3. Results
3.1. Analysis of the Filtration Rate Efficiency of the System
With regard to the experimental studies on the filtration efficiency of Rockfos
® material at different water circulation speeds in the treatment system, three experimental ponds were filled with water with the physical and chemical specifications presented in
Table 1.
The values of the physical and chemical parameters of well water tested for most parameters did not exceed the FLL standards [
10] for natural bathing ponds (see
Table 1), so it could be used to replenish ponds due to evaporation and for further stages of the experiment.
With regard to the physical and chemical factors of water in the test tanks (P1–P3), it was found that the water temperature varied between 14.2 and 24.3 °C, with an average of 18.56 °C for the test period (average from the water column is 18.04 °C, average from filtered water is 18.58 °C) and was expectedly higher than that in well water (9.8 °C). The minimum value was found in P1 and P3, while the maximum (24.3 °C) was recorded only in P3.
It should be added that the values of this parameter were similar regardless of the water flow rate through the filter. It was found that when measuring the temperature of the water after filtration, the values of this parameter were equal to or sometimes 0.1 °C higher than the temperature of the water taken directly from the pond (
Figure 13).
Oxygen saturation (OS%) ranged from 55.7% (P1) to 97.2% (P2), with an average of 82.89% for the study period (average from water column is 79.16%, average from filtered water is 84.01%) and was higher than in well water (OS = 34.8%)—
Figure 13. Slightly higher values of approx. 4–5% were recorded for P2 with a filtration flow rate of 10 m/h, which was associated with an even distribution of higher values for subsequent test dates and both sampling sites (see
Figure 13).
Lower oxygen saturation values were found either in early spring (P1, range: OS = 55.7–81%) or in late autumn (P3, range: OS = 66–76%), while higher values, regardless of the flow rate through the filter and the sampling site, were found in the summer months (June–September) within the range of 82.2–97.2%. For most of the test dates in the three reservoirs with different filtration flow rates, higher values of this parameter were observed in the filtered water (see
Figure 13).
The pH values were found to be within the following ranges: 7.8 (P1, filtration speed 5 m/h)—9.01 (P1), with an average pH of 8.48 for the entire test period (average pH of the water column = 8.34, average pH of the filtered water = 8.56), which were significantly higher than in well water (pH = 7.34).
The values of this parameter were similar and not very different regardless of the filtration speed and the date of the study. However, higher values were recorded for the filtrate. For both sampling sites, a slightly lower average pH value was recorded for P1 (pH = 8.46) and a slightly higher value for P3, at a filtration rate of 15 m/h (pH = 8.51)—
Figure 13.
With regard to electrolytic conductivity (EC), the values ranged from 155 (P1) to 275 µS/cm (P3), with an average of 204.46 µS/cm for the entire study period (average from water EC = 209.72 µS/cm, average from filtered water EC = 206.51 µS/cm) and were significantly lower than in well water (EC = 334 µS/cm)—see
Figure 13.
The lowest average value of this parameter was recorded for P1 (EC = 185.7 µS/cm), and the highest for P3 (EC = 222.5 µS/cm). Despite the differences between the average values, no regularities in the distribution of EC values were observed in relation to the sampling locations of all reservoirs. Different EC values were recorded both in the water column and in the filter—see
Figure 13.
With regard to seasonal variations, the lowest EC values, regardless of the filtration flow rate and sampling location, were recorded in the spring months (April and May), while the highest values were recorded in the autumn season (September–November).
In the case of total water hardness (TH), the values ranged from 9.9 °dH (P1) to 12.4 °dH (P1), with an average of 10.97 °dH for the entire study period (average from pond water TH = 10.77 °dH, average from filtered water TH = 11.11 °dH) and were higher than for well water (9.9 °dH). The lowest average TH values were found for P3 (10.7 °dH) and the highest for P1 (11.14 °dH)—
Figure 14.
For all test sites, slightly higher values of the tested parameter were observed in filtered water (
Figure 14). In terms of seasonality, elevated values of this parameter were recorded for the summer months (range: 10.8–12.4 °dH), while in spring and autumn, TH values for all sites varied, both for the sites themselves and for the sampling locations.
The N-NO
2 parameter was constant and took identical values for well water, water from the pond, and in the filtrate: 0.02 mg/dm
3—
Figure 14.
For the N-NO
3 parameter, the values ranged from 0.3 to 0.5 mg/dm
3 for all experimental tanks and sampling stations, with an average of 0.38 mg/dm
3 for the entire study period (average from water column N-NO
3 = 0.4 mg/dm
3 and average from filtrate N-NO
3 = 0.37 mg/dm
3) and comparable to the value in well water (N-NO
3 = 0.4 mg/dm
3)—see
Figure 14.
Despite differences in the average values for the sampling sites, no consistent patterns were found in the distribution of this parameter in subsequent tests. In the seasonal distribution, lower N-NO3 values were recorded in summer for P1 and in spring for P2 and P3, while higher values were recorded for P1 in the summer months and for P2 and P3 in the autumn months.
With regard to the Ptotal parameter, the values were limited to 0.021 (P1)—0.260 mg/dm3 (P3), with an average of 0.118 mg/dm3 for the entire test period (average from pond water Ptotal = 0.14 mg/dm3 and average from filtrate Ptotal = 0.098 mg/dm3) and were lower than in well water (0.365 mg/dm3).
The lowest values were recorded for P1 with a flow rate of 5 m/h (average 0.08 mg/dm
3), and the highest for P3 (flow rate 15 m/h, average 0.17 mg/dm
3)—
Figure 14.
For all experimental ponds, lower Ptotal values were found in the filtrate (
Figure 14). In terms of seasonal variation, higher values of this parameter for P1–P3 were expectedly noted in the spring months (higher Ptotal value of the water used to fill the wells) and lower values in the summer months. In the autumn season, lower values were recorded only for P1.
In order to carry out extended tests over a longer period of time covering a full-size natural bathing water body of type II (FSP), it was necessary to determine the appropriate filtration rate. The choice of the rate was based on phosphorus removal efficiency.
The calculations of the relevant statistical measures of phosphorus removal efficiency are shown in
Table 2 and time intervals of phosphorus filtration at the tested velocities in
Figure 15.
The highest average phosphorus retention efficiency was recorded during filtration at a speed of 5 m/h (P1), which was the reason for choosing this speed for extended testing (see
Table 2).
Low phosphorus concentrations in both pond water and filtered water, as well as natural inaccuracies in analytical tests, contributed to high standard deviations, while higher values of the mean compared to the median suggest a right-skewed distribution, i.e., a dominance of high values, which is also confirmed by further analyses of the bed’s adsorption capacity (below).
In order to calculate the phosphorus mass retained by the bed under specific experimental conditions, additional calculations were used, as illustrated in the example below. The results of phosphorus adsorption tests for a mineral filter at a filtration rate of 5 m/h are shown in
Figure 16. The points marked with blue diamond show the phosphorus concentrations in the water taken from the pond, i.e., before the filter, while the orange circles show the concentrations in the water treated by the filter, i.e., fed into the pool. The first component of the calculated total phosphorus mass retained on the filter (
Figure 16) was represented by a triangle with one vertex at point 0.0, one vertex at right angle 1.0, and the third vertex at the ordinate of point 1.
Using the formula for the area of a triangle, the total mass was calculated using the base of a right-angled triangle from 0.0 to 1.0, which represented one day (24 h), and the height of the triangle was 0.22 g P/m3. Since in the first case the filtration speed was 5 m/h for one day, 30 m3 of water was filtered through the filter with a surface area of 0.25 m2. Using these values, the total mass introduced to the filter was 3.30 g P.
