Next Article in Journal
Structural Economic Assessment of Polymetallic Nodules Mining Project with Updates to Present Market Conditions
Next Article in Special Issue
Degradation of Polymetallic Nodules in Deep-Sea Multi-Stage Lifting Motor Pump
Previous Article in Journal
Adsorption Properties of Waste Building Sludge for Environmental Protection
Previous Article in Special Issue
Stratigraphic Variations of Fe–Mn Micronodules and Implications for the Formation of Extremely REY-Rich Mud in the Western North Pacific Ocean
 
 
Font Type:
Arial Georgia Verdana
Font Size:
Aa Aa Aa
Line Spacing:
Column Width:
Background:
Article

Combined Mining and Pulp-Lifting of Ferromanganese Nodules and Rare-Earth Element-Rich Mud around Minamitorishima Island in the Western North Pacific: A Prefeasibility Study

1
Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan
2
Penta-Ocean Construction Co., Ltd., 1534-1 Yonku-cho, Nasushiobara, Tochigi 329-2746, Japan
*
Author to whom correspondence should be addressed.
Minerals 2021, 11(3), 310; https://doi.org/10.3390/min11030310
Submission received: 20 January 2021 / Revised: 13 March 2021 / Accepted: 14 March 2021 / Published: 17 March 2021

Abstract

:
An examination of the technical and economic feasibility of the combined mining of the rare-earth element-rich mud (REE-rich mud) and ferromanganese nodules (FN) around Minamitorishima (Marcus) Island in Northwest Pacific is introduced. A previous study showed that the mining of REE-rich mud around Minamitorishima Island was not economically feasible. Therefore, in this study, three changes from the previous mining model to improve its economy are proposed. The first one is combined mining with FN in the area. The second one is introducing a pulp-lifting system that can lift both REE-rich mud and FN at high concentrations through a riser pipe. The third one is the reuse of waste mud and processed slag for construction materials. The economic evaluation results show a change from a slightly negative to quite positive economy depending on the mixing ratio of REE-rich mud and FN in the pulp-lifting. In addition, some technical approaches necessary to realize the combined mining method are introduced.

1. Introduction

The presence of deep-sea rare-earth element-rich mud (REE-rich mud) in the Pacific seafloor which involves high contents of rare-earth elements was reported in a previous study [1]. Two areas with high contents of REE-rich mud in the range of 500–1500 ppm, such as off Hawaii in the northeastern equatorial Pacific and off Tahiti in the southeastern Pacific, were pointed out. The authors of the paper also suggested the areas’ potential as locations of rare-earth element resources. Several feasibility studies were conducted on the mining of these elements [2,3,4]. However, because of the presence of an overlaid sediment layer that is several tens of meters thick with poor rare-earth element contents of less than 500 ppm, the results showed that the mud’s 500–1500 ppm potential was not great enough for the mining to be economical. One paper [2] proposed an in situ chemical concentration for improving the economy. In 2013, another higher content area was found by the Japan Agency for Marine-Earth Science and Technology (JAMSTEC) near Minamitorishima (Marcus) Island in the Japanese exclusive economic zone (EEZ) [5]. In this area, there are rare-earth element-rich layers with 5000–6500 ppm contents within 10 m below the seafloor, which is 5600–5800 m deep. The distribution aspects of this area and its potential as a rare-earth element resource have been reported in detail [6,7]. The feasibility of mining REE-rich mud in the area using ferromanganese nodule (FN) mining technologies was examined by Yamazaki et al. [8]. The results showed a negative economy. In this study, FN mining technologies, including feasibility studies and metallurgy, were reviewed as the basis of the combined mining of REE-rich mud and FN, and the mining model and the results of the economic evaluation are presented.

2. FN and Research and Development Approaches to Mining

Many scientific, technical, and economical publications are available on FN, mostly because they are considered the primary commercial target in deep-sea mineral resources [9,10]. The geological distribution characteristics have been studied in detail by numerous researchers [11,12,13,14]. However, very little detailed information on the first mining target areas in the Clarion-Clipperton Fracture Zone (CCZ) was available even in the 1990s [15,16], though the international consortium had authorized their sites in US domestic law [17] and the Pioneer Investors with the International Seabed Authority (ISA) were placed there as contractors [18]. Without enough information, basic geological and geophysical factors had to be assumed in some previous economic feasibility studies on the development [19,20,21]. An economic feasibility study on cobalt-rich FN inside the Cook Islands EEZ [22] stood out, because the high cobalt content in FN and a mechanical lift were assumed in the mining model. The results of these four feasibility studies are summarized and compared in Table 1. Because the market demand for manganese in the 1980s and 1990s was only 40% of that in 2019 [23], the manganese recovery from FN mining was not considered in some economic analyses [20,22]. The price reduction in the market due to the large amount of manganese supplied by FN mining was thought not to recover the additional metallurgical processing cost.
The first stage of research and development (R&D) activities for FN mining was conducted by the international consortium in the 1960s and 1970s [24,25,26]. Though some of the consortium’s technological results were reported [27,28,29,30,31,32], most of the technically important data and results remain secret. The second stage was followed by several national projects [21,33,34,35,36,37]. Many publications were available from the national projects and other studies regarding seafloor FN miner design [38,39,40,41,42], the hydraulic lifting characteristics of FN in a pipeline [43,44,45,46,47], and the hydro-dynamics of the pipeline [48,49,50,51,52]. Among the national projects, ones conducted by China, India, Korea, and InterOceanMetals are still active.
Some important results and reviews of FN metallurgical processing have also been reported [53,54,55,56,57,58,59]. Most of the proposed processing methods were examined in Kojima [56], and the smelting and chlorine leaching method (SCL) was concluded to have an advantage in the study, though its cost was relatively higher than that of some hydro-metallurgical methods because of its waste-free characteristics.
The specifications of mining 5000 t/d in dry conditions, the transportation and the metallurgical processing systems, and the capital and operation expenditures (CAPEX and OPEX) of FN production were discussed in the ISA workshop in Chennai, India, in 2008. About 50 specialists in FN mining technologies, metallurgical processing, economy, and international law of the sea attended. The ISA controls all mineral resources-related activities in the international seabed area by law. Mining and metallurgical processing methods and cost analysis models were presented at first, then three working groups related to the mining technology, the metallurgical processing, and the economic model were created and the working groups reviewed the past published R&D results and models. At the end of the workshop, CAPEX, OPEX, and methods for mining, transportation, metallurgical processing, and model selection in the working groups were reported. Four mining methods with different collectors and risers and one processing method with hydrometallurgy were included in the report. The four mining methods involved using (a) a passive collector, (b) a tracked collector, (c) a Chinese collector with a steel riser pipe, and (d) Indian small tracked collectors with flexible risers. Applying the results of the workshop, the results of the economic feasibility analyses, including manganese recovery conducted after the workshop, were distributed to the attendees of the workshop [60]. Only the summary was open to the public [61]. Though updated distribution models of the CCZ have been presented by the ISA in the last ten years [62,63], no effective economic feasibility study has been undertaken.

