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17 August 2025

Optimization of a Compact Corona Discharge Ozone Generator for Emergency Water Treatment in Brazil

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Department of Chemical Engineering, Federal University of Rio Grande do Sul, Ramiro Barcelos Street, 2777, Porto Alegre 90035-007, RS, Brazil
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This article belongs to the Special Issue Advances in the Treatment of Refractory Organic Wastewater

Abstract

The growing demand for effective water treatment solutions, particularly in smaller communities in Brazil, highlights the potential of ozonation. However, implementing this technology at a smaller scale presents challenges, including the need to adapt it for compact systems and optimize processes for both efficiency and feasibility. This study investigates the use of a corona discharge ozone generator operating at 60 Hz in compact systems. Experiments evaluated ozone production at different gas flow rates (0.2 to 1.0 L of ozone-containing gas per minute), with the total flow divided between two lines, A (60%) and C (40%), for simultaneous treatment applications. Mass balance tests were performed using caffeine (CAF) and atenolol (ATL) as model compounds to assess molecular interactions. The results highlight the need to stabilize ozone generation to ensure consistent production and process efficiency, confirming ozone’s effectiveness in degrading emerging compounds (ECs), CAF and ATL, by approximately 80%, after process optimization using the compact ozonation unit. Key factors such as the position and diameter of the flow divider, diffuser type, and pollutant characteristics were shown to affect gas distribution, head loss, and ozone transfer efficiency. Thus, this work underscores the critical role of system configuration in optimizing ozonation, offering insights to enhance its feasibility for providing safe potable water during water crises and emergencies in Brazil.

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