Since the phosphorus concentration in the outlet stream was 0.08 g P/m3, using similar reasoning, 1.20 g P flowed out of the filter for one day. It follows that 2.10 g P was retained in the bed.
Analyzing the next interval between point 1 (17 April 2023) and point 2 (12 May 2025), which lasted 25 days, similar calculations were performed but using the formula for the area of a trapezoid. The lengths of the bases of the trapezoid in relation to the outlet stream were 0.22 g P/m3 and 0.12 g P/m3, and in relation to the outlet stream, 0.08 g P/m3 and 0.044 g P/m3. The height of the trapezoid was referenced to 25 days.
The calculations showed that 127.5 g of P entered the bed at that time, 46.5 g of P flowed out, which means that 81 g of P was retained in the bed.
Using the same reasoning for subsequent intervals, the corresponding values of phosphorus retained on the filter were calculated. In order to obtain comparable results (unit masses), the phosphorus masses obtained were divided by the mass of the Rockfos bed®, which has a volume of 0.5 m × 0.5 m × 0.4 m = 0.1 m3 and volume density of 770 kg/m3. Hence, the total mass of the bed was 77 kg.
The unit masses in individual test periods and cumulatively are presented in
Figure 17. Using these calculations for all three filtration speeds, graphs were constructed (
Figure 17) showing the masses of phosphorus absorbed by the beds between individual tests and the cumulative masses over the entire test period.
As can be seen in
Figure 17, initially, as a result of the formation of chemical bonds, larger amounts of phosphorus were retained on each of the beds. During the summer months, with increased biological activity, phosphorus concentrations in the basin were significantly lower, which translated into lower phosphorus concentrations in the effluent stream from the filters, and this in turn resulted in a lower mass of retained phosphorus. At low filtration rates (
Figure 17–P1), this condition persisted until the filter was shut down in the fall. Filters with higher rates (10 m/h and 15 m/h) showed an increase in the amount of phosphorus retained during the fall.
The results of the parameter tests in the three experimental ponds were also subjected to statistical analysis, including correlations between the tested factors. It was also analyzed whether the filter’s impact is statistically significant for the quality of the filtrate.
Due to the lack of data variability, the N-NO
2 and TH factors were not analyzed as they were not technologically justified. The results of the correlation analysis for these parameters of the experimental task are presented in
Figure 18.
A threshold value of ≥0.5 was adopted as a high positive correlation and ≤−0.5 as a high negative correlation. Since the properties of the correlation matrix in the R environment do not allow for any other graphical presentation of the results than that presented in
Figure 18, attention was focused only on the results of the correlation of technologically relevant parameters mentioned in the research methods.
In the case of P1, a high positive correlation was calculated for the Temp. factor in relation to: OS, pH, and N-NO
3. A low negative correlation (−0.17) was found between Temp. and EC, and an elevated negative correlation (−0.32) between Temp. and Ptotal. In turn, an elevated negative correlation (−0.48) was noted between pH and Ptotal. A high negative correlation was noted for the relationship between OS and Ptotal (−0.77), while between the values of the OS and N-NO
3 factors, a very low positive correlation of 0.07 was found (
Figure 18).
For P2, in turn, a very high positive correlation was found between the Temp. factor and OS (0.9). A low positive correlation (0.1) was found between Temp. and EC, and an elevated negative correlation (−0.38) between Temp. and N-NO
3. A very high negative correlation (−0.87) was observed between Temp. and Ptotal. For OS in relation to N-NO
3, the correlation value was negative and elevated (−0.47), and in relation to Ptotal, it was a high negative (−0.76). In the case of the pH and Ptotal relationship, a high negative correlation (−0.68) was determined—
Figure 18.
In P3 analyses, a high positive correlation was found for the Temp. parameter and the factors OS (0.73) and pH (0.51). For the pair Temp. and EC, a low positive correlation (0.17) was found, and for Temp. in relation to N-NO
3 a low negative correlation (−0.19) was found. In the relationship between Temp. and Ptotal, a high negative correlation (−0.85) was determined. In the case of OS and N-NO
3 analyses, there was an increased negative correlation (−0.4), while for the OS and Ptotal pair, there was a high negative correlation (−0.72). A similarly high negative correlation (−0.68) was found for the pH and Ptotal relationship—
Figure 18.
Collectively (P1 + P2 + P3), a high positive correlation was found for Temp. in relation to OS (0.66) and pH (0.53). For the pair Temp. and EC, the correlation was a low positive (0.03), and for Temp. in relation to N-NO
3 a low negative (−0.02). Temp. and Ptotal, in turn, had a high negative correlation (−0.59). OS in relation to N-NO
3 had a reduced negative correlation (−0.23), and OS in comparison with Ptotal had a high negative correlation (−0.54). For the pH and Ptotal pair, an elevated negative correlation (−0.38) was found—
Figure 18.
Before proceeding to the statistical comparative analysis of data before and after pond water filtration, the normality of data distribution was checked for each parameter separately using the Shapiro–Wilk test (with
p-values adjusted for multiple comparisons using the Benjamini–Hochberg procedure). The results, including test statistics and adjusted
p-values for each sampling point, are summarized in
Table 3.
The hypothesis of normality was rejected only for the OS and N-NO3 parameters, indicating a lack of normal distribution in these cases. The remaining variables met the normality assumption.
For normally distributed parameters, a t-test for dependent samples was used, comparing the values of pond water before and after filtration for the three experimental ponds.
For parameters that did not meet the normality assumptions, a non-parametric Wilcoxon rank test for dependent samples was performed. Differences were considered statistically significant at a significance level of 0.05.
Based on the analysis, it was found that statistically significant differences in pond water before and after filtration were found for P1 in the case of the factors: Temp. and TH; and for P2 and P3: EC, Ptotal, and OS (see
Table 4).
In the case of principal component analysis (PCA) of water quality factors, initial assumptions were checked. The overall Kaiser–Meyer–Olkin (KMO) measure of sampling adequacy was 0.71, indicating a moderate level of appropriateness for factor analysis. Individual MSA values were satisfactory for most variables (Temp. = 0.71; pH = 0.78; TH = 0.82; Ptotal = 0.83), while EC (0.31) and N-NO3 (0.41) exhibited low adequacy, suggesting limited usefulness in the PCA model. The variable N-NO2 was excluded from the analysis due to its lack of variability across samples, as all observations contained a constant value (0.02 mg/dm3), rendering it non-informative for PCA. Bartlett’s test of sphericity was statistically significant (χ2 = 115.01; df = 21; p < 0.001), confirming that the correlation matrix is sufficiently different from the identity matrix and justifying the application of PCA.
The results of the PCA are presented in the biplot (
Figure 19). The two principal components—PC1 (50.58%) and PC2 (27.92%)—together explain 78.50% of the total data variability, indicating a good representation of the original variables.
The vectors of the variables (Ptotal, N-NO
3, EC, OS, Temp., pH, TH) indicate the direction and strength of their correlation with the principal components. Longer vectors represent a greater influence of a given variable on sample differentiation, and their orientation relative to the PCA axes helps identify which component they are more strongly associated with (
Figure 19).
Samples are grouped according to location (P1–P3) and filtration stage, allowing for the assessment of similarities and differences between them. Post-filtration samples (marked in yellow) are clearly separated from pond water samples (marked in blue), suggesting that the filtration process significantly affects the physicochemical properties of the water. Separation along PC1 indicates that the main differences between samples arise from parameters strongly associated with this component, such as pH, N-NO
3, TH, and temperature. Additionally, differences between samples from individual ponds are observed, which may reflect local environmental conditions (
Figure 19).