3. Previous Economic Evaluation of REE-Rich Mud Mining

In the previous study [8], a production scale of 4000 t/d for REE-rich mud in dry conditions was assumed. Among the specifications for the mining, the transportation, the metallurgical processing systems, and CAPEX and OPEX for 5000 t/d of FN production in dry conditions in the ISA workshop report [60], the same tracked collector and lift sub-systems for FN were assumed as the ones for REE-rich mud. The CAPEX and OPEX for a larger production scale of FN than the ones for REE-rich mud were thought to cover some additional expenditures for REE-rich mud sub-systems. On the other hand, the mining vessel and many of the onboard facilities were newly examined and roughly designed in the study. Additionally, an acid leach and solvent separation process similar to that of Abe et al. [3] was assumed in the rare-earth element recovery. The similarities and differences between FN and REE-rich mud mining assumed in the study are summarized in Table 2. Though the mud excavator is different in terms of the nodule collector and the depth is more than that in the ISA model, all the CAPEX and OPEX of the system components such as excavator, riser, and pump and some of the onboard facilities were assumed to be the same as in the ISA model for the tracked collector and lift sub-systems. If the water content of REE-rich mud is assumed to be 66.7%, roughly estimated value from photos the core samples, the bulk density becomes about 1.5 g/cm3. Because of the high cohesiveness of REE-rich mud, the spatial concentration in the riser is kept similar to that in the ISA model. Thus, the daily production of REE-rich mud in the same mining system with the ISA model becomes about 4000 t/d in dry conditions under a 40,000 m3 daily volume of mud and water mixture lifted. The volumetric concentration is 6.67%. Because the mining site is in an open ocean area and close to equator, the total operation days per year were assumed as 250 days from the data used for the Japanese FN collector test near Minamitorishima Island [35]. The thickness of the excavated sediment layer was assumed to be 5 m from the seafloor and the average rare-earth element content was assumed to be about 2000 ppm.
The mining vessel herself and many of the onboard facilities were assumed to be different from those of the ISA model. The most important point in the design of the onboard facilities is how to concentrate the mud and water mixture. The easiest and cheapest method for concentration is gravity settling in a tank. Because REE-rich mud is classified into silty clay from a water depth of 5600 to 5800 m, it is difficult to achieve gravity settling. However, the cohesion of clayey particles accelerates the settling process [64]. Therefore, the use of a four-tank concentration and dewatering system for 4 days was proposed and assumed. One of the tanks was used for receiving the mud and water mixture on the first day. Then, on the second day it was used for gravity settling for 1 day. The supernatant water was discharged from the tank into the middle water column at a depth of 500 m because no chemical treatment was applied. The water content of the settled REE-rich mud at this stage became about 90% and the specific density is 1.15 g/cm3. The dry-up dewatering operation was separated into two stages. At first, a moderate temperature of 60–80 degrees in Celsius (°C) was applied to the settled mud for 1 day, then a temperature of 110 °C was used for 1 day in the same tank. The 1-day products stayed in the same tank. It was necessary to install water discharge and dry-up facilities in all the four tanks. Because of these installations, however, mud transfer among the tanks was not necessary. At the end of the concentration and dewatering after 4 days, the dried mud cakes were transferred and stored until they had to be loaded into a transportation vessel. The size of the mining vessel had to be large because of the four tanks, storage area, and other onboard facilities necessary.
Three economic measures calculated in the previous study were the net present value (NPV), the internal rate of return (IRR), and the payback period (PP). Though the rare-earth element prices given in the study were considered to be very expensive ones in 2012 and the waste disposal cost was not included, the results presented were minus $549M in NPV, minus 2.73% in IRR, and N/A in PP. None of these are good values in terms of economy. The main reasons for these values were the use of the large mining vessel, the lower concentration of slurry in the riser, and the lower income from rare-earth element sales.

4. Mining Model: Combined Mining of REE-Rich Mud and FN by Pulp-Lifting

In 2016, a vast FN area of co-distribution with REE-rich mud was found by JAMSTEC near Minamitorishima Island in the Japanese EEZ. The location and nodule distribution aspects were introduced [65]. The area size was expected to be 44,000 km2 at the time, and updated information for nodule distribution in this area has been reported [66]. The metal contents of FN were similar to those of the cobalt-rich ferromanganese crusts on the Pacific seamounts [67]. The same type of co-distribution area—FN with REE-rich mud—has been found beyond the Japanese EEZ around Minamitorishima Island, and China was authorized a third FN contract in the co-distribution areas next to the Japanese EEZ from ISA in 2019 [68].
Because of the co-distribution, a unique lift method is applicable for the combined mining of REE-rich mud and FN. The method is called pulp-lifting. It was investigated in a French FN R&D program in the 1980s [43]. A non-Newtonian solid–water mixture with a high solid volumetric concentration of 55~60% was created by mixing crushed FN, deep-sea sediments, and water. Then, the mixture was circulated in a 15 m vertical experimental pipeline by a piston pump. Because of the drastic reduction in frictional resistance between the pipe wall and the high-concentration pulp, it was clarified that the pipe diameter would be about half of the one needed for a same-nodule mass transportation under a normal solid–liquid slurry. The pump power necessary was found to be lower than one needed for the same mass transportation one under solid–liquid slurry conditions. Pulp-lifting has never been used in any deep-sea mining programs, but the method is popularly applied for coal–water mixtures (CWMs) in many coal electricity power stations. CWM created by powder coal and water with a mass concentration of about 70% is supplied to a boiler through a pipeline [69].
In the mining model of REE-rich mud and FN proposed in this study, the following assumptions were selected as basic conditions from the reviewed FN mining technologies, including feasibility studies, metallurgy, and other factors:
  • Production rate of 6000 t/d in dry conditions in REE-rich mud and 3000 t/d in dry conditions in FN;
  • Hydraulic cut and suction for REE-rich mud excavation;
  • Hydraulic suction for FN collection then crushing;
  • Mixing and pulp-making then feeding to a piston pump;
  • Pumping up through a riser;
  • Solid volumetric concentration of 55% and seawater concentration of 45% in pulp;
  • Water depth of 5800 m;
  • Drying lifted pulp then transferring it to carrier vessels;
  • Transportation distance of 2000 km from Minamitorishima Island EEZ to the leaching and processing location in Japan’s mainland;
  • Separation of REE-rich mud and crushed FN;
  • Leaching by HCl and solvent extraction with recovery ratios of 24% for Ce and 92% for other rare-earth elements in REE-rich mud [3];
  • Brick making by adding cement powder to the leached mud after neutralization and desalting then providing it for construction material free of charge;
  • Processing by SCL with recovery ratios of 80% for Mn and 94% for the other three metals in FN [56];
  • Processed slag sales as concrete aggregate in 100 $/t;
  • Calculating the CAPEX and OPEX of the mining model except for the brick-making and processing using an equation based on ones in the previous study [8]:
    C A = C B ( a A a B ) n
    where CA = the value in this study; CB = the value in the previous study; aA = the total mass in this study; aB = the total mass in the previous study; n = 0.6 scale factor [70].
  • Calculating the CAPEX and OPEX of the brick-making on the basis of Tsuji et al. [71];
  • Calculating the CAPEX and OPEX of the processing using Equation (1) on the basis of Kojima [56] and Park et al. [72].
One of the most important assumptions is the production rate of 6000 t/d in dry conditions in REE-rich mud. This was calculated from Japan’s domestic rare-earth element consumptions and the rare-earth element contents of the REE-rich mud recovered. The production rate of 3000 t/d in dry conditions in FN was selected as half of REE-rich mud. Japan’s domestic consumptions of the four metals are quite a lot larger than the masses recovered. Because higher concentrations of REE-rich mud and crushed FN and lower amounts of seawater from the pulp-lifting come up to the mining vessel, everything underwater and the onboard facilities including the vessel herself are smaller than those used the previous studies [3,8,60]. The direct drying of the lifted pulp is also induced from the higher concentrations. The separation of water from the pulp is difficult but the drying process is easy. One more important point is the selection of the metallurgical processing method. The SCL is a waste-free method and the best choice for Japan’s social and geographical situation. The slag is reused after smelting for aggregate and the sulfur liquid after the leaching is refreshed and reused for leaching. The CAPEX and the OPEX of the mining system are less expensive, as shown in Table 3. In the recovery of REE-rich mud on the seafloor, it is difficult to remove the overlaid sediment layer with smaller rare-earth element contents. An averaged rare-earth element content from the seafloor surface to the target depth of about 1000 ppm, the same as in Abe et al. [3] shown in Table 4, is assumed in the mining model. For example, the average top 5 m of the sediment column becomes 1000 ppm in the case of 0 ppm from the seafloor surface through to 4 m and 5000 ppm from 4 through to 5 m. The metal contents of FN presented by JAMSTEC [65] and shown in Table 5 are assumed in the mining model. They are cobalt-rich, copper-poor, and nickel-poor, similar to the cobalt-rich ferromanganese crusts on the Pacific seamounts and different from the FN in the CCFZ.

