1. Introduction
Coal accounts for a large proportion of the primary energy production and consumption structure, with an important role in driving economic development [
1,
2]. In recent years, coal mine accidents have declined, but many coal mines are still plagued by gas, dust, and toxic and harmful substances. With the deepening of coal mine mechanization, mining scale, and mining depth in China, the amount of dust produced during the operation has increased dramatically. In addition, the increased dumping of gas and toxic and harmful gases in the coal seam has led to a harsh environment for underground coal mine operations. In order to create a favorable working environment for underground mining, there is an urgent need to accurately evaluate the air quality in underground coal mines.
Gas is a common substance in coal mines. Its main component is CH
4, which usually accounts for more than 90%, followed by ethane and carbon dioxide. In different coal seams or mines, the composition and content of gas vary, with significant differences in some cases [
3]. During the coal mining process, the broken coal releases gas, increasing the gas concentration in the coal mine. The gas concentration is expected to increase continuously as the depth of coal mining increases [
4,
5,
6]. The increase in gas concentration can dilute the O
2 concentration. When the concentration exceeds 40%, death can occur due to hypoxia and suffocation. Therefore, it is necessary to introduce gas into the evaluation model of underground air quality in coal mines.
The dust produced during coal mining seriously affects the underground air quality and the safety of coal production. At present, the development of coal mine dust prevention and control and occupational safety and health in China is still in its infancy, and it is difficult to adapt the current technology and equipment to the complex and changeable working conditions of coal mines [
7,
8,
9]. The high dust concentration in coal mines increases the probability of workers suffering from pneumoconiosis and reduces the service life of equipment in coal mines [
10,
11,
12]. Therefore, dust concentration is an important indicator for the evaluation of air quality in coal mines. In addition, the underground air of coal mines contains a large amount of toxic and harmful gases (such as CO, H
2S, SO
2, NO, NO
2) during the coal mining process. These toxic and harmful gases threaten the health of underground workers and are the main evaluation indicators in most air quality evaluations [
13,
14,
15,
16].
SO
2, NO
x, CO, TSP (total suspended particulates), and gas jointly affect the air quality in coal mines. In addition to strengthening mine ventilation and diluting harmful gases and fumes, it is necessary to monitor toxic and harmful substances in real time and evaluate air quality, thus ensuring that the air quality under the coal mine meets the safety requirements. At present, there are many evaluation methods for ambient air quality, such as matter-element analysis, fuzzy comprehensive evaluation, the analytic hierarchy process, the pollution loss rate method, and the gray system theory method [
17,
18]. Compared with the atmosphere, the underground air in coal mines has special characteristics, with a higher concentration of gas and combustibles. However, most scholars tend to ignore the evaluation of air quality in underground coal mines by only evaluating and predicting atmospheric air quality. For example, Chen et al. [
19] evaluated the ambient air quality of a site based on the matter-element analysis method. The feasibility and rationality of this method in air quality evaluation were confirmed. Lv et al. [
20] evaluated the air quality in the Beijing–Tianjin–Hebei region using the fuzzy comprehensive evaluation method and established a comprehensive rating factor set. Based on the ambient air quality standard, they supplemented the ambient air quality standard evaluation set, obtained the air quality evaluation level, and listed the most important pollution factors for each city. Li et al. [
21] used the evaluation factor as the criterion layer based on the AHP and added the observation station as the sub-criteria layer for the first time. A hierarchical structure model was constructed to assess the air quality in Shandong Province for 12 months. Based on gray theory, Meng et al. [
22] used the gray clustering method, gray relational degree method, and gray situation decision-making method to evaluate the air quality of Jiamusi City, Heilongjiang Province. However, the evaluation results for the same sample were significantly different. After improving the weighting method and air quality classification principle, the final results were more consistent and had higher discrimination.
Compared with the evaluations of atmospheric air quality, fewer evaluations have been conducted on the air quality in underground mining areas. Only a few scholars have applied these methods to evaluate the air quality in underground mines, while a few of them evaluate the air quality in coal mines. The evaluation of underground air quality is primarily to ensure that the concentrations of harmful gas and dust do not exceed their maximum allowable concentrations. For example, Liu et al. [
23] used the matter-element theory to establish a matter-element model to evaluate the underground air quality in metal mines. The classic domain matrix, node domain matrix, and weights were determined, and the evaluation levels were finally obtained, providing a new method for underground air quality evaluation. Despite the simplicity and standardization of this method, it often leads to low discrimination of multiple influencing factors. Yang et al. [
24] established the factor set, comment set, evaluation matrix of each factor, and the weight of each layer using the fuzzy comprehensive evaluation method from the four aspects of water environment, atmospheric environment, ecological environment, and geological disasters. These results were applied to the environmental assessment of the western mines. However, the fuzzy comprehensive evaluation method has many influencing factors, and the relationship between each factor and the safety level is relatively vague. Shi et al. [
18] used the pollution loss rate method and the principle of the exponential relationship between pollutants’ concentrations and their effects on air quality to evaluate the air quality in metal mines. This method is simple and intuitive, but the synergistic effect between evaluation indicators is neglected. Du et al. [
25] established a comprehensive evaluation model of the coal mine environment based on generalized linear theory and the fuzzy analytic hierarchy process. The importance of each index factor was obtained by analyzing air, water, soil, and ecological compensation indicators using generalized linear theory. Afterward, the logarithmic fuzzy preference programming method was used to construct a comparison matrix to obtain weight values. The results also showed that this model overcomes the shortcomings of manual weighting. Although this method can effectively reveal the relationship between various factors, it is not convincing because of the low quantitative data and high qualitative components. Jiao [
26] developed an evaluation model for the environmental quality of mining areas using gray cluster analysis. A triangular whitening weight function was constructed to calculate the gray membership degree of measured values, and the degree of different pollution factors was obtained through the threshold inverse method. Then, the sampled data were evaluated by gray clustering. Finally, the evaluation results were consistent with the actual survey results. Despite the convenience and practicality of the gray theory model, its theoretical system is not perfect and its scope of application is small. Ye et al. [
27] used the generalized contrastive weighted comprehensive scale index method to evaluate the underground air quality of uranium mines. However, due to the long time interval, the reference standard became invalid for a long time. It is no longer applicable to the current evaluation of mine air quality.