As part of the sanitary analysis of experimental bathing ponds with different filtration rates, microbiological tests were carried out twice during the 2023 season—microscopic tests according to the adopted procedure—which are presented in
Table 5.
Based on the biocenotic analysis of water in experimental ponds P1–P3, with regard to their qualitative aspect, the presence of 40 taxonomic units of pro- and eukaryotic planktonic algae belonging to seven systematic groups was found:
Cyanoprokaryota (cyanobacteria),
Chrysophyceae (golden algae),
Bacillariophyceae (diatoms),
Cryptophyceae (cryptoflagellates),
Dinophyceae (dinoflagellates),
Euglenophyceae (euglenoids), and
Chlorophyta (green algae)—
Table 6.
The taxonomic structure of pro- and eukaryotic algae in individual reservoirs was similar. In the three studied reservoirs (P1–P3), a similar number of taxa was recorded—24 taxa in P1 and P3, and 25 in P2 (
Figure 20). In all reservoirs, green algae dominated, with a predominance of species from the genera
Chlamydomonas,
Monoraphidium, and
Scenedesmus. In reservoir P1, they accounted for 54%, and in P2 and P3, 48% and 58%, respectively (
Figure 21). The share of taxa from the
Cyanoprokaryota group, with a predominance of species from the genus
Chroococcus, was similar in all reservoirs.
Bacillariopyceae, with a predominance of species from the genera
Cyclotella and
Navicula, and
Euglenophyceae, represented mainly by the genus
Euglena. Single taxa occurred from the groups
Chrysophyceae,
Cryptophyceae, and
Dinophyceae (see
Table 5 and
Figure 20 and
Figure 21).
In terms of phytoplankton quality structure, the studied reservoirs showed very low species similarity (
Table 6). The Jaccard similarity coefficient calculated for all reservoirs ranged from S = 0.20 to 0.23, indicating a low species similarity of communities forming in ponds with different filtration circulation speeds of the water treatment system (
Table 7). The lowest similarity was recorded between P1 and P3, and the highest between P1 and P2.
The quantitative structure of phytoplankton in the experimental reservoirs was determined based on abundance and biomass (
Table 6,
Figure 21 and
Figure 22). Both the abundance and biomass of planktonic algae were low. The abundance of phytoplankton varied between the individual reservoirs. The total abundance of phytoplankton ranged from 512,145 individuals/dm
3 in tank P2 to 2,572,336 individuals per dm
3 of water in P3.
Lower abundance at the time of sampling was found in P1 and P2, while the highest abundance was found in P3 (
Figure 22 and
Figure 23). In P1, green algae and cyanobacteria had the largest share in total abundance. In the other two reservoirs (P2 and P3), green algae dominated.
The dominance of Chlorophyta was particularly noticeable in P3, where this group accounted for 84% of the total abundance. The high abundance of green algae in this reservoir was mainly determined by one species—Shroederia setigera (Schröd.) Lemm.
Phytoplankton biomass values in the studied reservoirs also varied (
Table 5,
Figure 24 and
Figure 25). The lowest biomass, 0.22 mg/dm
3 was found in P1, while the highest was in P3—0.8 mg/dm
3. In the three studied reservoirs, green algae had the largest share in the total biomass, although in P1 the dominance of this group was not clear. In this reservoir, they accounted for 28% of the total biomass. In P2 and P3, they accounted for 51% and 62%, respectively. Eugenides were also a group with a significant quantitative share, accounting for over 20% of the biomass in all studied reservoirs.
Chlorophyll a concentrations, as an indirect indicator of phytoplankton productivity, were low and similar in the individual reservoirs studied. The range of average values for this factor was from 2.2 (P1) to 2.9 µg/dm3 (P2 and P3).
Microscopic analyses allowed the identification of 15 zooplankton species belonging to various higher taxonomic units: superorder Cladocera (4 species: 1 species—P1, 2 species—P2, 1 species—P3, mainly from the genus Chydorus sp.); superorder Copepoda (three species, one species in three reservoirs, mainly from the genus Eucyclopsis); Rotifera (four species: two species in P1 and one species in each of the other tanks, mainly from the genus Brachionus sp.) and Rhizopoda (four species: two species in P2 and one species in each of the other tanks, mainly Acanthocystis turfacea).
3.2. Efficiency Analyses of the Prototype Filtration System
Further tests and analyses were carried out to test the efficiency of the prototype water treatment system for a full-scale experimental pond (FSP) under operational load.
After its construction, it was filled with well water from the same source as before, with specifications that mostly corresponded to the standards adopted for natural swimming ponds FLL [
10], see
Table 8.
With regard to the physical and chemical analysis of water in an experimental pond of type II in 2024, it was found that the average water temperature for the entire study period was 16.56 °C, ranging from 9.2 °C (pond water) to 22.0 °C (pond water and filtrate) and was higher than in well water (9.8 °C). The average temperature from the reservoir was 16.36 °C and 16.57 °C in the filtrate (
Figure 26). It was noted that the water temperature after filtration was equal to or slightly higher than the temperature of water taken directly from the pond (
Figure 26). In terms of seasonal variation, the lowest water temperatures were expected in the spring months (March–May) and the highest in the summer months (July–August), regardless of the sampling location. In 2025, the average for the study period was 17.77 °C, ranging from 10.8 °C (pond water) to 22.0 °C (pond water and filtrate). The average temperature of pond water in that year was 17.73 °C, and that of the filtrate was 17.76 °C. In contrast to the previous year, it was noted that the temperature of the filtered water was equal to or slightly lower than the temperature of the water taken directly from the pond (by 0.1 °C). With regard to seasonal distribution (covering only the first half of the year), it was similar to the previous year.
In the case of oxygen saturation (OS) concentration in water, the average for the entire study period in 2024 was 77.1%, ranging from 45.0% (pond water) to 91% (pond water) and was higher than in well water (35.2%). The average OS from the pond was 73.86%, while in the filter it was 76.87%, which, however, did not allow for the identification of consistent patterns in the temporal distribution of results in relation to the sampling location. In terms of seasonality, lower OS values were recorded in spring, the highest in summer, and in autumn these values ranged from 71.0 to 81%. In the following year, the values of this parameter averaged 61.8% for the entire study period, ranging from 48% (pond water) to 81.6% (pond water). The average OS value in pond water was 64.81%, and in filtered water 57.4% (
Figure 26). No regularity in the distribution of OS values was found for the sampling site. In terms of seasonality (first half of the year), the highest values were recorded in April and May. In the remaining months, these values varied between 35.3% and 76.0%.
With regard to pH, the average value of this parameter for the 2024 season was pH = 8.61, ranging from 7.82 (pond water) to 9.2 (filtrate), with an average value for pond water of pH = 8.50 and an average value for filtrate of pH = 8.67, which was higher than in well water (pH = 7.45)—
Figure 26. Higher values were always found for subsequent pH measurements in water after filtration through a mineral bed. In terms of seasonality, the lowest pH values were recorded at the beginning of the spring season (March–May) for both sampling sites, and then these values remained high in the range of pH = 8.48–9.2 in the following months. In 2025, the average pH value was 8.73, ranging from 7.2 (pond water) to 9.73 (filtrate), with an average pH of 8.29 for pond water and 9.12 for water after mineral filtration (
Figure 26). As in the previous year, the pH values for subsequent test dates were higher in the filtered water. In the early spring months, the pH values for both sites were lower, ranging from 7.82 to 8.82. In the following months, the pH of the pond water ranged from pH = 8.16–8.66, and in the case of the filtrate, from the end of April to the end of June, pH > 9.0.