5. Economic Feasibility of the Combined Mining of REE-Rich Mud and FN by Pulp-Lifting

5.1. Results of Basic Condition

Data on prices of rare-earth elements are available through paying member sites [73,74]. In this study, based on the 5-year average prices of rare-earth elements in the period 2013–2017 [75] (to exclude the higher ones in 2012), the 10-year average prices of the four metals in the period 2008–2017 [75], the contents in Table 4 and Table 5, and their recovery ratios assumed in the mining model, the revenues of the mining model under the basic conditions are calculated as shown in Table 6. It is obvious that the revenues from FN are 4.7 times more than the ones from REE-rich mud under the basic conditions of the combined mining model. In the economic evaluation, the first 3 years are assumed to be devoted to construction with no income, while the fourth year is assumed to be used for test operations with 50% income. Then, the next 16 years, from the 5th year to the 20th year, are assumed to be used for full mining, with 100% income. The total yearly income is calculated as about $780M, because the revenues listed in Table 6 and about $50M from the slag sales are the total. The same three economic measures—NPV, IRR, and PP—are calculated as shown in Table 7. The results show a slight negative economy.

5.2. Sensitivity Analyses by FN Production Rate

Because the revenues from FN shown in Table 7 have larger effects on economy, sensitivity analyses using the FN production rate are examined. In the analyses, the production of REE-rich mud is fixed as 6000 t/d and the one for FN is increased from 3000 to 7000 t/d. In each of the analyses, CAPEX, OPEX, and the income are recalculated. The results of the NPV are summarized in Figure 1. About 4000 t/d is found as the point of NPV = 0.

6. Expected Geotechnical Characteristics of REE-Rich Mud

Because the water depth, 5600–5800 m, is deeper than the carbonate compensation depth (CCD), REE-rich mud is composed of siliceous particles and classified into pelagic clay. No geotechnical data such as water content and cohesiveness are available to examine technical problems for REE-rich mud excavation on the seafloor. Though some data are available on deep-sea siliceous sediments [76,77], the technical problems expected for the excavation were examined based on the little data available. Example geotechnical properties of siliceous deep-sea sediments in shallow layers are shown in Figure 2 [76] and properties from shallow to deep layers are shown in Figure 3 [77]. Using recovered box-core samples, 50 cm square and 30–40 cm in height, the vane shear strength, sensitivity, water content, and cone penetration resistance were measured in the core column, as shown in Figure 2 [76]. In the vane shear strength and the sensitivity, the relationship is defined by Equation (2) [78]. In Figure 2 and Figure 3, the water content was calculated by Equation (3). The relationships among the geotechnical strength characteristics of clayey sediments are generally given by Equation (4) [79]. Using a recovered gravity-core sample that was 11 cm in diameter and 261 cm in height, measurements of some geotechnical factors were conducted. From these factors, the solid density, bulk density, and water content were calculated, as shown in Figure 3 [77]. From the obtained results shown in Figure 3, the highly cohesive and clayey nature of the gravity-core sample was recognized.
S t = S v o / S v r
where St = sensitivity, Svo = original undisturbed vane shear strength, Svr = remolded vane shear strength.
w = ( W W W O ) / W O × 100
where w = water content, Ww = water-saturated weight in air, Wo = dried weight in air.
q u = 0.2 × q c = 2 × S v o
where qu = undisturbed uniaxial strength, qc = cone penetration resistance.

7. Technical Considerations

The solid density of 3.25 g/cm3 and the porosity of 55% were reported for FN [80]. From these values, the volumetric concentration of about 45% for FN was calculated. From the water contents, 200~350% in Figure 2 and 330~493% in Figure 3, the volumetric concentration of 7~16% is expected for REE-rich mud. The value of 45% for FN is not bad, but the value of 7~16% for REE-rich mud is quite low compared with the one of 55~60% in the French pulp-lifting experiment [43]. To create a good pulp condition, the question of how to reduce seawater in REE-rich mud on the seafloor is considered to be of primary importance. The high cohesiveness of 12~21 kPa in Figure 3 is the secondary problem, but the sensitivity of about 3 in Figure 2 looks to be helpful to reduce the cohesiveness by remolding REE-rich mud during the excavation. The question of how to crush FN and make smaller particles on the seafloor is the third problem. Meanwhile, how to mix REE-rich mud and the crushed FN particles is the fourth problem and how to feed the mixture to a piston pump is the fifth. A good water content of REE-rich mud and a good size distribution of crushed FN for pulp-lifting must be experimentally clarified at first.
The next important is the service lifetime of the riser pipe. From the viewpoint of economy, usually the usage of a steel pipe is assumed in deep-sea mining models [2,3,4,8,19,20,21,60,72] and in this study, except in the mechanical lift model [22]. The other technological studies introduced as references in this study are related to the lift conditions in the steel pipe and the pipe dynamics of the steel pipe, except for the studies on metallurgical processing. However, the relatively short time of 2-5 years was reported in the case of the 1700 m water depth and several hundred tons in weight, including a submerged pump under a maximum wave height of 6 m for massive seafloor sulfide mining in Papua New Guinea [81]. In the case of deeper and rough wave conditions for the combined mining of REE-rich mud and FN, a shorter service lifetime is expected. Depending on the lifetime, it should be concluded that there would be greater OPEX for the steel riser pipe. The clarification of this problem is necessary.
Some other technical efforts such as clarifying the brick-making process by adding cement powder to the waste mud and checking the engineering properties of the processed slag as concrete aggregate are also important, because these are key points in their reuse.
After these technical clarifications, a realistic economic feasibility analysis will be conducted. We note that although detailed and useful geological data of REE-rich mud have already been published [82,83,84,85], the geotechnical data corresponding to geological variations are not available currently.