The evaluation methods above only consider the impact of harmful gases on air quality. In addition, gas cannot be ignored in evaluating underground air quality in coal mines. Gas is a common toxic and harmful substance in underground mines, which always affects the air quality in coal mines. In order to avoid the shortcomings of the above methods, a relatively comprehensive evaluation method is needed to evaluate the air quality of underground coal mines.
In this study, gas was determined as an evaluation indicator for underground air quality in coal mines. Based on the generalized contrastive weighted comprehensive scale index method, an optimization model for evaluating the air quality of coal mine was established. In this model, the weight value is obtained using the generalized contrast weighted method, and then the comprehensive scale index is derived. Finally, the air quality classification standard for coal mines is identified. The air quality evaluation was carried out on a coal mine underground tunneling working face in Shaanxi, and the validity and generality of the model were confirmed.
2. Evaluation Model of the Generalized Contrastive Weighted Comprehensive Scale Index
To date, various comprehensive index equations expressing environmental quality have been proposed. These calculation equations have their specific characteristics. Their purpose is to reflect the degree of environmental pollution resulting from the comprehensive action of various pollutants. Accordingly, appropriate methods are adopted to synthesize the sub-indices of pollutants.
Based on the Weber-Fisher Law, the principle of equal ratio assignment of harmful atmospheric concentrations and equal difference classification of hazard degrees is proposed. The harm level of the
I-th pollutant is usually expressed as a sub-index:
where
Cix is the measured concentration of the
i-th pollutant; and
Sij is the
j-th standard concentration limit for the
i-th pollutant. From the above equation, it can be concluded that a change in sub-index Δ
Ii and concentration changes Δ
Cix exhibit a linear relationship. Research has pointed out that within the range of the background concentration limit
Ci0 to the obvious hazard concentration limit
Cid, when the concentration of pollutants changes proportionally, the subjective differential response of people to the stimulation of pollutants changes equivalently, and this differential change should be used as the basis for the change in the degree of harm caused by pollutants.
Then, the evaluation model of the generalized contrastive weighted comprehensive scale index is proposed based on the principle. This method quantifies the damage of a single harmful substance through the scale sub-index. Then, the factor weighting method of the generalized contrast algorithm is used to calculate the scale sub-index, and the generalized contrastive weighted comprehensive scale index of air quality is derived. In recent years, such methods have been gradually popularized and applied in air quality assessment.
The generalized contrastive weighted comprehensive scaling index model is characterized by the fact that the pollutant concentration changes proportionally and the degree of harm to the environment changes equivalently, which is scientific and reasonable. When using the generalized contrastive weighted method to determine the weight, the influence of the scaling index on the weight (including enhancement and weakening) can be adjusted by selecting different adjustable parameters p, making it reasonable and flexible. The scale sub-index equation and the generalized contrastive weighted calculation equation are simple and standardized, with the evaluation method being comparable and universal. Therefore, this paper applies the model to the air quality evaluation of coal mines based on the introduction of gas.
2.1. Determination of Evaluation Indicators
The air in coal mines contains a large number of toxic and harmful substances such as NO
x, SO
2, CO, TSP, and gas. NO
x, especially NO
2, is highly toxic and causes strong irritation to human eyes and respiratory organs. It mainly comes from blasting operations and fuel equipment operations. SO
2 has a strong smell. Its contact with respiratory organs and moist skin produces sulfuric acid, which irritates and paralyzes respiratory organs, causing lung and bronchial inflammation. It mainly comes from the oxidation of sulfur-containing coal, spontaneous combustion of coal, and blasting of sulfur-containing coal seams. CO is colorless, odorless, and highly toxic. When the CO content reaches 0.4%, it causes death in a short period of time. When it is 13–75%, an explosion can occur in the case of fire. It mainly comes from natural coal oxidation, blasting operations, and fuel oil equipment operations. It is mostly present in the middle and upper parts of the roadway [
28,
29,
30]. TSP stands for total suspended particles. Particles smaller than 100 μm can enter the lungs, damaging alveoli and mucous membranes, and causing diseases such as pulmonary heart disease. It mainly comes from underground mining operations, transport reloading, and ventilation dust. Gas is colorless, odorless, non-toxic, and flammable. When the gas concentration reaches 5–16%, an explosion may occur when the gas is exposed to an open flame. When the gas concentration in coal mines rises, the oxygen concentration decreases, leading to suffocation of workers. The gas is mainly released from coal and rock. Based on the above analysis, SO
2, NO
x, CO, TSP, and gas are introduced into the model as evaluation indicators.