For the EC factor, the average for the 2024 season was EC = 196.64 µS/cm, with a range of 178 µS/cm (filtrate) to 217 µS/cm (filtrate), with an average EC of 198.8 µS/cm for pond water and 196.58 µS/cm for filtered water and was lower than in well water EC = 342 µS/cm (
Figure 26). No regularities were found in the distribution of EC values for different sampling sites—they were varied. In the case of seasonal analysis, the initial higher EC values associated with the specific characteristics of well water fell to EC = 202 µS/cm, and between the end of June and the end of August, they exceeded 200 µS/cm regardless of the sampling site, and then fell to between 188 and 198 µS/cm. In 2025, the average EC value was 175.71 µS/cm, ranging from 114.2 µS/cm (filtered water) to 222 µS/cm (pond water), with an average of 198.58 µS/cm for pond water and 157.9 µS/cm for the filtrate (
Figure 26). The lower EC values were found to be consistent for subsequent test dates in water after filtration with a mineral bed. Seasonally, however, no regularities were found—the results varied regardless of the season.
For the TH parameter, the average value for the 2024 season was 10.22 °dH with a range of 8.0 °dH (pond water) to 12.1 °dH (pond water), with an average of 10.30 °dH for pond water and 10.11 °dH for filtered water and was higher than in well water TH = 9.9 °dH (
Figure 27). No regularity in the distribution of TH values was observed for the sampling sites, either in terms of seasonality or in terms of results.
In 2025, the average TH value was 10.05 °dH, ranging from 8.9 (filtrate) to 11 °dH (pond water), with an average of 10.04 °dH for pond water and 10.05 °dH for filtrate (
Figure 27). Similarly, no regularity was found in the distribution of this parameter in relation to the sampling sites or in terms of seasonality.
The N-NO
2 parameter, as in the previous experimental task, took a constant value for well water, water from the water surface, and water after chamber filtration in subsequent tests: 0.02 mg/dm
3 (
Figure 27).
The N-NO
3 parameter, in turn, took an average value of 0.4 mg/dm
3 in 2024, ranging from 0.3 mg/dm
3 (pond water and filtrate) to 0.5 mg/dm
3 (reservoir), with an average for pond water of 0.4 mg/dm
3 and an average for filtrate of 0.38 mg/dm
3 and was identical to that in well water (
Figure 27).
These values corresponded to those in well water (0.4 mg/dm
3). No regularity was found in relation to the sampling locations—the values varied both between them and seasonally. It should be added that the median for all seasons of the study was 0.4 mg/dm
3 (
Figure 27).
In 2025, the average value of this parameter was 0.39 mg/dm3 ranging from 0.3 mg/dm3 to 0.4 mg/dm3 (pond water and filtrate), with an average of 0.38 mg/dm3 for pond water and an average of 0.4 mg/dm3 for filtrate. The distribution of values was as varied as in the previous year, with no regularity, both for the sampling sites and in terms of seasonality.
For the Ptotal parameter in 2024, the average value was 0.076 mg/dm
3, ranging from 0.017 mg/dm
3 (filtrate) to 0.28 mg/dm
3 (pond water), with an average of 0.091 mg/dm
3 for pond water and 0.069 mg/dm
3 for filtered water, and was lower for well water (0.385 mg/dm
3)—
Figure 27. For subsequent test dates, the regularity distribution of lower Ptotal values for filtered water was found (
Figure 27).
In the case of seasonal distribution from early spring to the end of June, this parameter for pond water gradually decreased in the range of 0.301 mg/dm3 to 0.021 mg/dm3, and in the following months it had more varied values in the range of 0.018 mg/dm3 to 0.1 mg/dm3.
In 2025, Ptotal took an average value of 0.126 mg/dm3, ranging from 0.015 mg/dm3 (filtrate) to 0.308 mg/dm3 (pond water), with an average of 0.182 mg/dm3 for pond water and 0.080 mg/dm3 for filtered water.
As in the previous year, for the subsequent test dates, a lower Ptotal value was found in the filtrate. Seasonal analyses did not reveal any regularities in the distribution of this parameter. In pond water, Ptotal values varied regardless of the sampling date and were always lower in the filtrate.
For a full-size swimming pond with a selected filtration rate of 5 m/h, extended tests were also carried out on the phosphorus adsorption efficiency and bed absorptivity, performed in the same way as for the analysis of the effective filtration rate for the three experimental ponds. The average phosphorus adsorption efficiency in 2024 was 18.28%, while in 2025 it was already 53.98%, with a tendency towards lower values in the summer period. An analysis of the variability of the mass of phosphorus absorbed by the bed (
Figure 26) also confirms that its absorption efficiency decreases during the summer months.
The above observations are confirmed by the very low bar heights between measurements 8 (7 June 2024) and 14 (30 August 2024). A significant decrease can also be observed in 2025, as samples 29 and 30 were taken on 3 June 2025, and 10 June 2025. Significant favorable changes were observed only in the second year of operation (see
Figure 28).
The test results for the analyzed parameters were subjected to statistical analysis. Correlations between the tested factors were examined for two sampling sites: pond water and water after mineral filtration, separately and collectively in 2024–2025 (
Figure 29,
Figure 30 and
Figure 31) for technologically justified parameters (excluding N-NO
2 and TH). A threshold value of ≥0.5 was taken as a high positive correlation and ≤−0.5 as a high negative correlation.
In the case of pond water in 2024, a high positive correlation was found for the Temp. parameter in relation to OS (0.82), pH (0.88), and N-NO
3 (0.77). For the pair Temp. and EC, a low positive correlation (0.01) was found, and for Temp. and Ptotal, a very high negative correlation (−0.91) was found. In the case of the relationship between OS and N-NO
3, a high positive correlation (0.5) was determined, and for OS andPtotal, a very high negative correlation (−0.86) was found. The correlation between pH and Ptotal also took on very high negative values (−0.89)—
Figure 29.
For mineral-filtered water in 2024, a high positive correlation was observed for Temp. compared to OS (0.77) and pH (0.83). For Temp. and N-NO
3, there was an elevated positive correlation (0.41). In the case of the pair Temp. and EC, a low positive correlation (0.03) was found, while for Temp. and Ptotal, a very high negative correlation (−0.88) was found. When analyzing OS and N-NO
3, an elevated positive correlation (0.21) was found, and for OS in relation to Ptotal, a high negative correlation (−0.8) was found. For the pH and Ptotal pair, a very high negative correlation (−0.86) was found—
Figure 29.
In the second season of the study (2025), it should be taken into account that due to the completion date of the research project, it only covered the first half of the year, which probably influenced the final results of the statistical analyses.
In pond water in 2025, an increased positive correlation (0.45) was found for the Temp. factor in relation to OS, similarly to Temp. and pH (0.39). For Temp. in relation to N-NO
3, a low positive correlation (0.01) was determined. A high negative correlation was found for Temp. in relation to EC (−0.53) and Ptotal (−0.55). There was a low positive correlation between OS and N-NO
3 (0.14) and a reduced negative correlation between OS and Ptotal (−0.24). A high negative correlation (−0.77) was recorded for pH and Ptotal—
Figure 30.
For the filtrate in 2025, elevated positive correlations were found for Temp. in relation to pH (0.4) and N-NO
3 (0.21), while high negative correlations were found for Temp. in relation to EC (−0.66) and Ptotal (−0.7) and pH in combination with Ptotal (−0.78). Analysis of Temp. and OS indicated a low, negative correlation (−0.14). In turn, an elevated negative correlation (−0.3) was recorded for OS and N-NO
3 and an elevated positive correlation (0.31) for OS and Ptotal—
Figure 30.
