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Minerals 2016, 6(3), 59; https://doi.org/10.3390/min6030059

Modeling the Effect of Composition and Temperature on the Conductivity of Synthetic Copper Electrorefining Electrolyte

Department of Materials Science and Engineering, School of Chemical Technology, Aalto University, P.O. Box 16200, Aalto FI-00076, Finland
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Academic Editor: William Skinner
Received: 1 March 2016 / Revised: 10 June 2016 / Accepted: 13 June 2016 / Published: 24 June 2016
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Abstract

The physico-chemical properties of the copper electrolyte significantly affect the energy consumption of the electrorefining process and the quality of the cathode product. Favorable conditions for electrorefining processes are typically achieved by keeping both the electrolyte conductivity and diffusion coefficient of Cu(II) high, while ensuring low electrolyte viscosity. In this work the conductivity of the copper electrorefining electrolyte was investigated as a function of temperature (50–70 °C) and concentrations of copper (Cu(II), 40–60 g/L), nickel (Ni(II), 0–20 g/L), arsenic (As(III), 0–30 g/L) and sulfuric acid (160–220 g/L). In total 165 different combinations of these factors were studied. The results were treated using factorial analysis, and as a result, four electrolyte conductivity models were built up. Models were constructed both with and without arsenic as the presence of As(III) appeared to cause non-linearity in some factor effects and thus impacted the conductivity in more complex ways than previously detailed in literature. In all models the combined effect of factors was shown to be minor when compared to the effect of single factors. Conductivity was shown to increase when copper, nickel and arsenic concentrations were decreased and increase with increased temperature and acidity. Moreover, the arsenic concentration was shown to decrease the level of conductivity more than previously suggested in the literature. View Full-Text
Keywords: copper electrorefining electrolyte; conductivity; conductivity model copper electrorefining electrolyte; conductivity; conductivity model
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).
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Kalliomäki, T.; Aromaa, J.; Lundström, M. Modeling the Effect of Composition and Temperature on the Conductivity of Synthetic Copper Electrorefining Electrolyte. Minerals 2016, 6, 59.

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