |
---|
Analyses | Ag | Au | Sb | S | Total | Ag | Au | Sb | S |
---|
2951 | 54.74 | 36.03 | 0.61 | 8.55 | 99.93 | 3.16 | 1.14 | 0.03 | 1.66 |
2952 | 55.39 | 36.33 | 0.64 | 8.61 | 100.97 | 3.17 | 1.14 | 0.03 | 1.66 |
2955 | 59.93 | 29.31 | 0.74 | 10.31 | 100.29 | 3.23 | 0.87 | 0.04 | 1.87 |
2957 | 61.73 | 25.93 | 0.85 | 10.27 | 98.79 | 3.33 | 0.77 | 0.04 | 1.86 |
Table 27.
EPMA data for allargentum.
Table 27.
EPMA data for allargentum.
| | | wt.% | | | | apfu Ʃ7 atom | |
---|
Analyses | Ag | Au | Sb | As | Cl | Total | Ag | Au | Sb | As | Cl |
---|
2812 | 84.28 | 0.00 | 16.46 | 0.05 | 0.09 | 100.88 | 5.94 | 0.00 | 1.03 | 0.01 | 0.02 |
2832 | 84.75 | 0.00 | 16.29 | 0.00 | 0.09 | 101.13 | 5.96 | 0.00 | 1.01 | 0.00 | 0.02 |
2841 | 84.74 | 0.00 | 16.49 | 0.00 | 0.10 | 101.33 | 5.94 | 0.00 | 1.02 | 0.00 | 0.02 |
2842 | 84.21 | 0.00 | 16.42 | 0.00 | 0.10 | 100.73 | 5.94 | 0.00 | 1.03 | 0.00 | 0.02 |
2843 | 84.60 | 0.09 | 16.32 | 0.06 | 0.08 | 101.15 | 5.95 | 0.00 | 1.02 | 0.01 | 0.02 |
2846 | 84.29 | 0.00 | 16.30 | 0.00 | 0.10 | 100.69 | 5.95 | 0.00 | 1.02 | 0.00 | 0.02 |
2847 | 84.54 | 0.00 | 16.34 | 0.00 | 0.08 | 100.96 | 5.95 | 0.00 | 1.02 | 0.00 | 0.02 |
Table 28.
EPMA data for Au-rich dyscrasite.
Table 28.
EPMA data for Au-rich dyscrasite.
| | | wt.% | | | | apfu Ʃ4 atom | |
---|
Analyses | Ag | Au | Sb | Te | S | Total | Ag | Au | Sb | Te | S |
---|
2760 | 70.84 | 3.65 | 24.66 | 0.13 | 0.07 | 99.35 | 2.98 | 0.08 | 0.92 | 0.00 | 0.01 |
2761 | 69.83 | 3.92 | 26.50 | 0.06 | 0.05 | 100.35 | 2.92 | 0.09 | 0.98 | 0.00 | 0.01 |
2762 | 67.81 | 4.11 | 26.98 | 0.00 | 0.21 | 99.10 | 2.87 | 0.10 | 1.01 | 0.00 | 0.03 |
Table 29.
EPMA data for galena.
Table 29.
EPMA data for galena.