When analyzing the total correlation for both sampling sites and the 2024–2025 study years, a high positive correlation was observed for the Temp. factor in relation to pH (0.52). Elevated positive correlations were observed for Temp. in relation to OS (0.34) and N-NO
3 (0.45) and for the pair OS and N-NO
3 (0.23). A high negative correlation (−0.61) was found for the relationship between Temp. and Ptotal, similar to pH and Ptotal (−0.74) and OS and Ptotal (−0.74)—
Figure 31.
In the statistical analysis of water quality data before and after filtration in the experimental pond, the distribution of variables was assessed using the Shapiro–Wilk test. This test showed that the data on temperature and N-NO3 content did not meet the assumption of normal distribution. The remaining parameters had a distribution close to normal.
For variables with a normal distribution, the t-test for dependent samples was used to compare the values before and after filtration. For parameters that did not meet this assumption, the non-parametric Wilcoxon rank test, appropriate for data with a non-normal distribution, was used. Differences were considered statistically significant at a significance level of 0.05.
Based on the analysis, it was found that statistically significant differences for pond water before and after filtration concerned the following factors: EC, pH, TH, Ptotal, and Temp. (see
Table 9).
4. Discussion
According to information obtained from the Polish Association of Natural Bathing Waters (PSNWK, Poland), approximately 200 private natural bathing ponds have been created in Poland in accordance with the FLL standard [
10]. Only a few others, standardized by this standard, have the status of public bathing ponds, e.g., the one operating in Świętochłowice (MOSIR Skałka), or the character of scenic and recreational ponds, e.g., in Ostrów Mazowiecka—approx. 5000 m
2, in Grodzisk Mazowiecki—approx. 10,000 m
2, or in Zduńska Wola—approx. 10,000 m
2.
Many more similar facilities are being built in Poland, but these are unregistered larger ponds, grandly called natural pools, which do not meet the basic assumptions and recommendations specifying the technical requirements and specifications of materials intended for the construction and operation of natural swimming ponds.
Although these recommendations are not included in the applicable legal standards, they are considered “good practices” and are part of nature-based solutions (NBS) in the field of green construction and are used in many European countries [
2,
13,
29].
For more technologically advanced types of natural pools, one of the recommendations for the functional parameters of filters in their filtration systems according to FLL [
10] standards is an appropriate filtration velocity in filter beds, defined as the ratio of the water flow rate to the filter surface area in plan view, without taking into account the bed. In particular, the effective filtration velocity is analyzed, i.e., the velocity at which water passes through the filter bed and is treated, usually expressed in meters per hour (m/h) or meters per second (m/s). This is a key design and operating parameter in filtration processes, influencing the effectiveness of contaminant removal and allowing the determination of operating parameters related to the length of filtration cycles and the filter rinsing regime [
29,
30,
31].
The effective filtration velocity should be adjusted to the type of contaminants, the type of filter material, its chemical composition, the dimensions of the filter bed, and the functional nature of the tank [
2,
13,
15,
29,
32,
33]. Too high a filtration velocity can lead to contaminants passing through the filter, while too low a velocity can result in excessive loading of the bed. This, in turn, necessitates more frequent backwashing of the bed and its premature clogging, which reduces the utility value of the water reservoir and increases its operating costs.
The FLL guidelines [
10] specify the filtration velocity range in filter beds at 0.8–5 m/h as appropriate for the proper functioning of the filtration system, which was taken as a reference point for studies on the operation of a modular filtration system. The functional efficiency of water filtration velocity in the modular filtration chamber was analyzed experimentally for three model ponds (P1—5 m/h; P2—10 m/h; P3—15 m/h) in relation to the system described in the Materials subsection using the modified rock material verified in numerous empirical studies, e.g., [
15,
27,
34], and for the material of a specific manufacturer (Rockfos
®)—by laboratory column tests [
13]. To analyze the effective filtration velocity, physical and chemical tests, and microbiological and microbiocenotic tests were carried out.
The accuracy of the preliminary analyses was ensured by filling the experimental tanks with water from a well with physical and chemical specifications indicating high utility values, mostly without exceeding the FLL [
10] standards for natural swimming ponds.
It was established that regardless of the filtration speed, higher values in the filtered water were found for the following parameters: temperature, oxygen saturation, pH, and total hardness, while lower values were found for nitrates and total phosphorus. No regularity was found in the distribution of nitrite values (constant value N-NO
2 = 0.02 mg/dm
3). Higher pH values in the filtrate should be associated with the high alkalinity of the Rockfos
® filter material (pH = 11–12, due to the high content of alkaline Ca and Mg compounds) and its tendency to alkalize the water in the post-filtration effluent, as confirmed by earlier laboratory studies by Walczak et al. [
13].
Longer contact of pond water with the filter material at a filtration rate of 5 m/h also resulted in higher pH values for the filtrate compared to higher filtration rates. However, it did not exceed the average limit values according to FLL standards (pH < 9.0). The same was true for other parameters tested. For the same reasons as for pH, higher values for a flow rate of 5 m/h (P1) were recorded for water hardness, which is a function of the concentration of mainly calcium and magnesium cations.
Electrical conductivity (EC), which is an indirect measure of mineralization and water pollution, was lower in the filtrate at the lowest filtration rate. This indicated the filtration potential of the mineral material against other contaminants during prolonged contact with pond water. This confirms the thesis that the degree of adsorbent utilization increases with the duration of water contact with the bed [
13,
35].
The concentration of biogenic nitrogen compounds is related to the dynamics of internal metabolism in aquatic ecosystems—mineralization and bioretention of nutrients [
36]. For nitrate ions (N-NO
3) formed mainly in the process of microbiological nitrification, lower values were found in the filtrate at speeds of 5 m/h and 10 m/h, which may indicate greater filtration capacity of these compounds with longer contact with the bed. However, it should be remembered that in natural swimming pools, the content of nitrogen compounds is mainly regulated by the metabolic activity of the ecosystem through the control of the biocenotic composition of the plants and the microbiology of the pond [
2,
13].
However, the key issue was the analysis of total phosphorus (P), a parameter that influences many other water quality factors and determines the negative consequences of eutrophication [
6,
23,
37]. In the waters of various ecosystems, phosphorus occurs in the form of mineral and organic compounds, in a dissolved state, in the form of insoluble compounds, as well as in the form of suspensions and colloids. Its presence is determined by biocenotic processes in the ecosystem, as well as anthropogenic sources—polluted surface waters, atmospheric precipitation, and excreta, secretions, and cosmetics introduced into the reservoir during bathing [
6,
13,
37,
38].
In the case of P1 (5 m/h), the lowest initial values of total phosphorus concentration in the reservoir water with effective operation of the Rockfos
® bed resulted in the lowest values of this parameter in the filter. However, the measure of filter efficiency is the average phosphorus removal efficiency, which was highest for this filtration rate and amounted to 32.65%. This was a clear indication for selecting this filtration rate for extended experimental studies. This conclusion was not overshadowed by the calculated cumulative phosphorus masses on the beds (bed capacity) for the analyzed filtration speeds. They show that the filter with the highest filtration speed (P3, 15 m/h) had the highest bed capacity. In this case, the water in the pond had the highest initial total phosphorus values, thus confirming the observation from previous laboratory tests [
13] that the adsorption efficiency of the mineral material used is directly proportional to the phosphorus concentration in the tested solution. It is worth noting that for this single parameter, exceedances of the FLL standards [
10] were found, for which the maximum level of Ptotal should not exceed 0.03 mg/dm
3.