8. Mining Area Management Plan

The mining area sizes necessary for the combined mining of REE-rich mud and FN are different. If the average FN population in the co-distribution area is the same as the one in CCFZ—10 kg/m2 in wet conditions—the population in dry conditions becomes 7.2 kg/m2 for the solid density and porosity of FN. Under the FN population, 417,000 m2 per day must be covered for an FN production of 3000 t/d. In case of an REE-rich mud production of 6000 t/d under the mining model and geotechnical characteristics detailed in this study, 4000 m2 per day must be excavated up to 5 m deep. The area size for REE-rich mud is only about 1% of that for FN. To minimize the horizontal transportation distance, the mining site for REE-rich mud should be placed at the center of the one for FN. The daily mining area management is expected to be similar to that in Figure 4. The area size of the co-distribution of REE-rich mud and FN increased from the first press release value of 44,000 km2 [65] to the updated value of 70,500 km2 [66]. From the area size necessary for daily FN mining, about 560 years (under 300 days of operation per year) is the expected lifetime of the combined mining under the basic conditions in the Japanese EEZ around Minamitorishima Island.

9. Concluding Remarks

The area of the co-distribution of REE-rich mud and FN in the Japanese EEZ has a chance to be used for commercial mining. The following three innovative changes in the mining model have improved the economy of the mining:
  • Combined mining with REE-rich mud and FN;
  • Pulp-lifting;
  • Reuse of waste mud and processed slag as construction materials.
The production ratio of 6000 t/d for REE-rich mud versus 3000 t/d for FN is slightly negative in economy. More FN in the pulp concentrates is necessary for a better economy. An appropriate water content of REE-rich mud and a good size distribution of crushed FN for pulp-lifting must be clarified first.

Author Contributions

Conceptualization, T.Y. and N.N.; methodology, T.Y.; software, T.Y.; validation, N.N. and R.A.; investigation, T.Y.; resources, T.S. and H.K.; writing—original draft preparation, T.Y.; writing—review and editing, T.S. and H.K.; supervision, R.A.; project administration, N.N. All authors have read and agreed to the published version of the manuscript.

Funding

This research received no external funding.

Institutional Review Board Statement

Not applicable.

Informed Consent Statement

Not applicable.

Data Availability Statement

Not applicable.

Acknowledgments

The data curation of the study was conducted by Kazuyuki Hayashi when he wrote a bachelor thesis related to the subject.

Conflicts of Interest

The authors declare no conflict of interest.