Analyses | wt.% | apfu Ʃ2 atom |
---|
Ag | Cu | Pb | Sb | Se | S | Total | Ag | Cu | Pb | Sb | Se | S |
---|
2467 | 0.04 | 0.00 | 85.74 | 0.15 | 0.00 | 13.35 | 99.29 | 0.00 | 0.00 | 0.99 | 0.00 | 0.00 | 1.00 |
2013 | 0.09 | 0.05 | 85.80 | 0.13 | 0.19 | 13.49 | 99.75 | 0.00 | 0.00 | 0.98 | 0.00 | 0.01 | 1.00 |
857 | 0.00 | 0.00 | 85.81 | 0.19 | 0.44 | 13.59 | 100.04 | 0.00 | 0.00 | 0.98 | 0.00 | 0.01 | 1.00 |
2215 | 0.28 | 0.00 | 84.26 | 0.78 | 1.10 | 13.23 | 99.65 | 0.01 | 0.00 | 0.96 | 0.02 | 0.03 | 0.98 |
372 | 0.88 | 0.00 | 83.74 | 1.06 | 1.53 | 13.18 | 100.38 | 0.02 | 0.00 | 0.94 | 0.02 | 0.05 | 0.96 |
1264 | 0.21 | 0.00 | 83.85 | 0.28 | 2.57 | 12.38 | 99.29 | 0.00 | 0.00 | 0.97 | 0.01 | 0.08 | 0.93 |
2266 | 1.37 | 0.00 | 82.57 | 0.08 | 3.34 | 11.91 | 99.27 | 0.03 | 0.00 | 0.96 | 0.00 | 0.10 | 0.89 |
1494 | 0.08 | 0.00 | 84.30 | 0.16 | 3.64 | 11.92 | 100.11 | 0.00 | 0.00 | 0.98 | 0.00 | 0.11 | 0.90 |
23 | 0.13 | 0.31 | 84.51 | 0.09 | 3.83 | 12.03 | 100.90 | 0.00 | 0.01 | 0.97 | 0.00 | 0.12 | 0.89 |
2264 | 1.67 | 0.00 | 82.73 | 0.09 | 4.63 | 11.54 | 100.66 | 0.04 | 0.00 | 0.95 | 0.00 | 0.14 | 0.86 |
2315 | 1.29 | 0.00 | 82.87 | 0.07 | 5.10 | 10.84 | 100.17 | 0.03 | 0.00 | 0.98 | 0.00 | 0.16 | 0.82 |
22 | 0.20 | 0.31 | 83.63 | 0.08 | 5.38 | 11.12 | 100.72 | 0.00 | 0.01 | 0.97 | 0.00 | 0.16 | 0.84 |
2265 | 1.53 | 0.00 | 81.15 | 0.08 | 6.57 | 10.68 | 100.01 | 0.03 | 0.00 | 0.95 | 0.00 | 0.20 | 0.81 |
754 | 0.05 | 0.00 | 82.87 | 0.12 | 6.67 | 10.55 | 100.26 | 0.00 | 0.00 | 0.98 | 0.00 | 0.21 | 0.81 |
2314 | 1.01 | 0.00 | 82.32 | 0.06 | 6.82 | 9.98 | 100.19 | 0.02 | 0.00 | 0.98 | 0.00 | 0.21 | 0.77 |
1262 | 0.30 | 0.00 | 79.39 | 0.32 | 14.02 | 7.09 | 101.12 | 0.01 | 0.00 | 0.97 | 0.01 | 0.45 | 0.56 |
Table 30.
EPMA data for clausthalite.
Table 30.
EPMA data for clausthalite.
Analyses | wt.% | apfu Ʃ2 atom |
---|
Ag | Pb | Zn | Sb | Se | S | Total | Ag | Pb | Zn | Sb | Se | S |
---|
303 | 0.19 | 77.35 | 0.50 | 0.09 | 16.35 | 6.36 | 100.83 | 0.00 | 0.94 | 0.02 | 0.00 | 0.52 | 0.50 |
239 | 0.05 | 78.52 | 0.41 | 0.06 | 16.32 | 5.90 | 101.26 | 0.00 | 0.97 | 0.02 | 0.00 | 0.53 | 0.47 |
1263 | 0.00 | 78.73 | 0.00 | 0.08 | 17.01 | 5.62 | 101.44 | 0.00 | 0.98 | 0.00 | 0.00 | 0.56 | 0.45 |
1255 | 0.05 | 78.43 | 0.00 | 0.10 | 17.60 | 5.66 | 101.83 | 0.00 | 0.98 | 0.00 | 0.00 | 0.58 | 0.43 |
1260 | 0.06 | 77.86 | 0.00 | 0.07 | 18.36 | 4.94 | 101.29 | 0.00 | 0.98 | 0.00 | 0.00 | 0.61 | 0.40 |
1261 | 0.00 | 76.47 | 0.00 | 0.08 | 18.74 | 4.87 | 100.16 | 0.00 | 0.97 | 0.00 | 0.00 | 0.62 | 0.40 |
Table 31.
Comparative table of mineral sequences in Kutná Hora and Freiberg.
Table 31.
Comparative table of mineral sequences in Kutná Hora and Freiberg.
Kutná Hora | Freiberg [29] |
---|
Stage | Sequence | Ore type | Sequence |
---|
I. | Ia. Fe-As | ‘kb’ | Fe-As |
Ib. Zn-Sn-Cu-Fe | Zn-Sn-Cu |
Ic. 1stcarbonate | |
II. | IIa. Pb-Ag | Pb-Ag |
IIb.2nd carbonate | |
III. | IIIa. Ag-Sb | ‘eb’, ‘eq’ | Ag-Sb |
IIIb. Sb-Fe | | |
IV. | quartz–pyrite–calcite | | |