Generalizing the assessment of water quality changes in P1–P3, it can be seen that the complex processes occurring in the pools with vegetation and contact with atmospheric air obviously increase the water temperature and oxygenation compared to the same parameters determined in well water. The pH value increased, which is a consequence of the highly alkaline Rockfos® material. A particularly elevated pH occurred in P1, a consequence of the low filtration rate and, consequently, extended contact time with the filter bed. This extended contact time and the specific nature of the Rockfos® material contribute to increased hardness, reduced phosphorus concentration, and lower conductivity. Despite the undoubtedly ongoing biological processes in P1–P3, no changes in nitrogen compounds were observed.
In the experiment to determine the most effective filtration rate, correlations between the physical and chemical parameters of the water were also analyzed. For reasons related to the water treatment technology, only the relationships between the parameters key to this process were analyzed. It was found that under the specific conditions of quasi-natural bathing ponds (P1–P3), the correlations of some factors may differ from those expected and are generally not dependent on the filtration rate. An example is the high positive correlation between temperature and oxygen saturation of water. An increase in temperature usually reduces the solubility of gases in water, including oxygen. However, in ponds with a plant regeneration zone, elevated temperatures increase the intensity of photosynthesis, which has the side effect of releasing oxygen from water photolysis into the environment [
6,
39]. A high positive correlation was also found between temperature and pH. In this case, higher temperatures increase the dissociation of calcium and magnesium ions from the substrate, causing the water in the pond to become more alkaline.
As the temperature increases, the values of electrical conductivity (EC) in water increase. This is due to the fact that higher temperatures increase the mobility of ions in solutions, which in turn facilitates the flow of electricity [
40]. For filtration rates (10 m/h and 15 m/h), a positive correlation between these parameters was expected and found, albeit insignificant. For a filtration rate of 5 m/h, the correlation was slightly negative, which may suggest a higher rate of metabolic changes in the ecosystem related to the bioaccumulation of compounds dissolved in water [
6].
A slightly more problematic issue is the high negative correlation between temperature (Temp.) and total phosphorus concentration (Ptotal). On the one hand, an increase in temperature can lead to an increase in the solubility of various forms of phosphorus (orthophosphates) and accelerate biological and chemical processes, which increases the phosphorus content in water. On the other hand, an increase in temperature may accelerate the metabolic processes of microorganisms involved in its removal. This is, therefore, determined by many complex factors contributing to the functioning of a specific aquatic ecosystem [
6,
39] as well as by the processes taking place in the biological treatment chamber of a water treatment system.
Temperature, although in different ways, has a significant impact on the level of nitrates in water. Increased temperatures can accelerate processes that lead to the formation of nitrates in water, such as the decomposition of organic matter, including increasing the activity of enzymes responsible for nitrification processes (the oxidation of ammonia to nitrites and then to nitrates). Higher temperatures can also promote processes that remove them, such as denitrification (conversion of nitrates to nitrogen gas), which, however, occurs in an anaerobic environment [
41]. For the lowest flow rate (P1, 5 m/h), a high positive correlation was found for temperature and N-NO
3 concentration, which may indicate increased organic matter decomposition. At other filtration flow rates (P2, 10 m/h and P3, 15 m/h), only negative correlations between these parameters were observed, which should be associated with differences in the availability of organic matter, the nature of oxygen conditions, and the composition of microbiocenosis.
The distribution of phosphorus (P) in a water reservoir is generally inversely proportional to the oxygen concentration [
6,
39]. This is confirmed by analyses of the high negative correlation between water oxygen saturation and total phosphorus concentration in the experimental ponds (P1–P3).
During the experiment, a high negative correlation between pH and total phosphorus was also noted. It is assumed that pH affects the forms in which phosphorus occurs in water and its availability to living organisms. For plants, phosphorus in water is mainly available in the form of orthophosphate ions (H
2PO
4− and HPO
42−). These ions are an inorganic form of phosphorus and are most easily absorbed by plant roots. Plants absorb phosphorus most efficiently at a pH of =5.6–7.2, with an optimal pH for this process of around 6.5. Higher pH can lead to the precipitation of phosphates from the solution, while lower pH can increase the solubility and availability of phosphorus, but also increase the toxicity of nitrates and ammonium ions [
42], which can negatively affect aquatic organisms. The reason for the higher pH in the experimental ponds (P1–P3) is obviously due to the alkaline mineral bed (Rockfos
®) used in the water treatment system in the ponds. However, the average values of this parameter did not exceed the FLL limits [
10] and the baseline limits for a well-functioning pond ecosystem: pH = 7.5–8.5 [
43].
For a filtration flow rate of 5 m/h (P1), a positive correlation between oxygen concentration (OS) and nitrate concentration N-NO
3 was expectedly noted, though it was insignificant. Under aerobic conditions, nitrifying bacteria convert ammonia into nitrites and then into nitrates. The higher the oxygen concentration, the more effective this process is. Under anaerobic conditions, nitrates can be reduced to molecular nitrogen, which escapes into the atmosphere [
40]. At higher filtration flow rates (10 m/h and 15 m/h), nitrification processes were not sufficiently intense, which resulted in increased negative correlations in statistical calculations. The negative correlation between OS and Ptotal in water results from the release of phosphorus into the water in the form of soluble orthophosphates, which, under conditions of high oxygen concentrations, accumulate as polyphosphates and organic phosphorus. A decrease in oxygen concentration in the bottom zone of the reservoir causes anaerobic decomposition of sediments, algae, and other organisms, converting phosphorus compounds into simple phosphates that dissolve in water, consequently increasing its concentration in the water.
The water flow rates through the treatment system influenced the statistical analysis of the parameters in the water before and after mineral filtration. For the t-test (for normally distributed data) and for the Wilcoxon rank test (for variables that did not meet this assumption) at a significance level of 0.05, statistically significant differences were found for different parameters for different experimental ponds: P1 (5 m/h): Temp., TH; P2 (10 m/h): EC, Ptotal and OS (O2); and for P3 (15 m/h): EC, TH, Ptotal, N-NO3. It was observed that with an increase in the filtration circulation speed in the ponds, the number of factors whose values in the water before and after filtration showed statistically significant differences increased. Similar observations can be made in the case of principal component analysis (PCA) of the studied factors. It was found that the filtration process significantly affects the physicochemical properties of water. Perhaps the biophysical and chemical conditions in the pond waters with varying filtration flow rates created a diverse, multi-factor background for the course and intensity of internal metabolic processes in the studied reservoirs.
The elements determining the conditions for the course of metabolic processes in the experimental reservoirs were certainly their bacteriocenoses and the developing biocenotic composition of phyto- and zooplankton.
The presence of human and animal pathogens, both fecal and non-fecal pathogenic microorganisms, poses a health risk to bathing water users [
2,
44,
45]. It also impairs the metabolic activity of the biocoenosis of the reservoir [
6]. The mechanism of natural sanitary water treatment is related to the function of the pond’s regeneration zone, which acts as Treated Wetlands (TWs). Here, biogenic substances and toxic compounds are bioaccumulated by repository plants forming a phyto-geochemical barrier [
2,
23,
28]. The root zone of repository macrophytes is an element of phytoremediation (rhizofiltration, phytoextraction, and phytostabilization). Thanks to the root phytoncides secreted, with the participation of a developing biofilm from appropriate bacterial cultures, it accelerates the mineralization of organic compounds and participates in the natural process of water disinfection. This affects the species composition of the reservoir’s bacteriocenosis, determining its sanitary conditions [
2,
46,
47,
48,
49].