References

  1. Kato, Y.; Fujinaga, K.; Nakamura, K.; Takaya, Y.; Kitamura, K.; Ohta, J.; Toda, R.; Nakashima, T.; Iwamori, H. Deep-sea mud in the Pacific Ocean as a potential resource for rare-earth elements. Nat. Geosci. 2011, 4, 535–539. [Google Scholar] [CrossRef]
  2. Bashir, M.B.; Kim, S.H.; Kiosidou, E.; Wolgamot, H.; Zhang, W. A Concept for Seabed Rare Earth Mining in the Eastern South Pacific; LRET Collegium 2012 Series; University Southampton: Southampton, UK, 2012; Volume 1, p. 121. [Google Scholar]
  3. Abe, K.; Watanabe, D.; Fujinaga, K.; Kato, Y.; Nakamura, T.; Yamazaki, T. Technical and Economic Feasibility Study on Rare-earth Elements and Yttrium-rich Mud. In Proceedings of the 23rd Ocean Engineering Symposium, Tokyo, Japan, 2–3 August 2012. JFOES & JASNAOE, OES23-089 (In Japanese with English Abstract). [Google Scholar]
  4. Wolgamot, H.; Zhang, W.; Kiosidou, E.; Kim, S.H.; Bashir, M. Considerations for Seabed Rare Earth Mining in the Pacific. In Proceedings of the 32nd International Conference on Ocean, Offshore and Arctic Engineering, Nantes, France, 9–14 June 2013. OMAE2013-10844. [Google Scholar]
  5. JAMSTEC Press Releases. Available online: http://www.jamstec.go.jp/e/about/press_release/20130321/ (accessed on 26 October 2020).
  6. Iijima, K.; Yasukawa, K.; Fujinaga, K.; Nakamura, K.; Machida, S.; Takaya, Y.; Ohta, J.; Haraguchi, S.; Nishio, Y.; Usui, Y.; et al. Discovery of extremely REY-rich mud in the western North Pacific Ocean. Geochem. J. 2016, 50, 557–573. [Google Scholar] [CrossRef] [Green Version]
  7. Takaya, Y.; Yasukawa, K.; Kawasaki, T.; Fujinaga, K.; Ohta, J.; Usui, Y.; Nakamura, K.; Kimura, J.-I.; Chang, Q.; Hamada, M.; et al. The tremendous potential of deepsea mud as a source of rare-earth elements. Sci. Rep. 2018, 8, 1–8. [Google Scholar] [CrossRef] [PubMed] [Green Version]
  8. Yamazaki, T.; Yamamoto, Y.; Nakatani, N.; Arai, R. Preliminary Economic Evaluation of Deep-sea REE Mud Mining. In Proceedings of the 33rd International Conference on Ocean, Offshore and Arctic Engineering, San Francisco, CA, USA, 8–13 June 2014. OMAE2014-23141. [Google Scholar]
  9. Mero, J.L. The Mineral Resources of the Sea; Oceanography Series, 1; Elsevier: Amsterdam, The Netherlands, 1965; p. 312. [Google Scholar]
  10. Cronan, D.S. Underwater Minerals; Academic Press: London, UK, 1980; p. 362. [Google Scholar]
  11. Craig, J.D.; Andrews, J.E. A Factor Analysis Study of Deep Sea Ferromanganese Deposits in the Equatorial North Pacific Ocean. Mar. Min. 1978, 1, 305–326. [Google Scholar]
  12. Andrews, J.E.; Friedrich, G.H.W. Distribution Patterns of Manganese Nodule Deposits in the Northeast Equatorial Pacific. Mar. Min. 1979, 2, 1–43. [Google Scholar]
  13. Friedrich, G.; Glasby, G.P.; Thijssen, T.; Plüger, W.L. Morphological and Geochemical Characteristics of Manganese Nodules Collected from Three Areas on an Equatorial Pacific Transect by RV Sonne. Mar. Min. 1983, 4, 167–253. [Google Scholar]
  14. Von Stackelberg, U.; Beiersdorf, H. The Formation of Manganese Nodules between the Clarion Clipperton Fracture Zones Southeast of Hawaii. Mar. Geol. 1991, 98, 411–423. [Google Scholar] [CrossRef]
  15. Morgan, C.L.; Nichols, J.A.; Selk, B.W.; Toth, J.R.; Wallin, C. Preliminary Analysis of Exploration Data from Pacific Deposits of Manganese Nodules. Mar. Georesour. Geotechnol. 1993, 11, 1–25. [Google Scholar] [CrossRef]
  16. ISA. POLYDAT: Polymetallic nodule database. In Proceedings of the Workshop on Proposed Technologies for Mining Deep-Seabed Polymetallic Nodules, International Seabed Authority, Kingston, Jamaica, 3–6 August 1999; pp. 447–456. [Google Scholar]
  17. Padan, J.W. Commercial Recovery of Deep—Seabed Manganese Nodules: Twenty Years of Accomplishments. Mar. Min. 1990, 9, 87–103. [Google Scholar]
  18. ISA. Plans of Work for Exploration of Government of India, IFREMER/AFERNOD, DORD, Yuzhmorgeologiya, COMRA, IOM, Republic of Korea; Report of the Secretary General No. ISBA/4/A/1/Rev.2; International Seabed Authority: Kingston, Jamaica, 1998; p. 47. [Google Scholar]
  19. Andrews, B.V.; Flipse, J.E.; Brown, F.C. The Economic Viability of a Four-Metal Pioneer Deep Ocean Mining Venture; PB84-122563; US Dept. of Commerce: Washington, DC, USA, 1983; p. 201. [Google Scholar]
  20. Hillman, C.T.; Gosling, B.B. Mining Deep Ocean Manganese Nodules: Description and Economic Analysis of a Potential Venture; IC 9015; US Bureau of Mines: Washington, DC, USA, 1985; p. 19. [Google Scholar]
  21. Charles, C.; Herrouin, G.; Mauviel, F.; Bernard, J. Views on Future Nodule Technologies Based on IFREMER-GEMONOD Studies. Mater. Soc. 1990, 14, 299–326. [Google Scholar]
  22. Søreide, F.; Lund, T.; Markussen, J.M. Deep Ocean Mining Reconsidered a Study of the Manganese Nodule Deposits in Cook Island. In Proceedings of the 4th ISOPE Ocean Mining Symposium, Szczecin, Poland, 23–27 September 2001; pp. 88–93. [Google Scholar]
  23. Honkawa Data Tribune. Available online: https://honkawa2.sakura.ne.jp/5500.html (accessed on 26 December 2020). (In Japanese).
  24. Welling, C.G. An advanced design deep sea mining system. In Proceedings of the 13th Offshore Technology Conference, Houston, TX, USA, 4–7 May 1981. [Google Scholar]
  25. Kaufman, R.; Latimer, J.P.; Tolefson, D.C. The design and operation of a Pacific Ocean deep ocean mining test ship: R/V Deepsea Miner II. In Proceedings of the 17th Offshore Technology Conference, Houston, TX, USA, 6–9 May 1985. [Google Scholar]
  26. Bath, A.R. Deep sea mining technology: Recent developments and future projects. In Proceedings of the 21st Offshore Technology Conference, Houston, TX, USA, 1–4 May 1989. [Google Scholar]
  27. Heine, O.R.; Suh, S.L. An Experimental Nodule Collection Vehicle Design and Testing. In Proceedings of the 10th Offshore Technology Conference, Houston, TX, USA, 8–11 May 1978. [Google Scholar]
  28. Clauss, G. Hydraulic Lifting in Deep-Sea Mining. Mar. Min. 1978, 1, 189–208. [Google Scholar]
  29. Burns, J.Q.; Suh, S.L. Design and Analysis of Hydraulic Lift Systems for Deep Ocean Mining. In Proceedings of the 11th Offshore Technology Conference, Houston, TX, USA, 30 April 1979. [Google Scholar]
  30. Grote, P.B.; Burns, J.Q. System Design Considerations in Deep Ocean Mining Lift System. Mar. Min. 1981, 2, 357–383. [Google Scholar]
  31. Chung, J.S.; Whitney, A.K.; Loden, W.A. Nonlinear Transient Motion of Deep Ocean Mining Pipe. J. Energy Resour. Technol. 1981, 103, 2–10. [Google Scholar] [CrossRef]
  32. Kollwentz, W. Lessons Learned in the Development of Nodule Mining Technology. Mater. Soc. 1990, 14, 285–298. [Google Scholar]
  33. Kotlinski, R. InterOceanMetal Joint Organization: Achievements and Challenges. In Proceedings of the 1st ISOPE Ocean Mining Symposium, Tsukuba, Japan, 21–22 November 1995; pp. 5–7. [Google Scholar]
  34. Yang, N.; Wang, M. New Era for China Manganese Nodules Mining: Summary of Last Five Years’ Research Activities and Prospective. In Proceedings of the 2nd ISOPE Ocean Mining Symposium, Seoul, Korea, 24–26 November 1997; pp. 8–11. [Google Scholar]
  35. Yamada, H.; Yamazaki, T. Japan’s Ocean Test of the Nodule Mining System. In Proceedings of the 8th International Offshore and Polar Engineering Conference, Montreal, QC, Canada, 24–29 May 1998; pp. 13–19. [Google Scholar]
  36. Hong, S.; Kim, K.-H. Research and Development of Deep Seabed Mining Technologies for Polymetallic Nodules in Korea. In Proceedings of the Proposed Technologies for Deep Seabed Mining of Polymetallic Nodules, International Seabed Authority, Kingston, Jamaica, 3–6 August 1999; pp. 261–283. [Google Scholar]
  37. Muthunayagam, A.E.; Das, S.K. Indian polymetallic nodule program. In Proceedings of the 3rd ISOPE Ocean Mining Symposium, Goa, India, 8–11 November 1999; pp. 1–5. [Google Scholar]
  38. Li, L.; Zhang, J. The China’s Manganese Nodules Miner. In Proceedings of the 2nd ISOPE Ocean Mining Symposium, Seoul, Korea, 24–26 November 1997; pp. 95–99. [Google Scholar]
  39. Yasukawa, H.; Ikegami, K.; Minami, T. Motion Analysis of a Towed Collector for Manganese Nodule Mining in Ocean Test. In Proceedings of the 9th International Offshore and Polar Engineering Conference, Brest, France, 30 May–4 June 1999; pp. 100–107. [Google Scholar]
  40. Hong, S.; Choi, J.-S.; Kim, J.-H.; Yang, C.-H. Experimental Study on Hydraulic Performance of Hybrid Pickup Device of Manganese Nodule Collector. In Proceedings of the 3rd ISOPE Ocean Mining Symposium, Goa, India, 8–11 November 1999; pp. 69–77. [Google Scholar]
  41. Yamazaki, T.; Kuboki, E.; Yoshida, H. Tracing Collector Passes and Preliminary Analysis of Collector Operation. In Proceedings of the 3rd ISOPE Ocean Mining Symposium, Goa, India, 8–11 November 1999; pp. 55–62. [Google Scholar]
  42. Deepak, C.R.; Shajahan, M.A.; Atmanand, M.A.; Annamalai, K.; Jeyamani, R.; Ravindran, M.; Schulte, E.; Handschuh, R.; Panthel, J.; Grebe, H.; et al. Developmental Test on the Underwater Mining System Using Flexible Riser Concept. In Proceedings of the 4th ISOPE Ocean Mining Symposium, Szczecin, Poland, 23–27 September 2001; pp. 94–98. [Google Scholar]
  43. Bernard, J.; Bath, A.R.; Greger, B. Analysis and comparison of nodule hydraulic transport systems. In Proceedings of the 9th Offshore Technology Conference, Houston, TX, USA, 27–30 April 1987; p. 5476. [Google Scholar]
  44. Saito, T.; Usami, T.; Yamazaki, T.; Tomishima, Y.; Kiyono, F. Lifting Characteristics of Manganese Nodules by Air-Lift-Pump on 200m Vertical Test Plant. In Proceedings of the OCEANS’89, Seattle, WA, USA, 8–21 September 1989; pp. 48–53. [Google Scholar]
  45. Xia, J.; Xia, L.; Zau, W.; Tang, D.; Huang, J.; Wang, S. Studies on Reasonable Hydraulic Lifting Parameters of Manganese Nodules. In Proceedings of the 2nd ISOPE Ocean Mining Symposium, Seoul, Korea, 24–26 November 1997; pp. 112–116. [Google Scholar]
  46. Yoon, C.-H.; Kwon, K.-S.; Kwon, O.-K.; Kwon, S.-K.; Kim, I.-K.; Lee, D.-K.; Lee, H.-S. An Experimental Study on Lab Scale Air-Lift Pump Flowing Solid-Liquid-Air Three-Phase Mixture. In Proceedings of the 10th International Offshore and Polar Engineering Conference, Seattle, WA, USA, 27 May–2 June 2000; pp. 515–521. [Google Scholar]
  47. Chung, J.S.; Lee, K.; Tischler, A.; Yarim, G. Effect of Particle Size and Concentration on Pressure Gradient in Two-Phase Vertically Upward Transport. In Proceedings of the 4th ISOPE Ocean Mining Symposium, Szczecin, Poland, 23–27 September 2001; pp. 132–138. [Google Scholar]
  48. Aso, K.; Kan, K.; Doki, H.; Ohkoshi, T. The Effect of Vibration Absorbers on the Longitudinal Vibration of a Pipe String in the Deep Sea—Part 2: A Case of Mining Manganese Nodules. Int. J. Offshore Polar Eng. 1994, 4, 62–67. [Google Scholar]
  49. Chung, J.S.; Cheng, B.-R.; Huttelmaier, H.P. Three-Dimensional Coupled Responses of a Vertical Deep-Ocean Pipe: Part II. Excitation at Pipe Top and External Torsion. Int. J. Offshore Polar Eng. 1994, 4, 321–339. [Google Scholar]
  50. Cheng, B.-R.; Chung, J.S. Effects of Axial Dampers and Elastic Joints on 3-D Dynamic Responses of a Deep-Ocean Pipe with Torsional Coupling. Int. J. Offshore Polar Eng. 1997, 7, 36–43. [Google Scholar]
  51. Ohta, T.; Morikawa, M. Bending Strength of Lifting Pipes Handling of Pipe Connection in Manganese Mining System. In Proceedings of the 2nd ISOPE Ocean Mining Symposium, Seoul, Korea, 24–26 November 1997; pp. 68–74. [Google Scholar]
  52. Handschuh, R.; Grebe, H.; Panthel, J.; Schulte, E.; Wenzlawski, B.; Schwarz, W.; Atmanand, M.A.; Jeyamani, R.; Shajahan, M.; Deepak, R.; et al. Innovative Deep-Ocean Mining Concept Based on Flexible Riser and Self-propelled Mining Machine. In Proceedings of the 4th ISOPE Ocean Mining Symposium, Szczecin, Poland, 23–27 September 2001; pp. 99–107. [Google Scholar]
  53. Agarwal, J.C.; Beecher, N.; Davies, D.S.; Hubred, G.L.; Kakaria, V.K.; Moslen, J.H. Comparative Economics of Recovery of Metals from Ocean Nodules. Mar. Min. 1979, 2, 119–130. [Google Scholar]
  54. Hubred, G.L. Manganese Nodule Extractive Metallurgy Review 1973–1978. Mar. Min. 1980, 2, 191–212. [Google Scholar]
  55. Black, J.R.H. Metals Recovery from Manganese Nodules: A Review of Processing Schemes. In Marine Mining: A New Beginning; Humphrey, P.B., Ed.; Hawaii Department of Planning and Economic Development: Honolulu, HI, USA, 1982; pp. 93–107. [Google Scholar]
  56. Kojima, K. Review of Studies on Manganese Nodules Processing. In Proceedings of the 2nd ISOPE Ocean Mining Symposium, Seoul, Korea, 24–26 November 1997; pp. 19–22. [Google Scholar]
  57. Kim, D.-J.; Park, K.-H. Study on the Leaching Mechanism of Cu and Ni from Deep-sea Manganese Nodules with Hydrochloric Acid. In Proceedings of the 2nd ISOPE Ocean Mining Symposium, Seoul, Korea, 24–27 November 1997; pp. 172–176. [Google Scholar]
  58. Xiang, Z.; Zequan, H.; Yujun, S.; Yongjun, M.; Shuguang, Q.; Xianbai, L. The Smelting-Rusting-Solvent Extraction Process to Recover Valuable Metals from Polymetallic Nodules. In Proceedings of the 3rd ISOPE Ocean Mining Symposium, Goa, India, 8–11 November 1999; pp. 227–231. [Google Scholar]
  59. Das, R.P. India’s Demonstration Metallurgical Plant to Treat Ocean Nodule. In Proceedings of the 4th ISOPE Ocean Mining Symposium, Szczecin, Poland, 23–27 September 2001; pp. 163–166. [Google Scholar]
  60. ISA. Polymetallic Nodule Mining Technology: Current Status and Challenges Ahead. In Proceedings of the Executive Summary of ISA workshop, Chennai, India, 18–22 February 2008. [Google Scholar]
  61. ISA. Report on the International Seabed Authority’s Workshop on Polymetallic Nodule Mining Technology: Current status and Challenges Ahead. Available online: https://www.isa.org.jm/files/documents/EN/14Sess/LTC/ISBA-14LTC-3.pdf (accessed on 26 October 2020).
  62. ISA. A Geological MODEL of Polymetallic Nodule Deposits in the Clarion-Clipperton Fracture Zone; ISA Technical Study: No. 6; International Seabed Authority: Kingston, Jamaica, 2010; p. 211. [Google Scholar]
  63. ISA. Polymetallic Nodules Resource Classification -Report of an International Workshop Held in 2014-, ISA Technical Study: No. 19; International Seabed Authority: Kingston, Jamaica, 2017; p. 79. [Google Scholar]
  64. Yamazaki, T.; Kuboki, E.; Yoshida, H.; Suzuki, T. A Consideration on Size Distribution of Resuspended Deep-sea Sediments. In Proceedings of the 10th International Offshore and Polar Engineering Conference, Seattle, WA, USA, 27 May–2 June 2000; pp. 507–514. [Google Scholar]
  65. JAMSTEC Press Releases. Available online: http://www.jamstec.go.jp/e/about/press_release/20160826/ (accessed on 26 October 2020).
  66. Machida, S.; Sato, T.; Yasukawa, K.; Nakamura, K.; Iijima, K.; Nozaki, T.; Kato, Y. Visualisation method for the broad distribution of seafloor ferromanganese deposits. Mar. Georesour. Geotechnol. 2021, 39, 267–279. [Google Scholar] [CrossRef] [Green Version]
  67. Machida, S.; Fujinaga, K.; Ishii, T.; Nakamura, K.; Hirano, N.; Kato, Y. Geology and geochemistry of ferromanganese nodules in the Japanese Exclusive Economic Zone around Minamitorishima Island. Geochem. J. 2016, 50, 539–555. [Google Scholar] [CrossRef] [Green Version]
  68. ISA. Available online: https://www.isa.org.jm/exploration-contracts/beijing-pioneer-hi-tech-development-corporation and https://www.isa.org.jm/map/beijing-pioneer-hi-tech-development-corporation (accessed on 26 October 2020).
  69. Ogawa, J.; Shibata, K. Production Technology of COM and CWM. J. Fuel Soc. Jpn. 1990, 69, 828–832, (In Japanese with English Abstract). [Google Scholar] [CrossRef]
  70. Japan Coal Development Technology Cooperation Center. Mine Investment Analysis, Overseas Coal Development Technical Guide; Japan Coal Development Technology Cooperation Center: Tokyo, Japan, 1993; Volume 2, p. 55. (In Japanese) [Google Scholar]
  71. Tsuji, T.; Tanaka, Y.; Nakagawa, M.; Nonaka, S.; Nagao, K.; Akashi, Y.; Kiso, E.; Tasaki, T. Materials Properties and Production Technology of Artificial Stone Using the Dredged Soil. J. Jpn. Soc. Civ. Eng. Ser. B3 (Ocean Eng.) 2015, 71, I_1173–I_1178, (In Japanese with English Abstract). [Google Scholar]
  72. Park, S.; Yamazaki, T.; Shimada, S.; Yamamoto, T. Development Potential Examination Method for Cobalt-rich Manganese Crusts. J. Min. Mater. Process. Inst. Jpn. 2002, 118, 641–649, (In Japanese with English Abstract). [Google Scholar]
  73. SMM Information & Technology. Available online: https://www.metal.com/ (accessed on 7 February 2021).