For the analyzed flow rates, the data obtained for the number of coliform bacteria, the number of Escherichia coli bacteria, and the number of fecal enterococci were lowest at lower filtration rates (5 m/h and 10 m/h). This may result from the dynamics of water circulation, which at higher speeds causes greater leaching of the biofilm from the root zone of re-growing plants and is not conducive to the concentration of sanitizing root exudates, which reduces the natural disinfecting properties of the TWs system. Despite the lack of standards for the occurrence of fecal pathogens in natural swimming ponds, their abundance in relation to the nature of use of the tested water bodies should be considered harmless at all filtration speeds.
A properly functioning water reservoir ecosystem is associated with properly progressing ecological succession, which is most important for the functional parameters of the natural pool on a micro scale. The aim of such micro-succession is to achieve a biocenotic balance between phytoplankton (algae and cyanobacteria) and feeding on zooplankton (mainly crustaceans), based on functioning trophic networks [
2,
6,
39]. Phytoplankton itself develops thanks to the availability of water-soluble orthophosphates, and its mass appearance (bloom) affects the growth of primary production in the reservoir. The amount of synergistic toxins secreted by phytoplankton also increases, which often leads to intoxication of the water reservoir, determining changes in water quality parameters [
6,
13,
23].
Qualitative and quantitative analyses of pro- and eukaryotic planktonic algae in ponds with different filtration rates indicated typical early stages of succession, although not identical in nature. This could indicate the influence of filtration rate on the formation of biotope conditions for the developing phytoplankton biocenosis. The species similarity of phytoplankton for the three ponds with different filtration rates was low, reaching only 0.23 (Jaccard coefficient) on a scale of 0.0 to 1.0. However, the taxonomic structure for these reservoirs was not very diverse, with only 24–25 species recorded for each reservoir. In all reservoirs, although in varying proportions, green algae (
Chlorophyta) were the most abundant, with a predominance of unicellular or cenobitic species of the genera
Chlamydomonas,
Monoraphidium, and
Scenedesmus. Low biogenic phosphorus values in the tested reservoirs, combined with competition for nutrients with macrophytes in the regeneration zone, were not conducive to the appearance of filamentous green algae (e.g., from the
Cladophora,
Spirogyra, or
Zygnema families), which are problematic for maintaining biocenotic balance [
6,
50] and, consequently, the recreational use of ponds. The share of taxa include those from the cyanobacteria (
Cyanoprokaryota) and diatom (
Bacillariopyceae) groups, as well as those represented mainly by single taxa of euglenines (
Euglenophyceae), golden algae (
Chrysophyceae), cryptophytes (
Cryptophyceae), and dinoflagellates (
Dinophyceae). Both the abundance of biocenotic groups and their biomass, in terms of numbers and percentages, showed the lowest values for ponds with lower filtration flow rates (5 m/h and 10 m/h). This is particularly important when analyzing the presence of cyanobacterial species, whose mass appearance and ability to release cyanotoxins (dermatotoxins, hepatotoxins, or neurotoxins) can lead to water body poisoning, which is problematic both for the water body ecosystem itself [
6,
49,
50,
51] as well as its users [
13].
Low numbers and biomass of planktonic algae determined low concentrations of chlorophyll a, as an indirect indicator of their productivity, with the lowest value (2.2 µg/dm
3) recorded for P1 with a filtration flow rate of 5 m/h. Despite this fact, according to the nomenclature based on trophic status [
50], this and other tested ponds should be classified as oligotrophic.
Freshwater zooplankton is more biologically diverse than phytoplankton, so its detailed analysis requires specialist knowledge. It comprises many taxonomic groups, such as protozoa, rotifers, coelenterates, cnidarians, annelids, arthropods, larval stages of molluscs, and echinoderms, as well as simple forms of vertebrates and fish eggs and fish juvenile stages. However, freshwater zooplankton is typically composed of heterotrophic protozoa, rotifers, and crustaceans [
6,
50].
Limited by their scope, preliminary analyses of zooplankton also indicated the early stages of succession of this zoocoenosis. A small number (15) of typical species characteristic of the main systematic groups were found: cladocerans (
Cladocera); copepods (
Copepoda); rotifers (
Rotifera); and rhizopods (
Rhizopoda) with a similar biocenotic structure. The filtration circulation speed in the ponds, therefore, had no influence on its formation. In all tested reservoirs, only small forms of filter feeders dominated, mainly cladocerans (from the
Chydorus family) capable of filtering the smallest food particles (e.g., single-celled algae) from the environment. It is worth noting that among planktonic filter feeders, especially rotifers, there is a general rule known as the Size Efficiency Hypothesis [
52]. It is based on the fact that both small and large filter feeders (e.g.,
Daphnia magna) compete for small food, but only the large ones are able to consume larger food. When small food becomes scarce, larger filter feeders fare better in such conditions—they are able to tolerate lower densities of filtered food than smaller filter feeders. This perspective is changed by the presence of large filamentous algae (green algae or cyanobacteria) in the reservoir. They clog the filtering apparatus of large planktonic filter feeders, but due to their size, they do not limit the ability of smaller filter feeders to obtain food [
6,
52]. For the self-regulation of the ecological system of pond water, the presence of smaller forms of filter-feeding zooplankton, therefore, seems to be a more adaptive solution. It is worth noting that the mere presence of zooplankton, regardless of its taxonomic composition, does not always reduce the amount of phytoplankton. This takes into account, for example, the possibility of low consumption stimulating phytoplankton growth, or the growth of inedible phytoplankton forms due to selective feeding on edible forms. The processes of regulating biocenotic relationships are, therefore, difficult to implement and depend on many different biotic and abiotic factors in the aquatic environment [
6,
39,
50].
A summary of the above issues:
High effective filtration efficiency for phosphorus (32.65%).
No exceedances of FLL standards [
10] for most water quality parameters in the pond at its operational load.
Lower number of problematic fecal pathogens (on average 393—coliform bacteria; 74—Escherichia coli; 34—fecal enterococci, MPN/100 mL).
Correct phytoplankton succession with the lowest share of cyanobacteria threatening toxin formation in the reservoir (both in terms of abundance and biomass).
Oligotrophic nature of the reservoir confirmed by the lowest chlorophyll a concentrations.
The presence of a properly developing zooplankton biocenotic structure, with the participation of its smaller forms, in combination with the analysis of conversion and statistical results, provided a sufficient basis for accepting the extended filtration rate of 5 m/h for rapid filters for the study.
This choice of a 5 m/h filtration rate is also supported by preliminary economic analyses. The purchase cost of a pump for a flow rate of 15 m/h is 100% higher than for a rate of 5 m/h. The energy cost of maintaining a modular water filtration system at a flow rate of 5 m/h for a pond of approximately 100 m2 is approximately €65/year (a circulating pump with a power rating based on a 50 W pump operating 24 h a day for 300 days a year), and €195/year for a filtration rate of 15 m/h. The latter scenario assumes a higher frequency of cleaning and reactive material replacement due to faster bed clogging, which also increases the system’s operating costs.
Extended field experiments concerned the functioning of an innovative water treatment system using a prototype modular filter chamber. It was designed according to functional assumptions [
2] as a dedicated technological solution mainly for natural swimming ponds.
Both the design and the prototype of the filter chamber were implemented according to the co-authors’ guidelines by a competent technology company and analyzed in terms of functionality, mechanical loads, and safety of use. It therefore meets the basic requirements for modularity and multiplicity (compatibility of multidirectional system connections), durability and lightness of construction (HDPE plastic), functionality in relation to various types and sizes of swimming ponds, the possibility of independent assembly and equipping the system with dedicated accessories, as well as service and maintenance facilities, allowing individual chambers to be disconnected without immobilizing the entire system.
The latter improvement is related to the use of valve control, which, in the context of the filtration system dedicated to the natural pool, is the subject of a patent application described in the first part of this paper.