  74. MetalPrices. Available online: https://mineralprices.com/ (accessed on 7 February 2021).
  75. Dataset of World Economy. Available online: https://ecodb.net/commodity/metal/ (accessed on 26 October 2020). (In Japanese).
  76. Yamazaki, T.; Tsurusaki, K.; Handa, K.; Inagaki, T. Geotechnical Properties of Deep Ocean Sediment Layer. J. Min. Mater. Process. Inst. Jpn. 1995, 110, 309–315, (In Japanese with English Abstract). [Google Scholar]
  77. Yamazaki, T.; Komine, T.; Kawakami, T. Geotechnical Properties of Deep-sea Sediments and the In-situ Measurement Techniques. In Proceedings of the 6th ISOPE Ocean Mining Symposium, Changsha, China, 9–13 October 2005; pp. 48–55. [Google Scholar]
  78. Abuhajar, O.; El Naggar, M.H.; Newson, T. Review of Available Methods for Evaluation of Soil Sensitivity for Seismic Design. In Proceedings of the International Conference Recent Advances in Geotechnology, Earthquake Engineering and Soil Dynamics, San Diego, CA, USA, 24–29 May 2010. Paper No. 1.32b. [Google Scholar]
  79. Yamashita, S.; Kawaguchi, T.; Ohshima, H. Design of handy cone penetration tester and its application. Jpn. Geotech. J. 2016, 11, 193–200, (In Japanese with English Abstract). [Google Scholar] [CrossRef] [Green Version]
  80. Yamazaki, T.; Tomishima, Y.; Handa, K.; Saito, T. Studies on Characteristics of Friability of Manganese Nodules and on their Friability in the On-Board Facilities. Shigen; National Research Institute of Resources and Environment: Tsukuba, Japan, 1990; Volume 2, pp. 339–350, (In Japanese with English Abstract). [Google Scholar]
  81. Stanton, P.; Yu, A. Interim Use of API Codes for Design of Dynamic Riser Systems for Deepsea Mining Industry. In Proceedings of the 29th International Conference on Ocean, Offshore and Arctic Engineering, Shanghai, China, 6–11 June 2010. OMAE2010-20189. [Google Scholar]
  82. Ohta, J.; Ysukawa, K.; Machida, S.; Fujinaga, K.; Nakamura, K.; Takaya, Y.; Iijima, K.; Suzuki, K.; Kato, Y. Geological factors responsible for REY-rich mud in the western North Pacific Ocean: Implications from mineralogy and grain size distributions. Geochem. J. 2016, 50, 591–603. [Google Scholar] [CrossRef] [Green Version]
  83. Yasukawa, K.; Kino, S.; Azuma, K.; Tanaka, E.; Miura, K.; Ohta, J.; Fujinaga, K.; Nakamura, K.; Kato, Y. Geochemical features of Fe-Mn micronodules in deep-sea sediments of the western North Pacific Ocean: Potential for co-product metal extraction from REY-rich mud. Ore Geol. Rev. 2020, 127, 103805. [Google Scholar] [CrossRef]
  84. Tanaka, E.; Nakamura, K.; Yasukawa, K.; Miura, K.; Fujinaga, K.; Ohta, J.; Iijima, K.; Nozaki, T.; Machida, S.; Kato, Y. Chemostratigraphy of deep-sea sediments in the western North Pacific Ocean: Implications for genesis of mud highly enriched in rare-earth elements and yttrium. Ore Geol. Rev. 2020, 119, 103392. [Google Scholar] [CrossRef]
  85. Tanaka, E.; Nakamura, K.; Yasukawa, K.; Miura, K.; Fujinaga, K.; Ohta, J.; Iijima, K.; Nozaki, T.; Machida, S.; Kato, Y. Chemostratigraphic Correlations of Deep-Sea Sediments in the Western North Pacific Ocean: A New Constraint on the Distribution of Mud Highly Enriched in Rare-Earth Elements. Minerals 2020, 10, 575. [Google Scholar] [CrossRef]
Figure 1. Sensitivity analyses of net present value (NPV) using FN production rates.
Figure 1. Sensitivity analyses of net present value (NPV) using FN production rates.
Minerals 11 00310 g001
Figure 2. Example geotechnical properties of siliceous deep-sea sediments in shallow layers at Penrhyn Basin, South Pacific, about 5200 m deep [76].
Figure 2. Example geotechnical properties of siliceous deep-sea sediments in shallow layers at Penrhyn Basin, South Pacific, about 5200 m deep [76].
Minerals 11 00310 g002
Figure 3. Example geotechnical properties of siliceous deep-sea sediments from shallow to deep layers in the Japanese FN contract area in the Clarion-Clipperton Fracture Zone (CCZ), North Pacific, about 5200 m deep [77].
Figure 3. Example geotechnical properties of siliceous deep-sea sediments from shallow to deep layers in the Japanese FN contract area in the Clarion-Clipperton Fracture Zone (CCZ), North Pacific, about 5200 m deep [77].
Minerals 11 00310 g003
Figure 4. Daily mining area management for the combined mining of REE-rich mud and FN (not in an accurate scale).
Figure 4. Daily mining area management for the combined mining of REE-rich mud and FN (not in an accurate scale).
Minerals 11 00310 g004
Table 1. Summarization and comparison of earlier economic feasibility studies for ferromanganese nodule (FN) mining [19,20,21,22].
Table 1. Summarization and comparison of earlier economic feasibility studies for ferromanganese nodule (FN) mining [19,20,21,22].
Authors
Processing method
Andrews et al. [19]
Reduction and Hydrochloric Acid Leach Process
Hillman and Gosling [20]
Cuprion Ammoniacal Leach Process
Charles et al. [21]
Reduction and Hydrochloric Acid Leach Process
Søreide et al. [22]
High-Temperature & High-Pressure Sulfuric Acid Leach Process
SubsystemMiningTrans.Process.MiningTrans.Process.MiningTrans.Process.MiningTrans.Process.
(condition)(wet)(dry)(dry)(wet)(dry)(dry)(wet)(dry)(dry)(wet)(dry)(dry)
Production (t/y)2.3 M1.5 M1.5 M4.2 M3.0 M3.0 M2.3 M1.5 M1.5 M1.1 M0.7 M0.7 M
Operation days300 d/y300 d/y330 d/y300 d/y300 d/y330 d/y250 d/y
Capital expenditure (CAPEX)$180M$176M$513M$590M$310M$727M$282M$188M$470M$127M$93M$271M
CAPEX ratio21%20%59%36%19%45%30%20%50%26%19%55%
Equity/Loan100/0 100/0 50/50 30/70
Operating expenditure (OPEX)$45M$25M$165M$77M$37M$111M$48M$36M$156M$21.8M$13.5M$22.9M
Loan interest0% 0% 8%
Survey cost$6M $3M $1.9M
OPEX ratio19%11%70%34%16%50%20%15%65%38%23%39%
MetalPriceRecoveryProductPriceRecoveryProductPriceRecoveryProductPriceRecoveryProduct
Co$5.5/lb85%3375 t/y$8.53/lb65%5070 t/y$6.8/lb85%3525 t/y$20/lb83%2652 t/y
Ni$3.75/lb95%18,525 t/y$3.62/lb92%36,708 t/y$3.6/lb95%19,730 t/y$3.33/lb98%2548 t/y
Cu$1.25/lb95%15,675 t/y$1.17/lb92%28,704 t/y$0.95/lb95%17,810 t/y$1/lb97%1890 t/y
Mn$0.4/lb93%404,550 t/y $0.3/lb93%382,500 t/y
Taxes46% Total 29% 10%
NPV −81M
IRR6.4% 7.4% 12% 9.6%
Table 2. Similarities and differences between rare-earth element-rich mud (REE-rich mud) and FN mining.
Table 2. Similarities and differences between rare-earth element-rich mud (REE-rich mud) and FN mining.
ItemREE-Rich MudFN
Water depth5600–5800 mabout 5000 m
Seafloor excavationHydraulic cut and suctionHydraulic suction
LiftPump hydraulic in riserPump hydraulic in riser
DewateringSettlement and dry-upSeparation and dry-up
Transport2000 km by cargo carrier to Japan’s main land2000–5000 km by cargo carrier to North America
ProcessingAcid leach and solvent separationHydro-metallurgy
Table 3. Estimated capital and operating expenditures (CAPEX and OPEX) under basic conditions.
Table 3. Estimated capital and operating expenditures (CAPEX and OPEX) under basic conditions.
CAPEX ($M)OPEX ($M)
Mining179.780.7
Transportation223.833.7
Leaching (REE-mud)198.3261.9
Brock making155.6226.0
Processing (FN)863.6110.8
Total1621.0713.1
REE-mud: rare-earth element-rich mud; FN: ferromanganese nodule.
Table 4. Element contents in REE-rich mud assumed from Abe et al. [3].
Table 4. Element contents in REE-rich mud assumed from Abe et al. [3].
ElementContent (ppm)
Ce177.9
La154.0
Pr46.2
Nd192.6
Sm44.9
Eu11.1
Gd49.0
Tb7.3
Dy45.4
Y277.2
Table 5. Metal contents in FN assumed from the Japan Agency for Marine-Earth Science and Technology (JAMSTEC) [65].
Table 5. Metal contents in FN assumed from the Japan Agency for Marine-Earth Science and Technology (JAMSTEC) [65].
MetalContent (%)
Ni0.4
Cu0.2
Co0.5
Mn20.0
Table 6. Assumed prices and estimated revenues with their production under the basic conditions.
Table 6. Assumed prices and estimated revenues with their production under the basic conditions.
Element and MetalPrice ($/t)Yearly Revenue ($M)
Ce15,0001.2
La15,0003.8
Pr125,8339.6
Nd83,33326.6
Sm35,0002.6
Eu1,500,00027.6
Gd100,0008.1
Tb1,033,33312.5
Dy508,33338.2
Y56,66626.0
Ni16,12151.8
Cu667811.3
Co34,698155.6
Mn2463354.7
Total 729.6
Table 7. Result of the economic evaluation under basic conditions.
Table 7. Result of the economic evaluation under basic conditions.
NPV ($M)IRR (%)PP (year)
−526.73.6615
Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Share and Cite

MDPI and ACS Style

Yamazaki, T.; Nakatani, N.; Arai, R.; Sekimoto, T.; Katayama, H. Combined Mining and Pulp-Lifting of Ferromanganese Nodules and Rare-Earth Element-Rich Mud around Minamitorishima Island in the Western North Pacific: A Prefeasibility Study. Minerals 2021, 11, 310. https://doi.org/10.3390/min11030310

AMA Style

Yamazaki T, Nakatani N, Arai R, Sekimoto T, Katayama H. Combined Mining and Pulp-Lifting of Ferromanganese Nodules and Rare-Earth Element-Rich Mud around Minamitorishima Island in the Western North Pacific: A Prefeasibility Study. Minerals. 2021; 11(3):310. https://doi.org/10.3390/min11030310

Chicago/Turabian Style

Yamazaki, Tetsuo, Naoki Nakatani, Rei Arai, Tsunehiro Sekimoto, and Hiroyuki Katayama. 2021. "Combined Mining and Pulp-Lifting of Ferromanganese Nodules and Rare-Earth Element-Rich Mud around Minamitorishima Island in the Western North Pacific: A Prefeasibility Study" Minerals 11, no. 3: 310. https://doi.org/10.3390/min11030310

Note that from the first issue of 2016, this journal uses article numbers instead of page numbers. See further details here.

Article Metrics

Back to TopTop