The lack of such a solution is a fundamental drawback of current technological solutions for water treatment in ponds, as it does not allow for selective filtration during the functional rest of any of the filtration cartridges. System maintenance involves closing the water circulation loop, which has a negative impact on the operational efficiency of the entire system [
2].
Therefore, the filtration efficiency of the prototype water treatment system described in the Materials section was tested for a full-size natural swimming pond type II (FSP).
The study found that regardless of the sampling location, most of the average values of the parameters tested (with the exception of Ptotal) did not exceed the standards for natural bathing ponds set by FLL [
10]. The filtration processes in both study seasons did not have a significant impact on the values of Temp. and N-NO
2 ion concentrations (constant value in pond water and in the N-NO
2 filter = 0.02 mg/dm
3). Higher values were obtained in the filtrate for the pH value and lower values for the other tested parameters (OS, EC, TH, N-NO
3, and Ptotal).
As expected, the highly alkaline nature of Rockfos
® caused alkalization processes in the pond water. Seasonal fluctuations in pH in the pond water were also noted for both study seasons. These are related to the specific environmental conditions associated with the succession of seasons: changes in temperature, precipitation, and biological activity, including the intensity of photosynthesis affecting the assimilation of CO
2 from the aquatic environment [
6,
52].
For the electrolytic conductivity (EC) factor, of which values are a measure of the dissociation of various compounds dissolved in water, it was found that this parameter was characterized by variability regardless of the sampling date. This fact confirms the observed regularity of lower EC values in the filtrate water for subsequent sampling dates. The decrease in EC in pond water was due to the inflow of rainwater, which is naturally low in mineralization, but it could also indicate that the Rockfos® mineral material used gained greater filtration efficiency during the subsequent period of its operation and that the ecosystem of the reservoir was metabolically active.
Another parameter dependent on many environmental factors, including those related to the seasons, is oxygen saturation (OS). Its values in the filter were lower, probably due to the predominance of heterotrophic succession in the biological filter, with respiration prevailing over production (photosynthesis). Higher values of this parameter in pond water may also result from aeration of the reservoir during bathing. Water circulation and mixing promote the dissolution of oxygen in water, enabling gas exchange between water and the atmosphere, thus increasing the concentration of dissolved oxygen in water [
6,
49]. Higher oxygen concentrations in water were recorded in colder months, confirming the rule that the solubility of gases in liquids, including oxygen in water, is inversely proportional to temperature [
53,
54].
Water hardness (TH), which is a function of the concentration of calcium, magnesium, and sodium cations, took values significantly lower than the FLL standard [
10] for natural pools TH > 30 °dH (10.7 mval/L) during the field experiment. It was above the values specified for well water (pond filling) in both the pond water and in the filter, but as a rule, it was lower in the filter than in the pond water. Despite the possibility of Ca and Mg ions being released from the deposit, its high alkalinity could cause calcium and magnesium carbonates to precipitate at elevated pH values, reducing the level of these elements in the filter [
49]. The lack of consistent patterns in the distribution of this parameter in relation to sampling sites and in seasonal terms can be linked to varying intensities of biological processes, which, on the one hand, concern the biocenotic bioaccumulation of these elements and, on the other hand, concern their release during the decomposition of dead organic matter [
6].
For nitrate ions (N-NO3) formed mainly from ammonium ions by nitrites in the process of microbiological nitrification, the adsorption reactivity of the filtration system was low (0.3 to 0.5 mg/dm3, corresponding to those in well water 0.4 mg/dm3). Their quantity is regulated by the internal metabolism of the reservoir, with the participation of repository macrophytes and the microbiocenotic structure of the pond (bioaccumulation, decomposition of organic matter, and nitrification).
For the proper functioning of natural bathing water bodies, it is necessary to control the phosphorus content, which is a key biogenic element determining other water quality parameters. For both seasons of the study, lower Ptotal values were found compared to well water, and the correct distribution of lower Ptotal values was found for filtered water, although with varying intensity. The average Ptotal values in the 2024 and 2025 seasons exceeded the FLL standards for eco-basins (Ptotal < 0.03 mg/dm
3). However, the average effective efficiency value showed a progressive increase in phosphorus adsorption from season to season, reaching 53.98% in 2025. This confirmed the observation that for highly efficient filter materials, phosphorus removal efficiency increases with bed break-in [
55]. An analysis of the bed’s absorptivity indicates that for both study seasons, its absorption efficiency decreases during the summer months, which is due to the intensity of seasonal biological processes. A notable issue is the exceeding of FLL standards [
10] for the amount of Ptotal in FSP water. However, the practice of constructing, operating, and maintaining natural swimming ponds shows that full operational efficiency based on the development of environmental homeostasis in a living pond ecosystem and the appropriate selection of a treatment system and filtration parameters is only achieved after several years of operation. Based on the tests carried out, it can only be concluded that the tested water filtration system has progressive adsorption capabilities, which in the case of this study should be assessed positively.
The analysis of correlations between the physical and chemical factors of water at the sampling sites and in subsequent seasons showed similar high positive and negative correlations as in the case of testing the effective filtration rate. In particular, in the 2024 season, the previously analyzed high positive correlations were found between the temperature (Temp.) and the factors, OS, pH, and N-NO3, as well as high negative correlations between Temp. and Ptotal and for pH and Ptotal. Same as before, a high negative correlation was also found for OS and Ptotal. For the pair OS and N-NO3, on the other hand, only positive correlations were found, as in the tested ponds (P1–P3), indicating that the intensity of the microbiological nitrification process is directly proportional to the amount of dissolved oxygen in the water. Greater variation in the values and nature of the correlations was observed in the second season of the study (2025), particularly in the filtrate. Its analysis should, therefore, be considered incomplete, covering only the first half of the pond’s operating season; hence, there is no justification for drawing competent conclusions.
Testing statistically significant differences in water parameters before and after filtration using the t-test and Wilcoxon rank test allowed us to conclude that, in addition to the factors showing such differences in the previous experiment (EC, Ptotal, and TH), there is one more factor—pH. The nature of these relationships may be determined by the specific biocenotic interactions in the pond and the specifications of the filtration system used. In this case, for example, the efficiency of mechanical pollutant removal by a dedicated filter and the operation of a surface skimmer, the metabolic activity of the biological chamber, or the alkaline nature of the Rockfos® filter mineral.
A key issue for the commercialization of the presented technological solution is the investment cost, as well as the operating and maintenance costs of the water treatment system. Financial analyses indicate that the investment cost of a modular filtration system for a natural swimming pond with an area of approximately 100 m2 is approximately €7500, compared to €10,000–12,000 for other technological solutions currently available in the market. In the case of the presented system, the mechanical and biological filters have approximately 25% larger surface areas, and the mineral filter has approximately 35–40% larger capacity compared to existing market solutions. Operating and maintenance costs for all technological solutions are similar. The energy cost to maintain the modular water filtration system at a flow rate of 5 m/h for a pond with an area of approximately 100 m2 is approximately €65/year, while the maintenance cost—cleaning the mechanical and biological filters—is approximately €200/year (mechanical cleaning and possible replacement of the biological filter fabric). The use of the proposed water filtration system is, therefore, characterized by a 25% lower investment amount and shows potentially higher efficiency after the bed has been worked out and a similar cost of using and servicing the system in relation to other market systems.
The summary of the above analysis allows us to conclude that the prototype water treatment system with a modular mineral filtration chamber filled with the tested Rockfos® mineral, in a full-size pond of the second type (FSP), at a circulation rate of 5 m/h, demonstrates high functional efficiency under full operating conditions.