2.2. Establishment of Evaluation Model
2.2.1. Calculation of Scale Sub-Index
The main measure of environmental quality is the degree of harm caused by air pollutants. The change in the concentration of harmful substances in coal mines is equally proportional, and the change in harm degree is equally variable. The index reflecting this change is defined as the scale sub-index. It is represented by
Kj and calculated as follows [
31]:
where
Cjk is the measured concentration value of harmful substance
j;
Cj0 is the background concentration value of harmful substance
j; and
aj is the importance ratio of two adjacent levels of harmful substance
j,
aj = (
Cjd/Cj0)
1/9, where
Cjd is the obvious hazardous concentration of harmful substance
j.
The corresponding results in Equation (2) are normalized, and the equation for the normalized scale sub-index
Ij is obtained [
31]:
According to the “Ambient Air Quality Standard” [
32] and the “Coal Mine Safety Regulations” [
33], and the background concentration limits (
Cj0) and obvious hazardous concentration limits (
Cjd) of several pollutants adopted by the environmental protection department, the first-level and second-level concentration standards of this model correspond to the standards in the “Ambient Air Quality Standard”. Moreover, the obvious hazardous concentration limit is used as the third-level concentration limit for this model.
Table 1 lists the background concentration limits
(Cj0), obvious hazard limits (
Cjd), and primary and secondary standard concentration limits (
Cj1 and
Cj2, respectively) of each evaluation indicator.
Table 2 shows the normalized scale sub-index
Ijk under the corresponding level obtained from
Table 1 and Equation (3).
2.2.2. Calculation of Generalized Contrastive Weighted Value
Factor weighting is based on the principle that a larger scale sub-index of the factor results in a larger weight. However, it is not a simple linear relationship. As
Figure 1 shows, the weight change of the smaller scale sub-index should be greater than the linear change, while the weight change of the larger scale sub-index should be less than the linear change. On this basis, the importance of the smaller scale sub-index in the evaluation should be appropriately increased, while the importance of the larger scale sub-index should be appropriately suppressed. Therefore, when the scale sub-index of a factor is 0.5, its weight does not change. When the scale sub-index is greater than 0.5, and especially when it is close to 1, its weight should be properly suppressed. In addition, when the scale sub-index is smaller than 0.5, and especially when it is close to 0, its weight should be properly strengthened. The rate at which the weight changes with the sub-index can be controlled by changing the value of the adjustable parameter
p.
Finally, the calculation equation of the generalized contrast weight
Wj′ is [
31]:
where
p is an adjustable parameter that controls the speed of weight change, and its value range is 0 ≤
p ≤ 1.
Generally, the value of
p is 1/2. Considering that the sub-index calculated by Equation (2) may be less than 0 and greater than 1, Equation (4) is extended to obtain the final calculation in Equation (5) [
31]:
2.2.3. Calculation of Generalized Contrastive Weighted Comprehensive Scale Index
The weight
Wj is normalized to obtain
:
On the basis, the equation for calculating the generalized contrastive weighted comprehensive scale index (
I) of the air quality in underground coal mines is obtained:
where
is the normalized generalized contrastive weighted value.
The frame diagram of this optimization model is shown in
Figure 2.
2.2.4. Classification of Underground Air Quality in Coal Mines
According to Equations (3) and (5)–(7), the generalized contrastive weighted comprehensive scale index
I at all levels is obtained based on the standard values of each substance specified in the Ambient Air Quality Standard. Then, the correspondence between the grading evaluation standard of hazardous substances and its comprehensive scale index is obtained: grade I, I ∈ (0, 0.490); grade II, II ∈ (0.490, 0.668); grade III, III ∈ (0.668, 1); grade IV, IV ∈ (1, +∞).
Table 3 shows the classification and evaluation standard of underground air quality in coal mines.
Grade I refers to the coal mine underground with excellent air quality and safety. Under this grade, the coal mine can be maintained and workers can continue to work. Grade II refers to coal mines with good air quality and a relatively safe state. Under this grade, workers need to take precautions, wear individual protective masks, and turn on the spray to reduce dust. Grade III refers to poor air quality in underground coal mines, which is slightly dangerous. Under this grade, the cause must be identified, and strengthening measures such as additional dust collectors and increased ventilation must be adopted to improve the air quality in underground coal mines. Grade IV refers to poor air quality in the underground coal mine, which is in a serious state of danger. Under this grade, the environment can cause significant harm to the operators. Warnings should be issued to underground operators immediately. Moreover, compulsory measures such as shortening operating time, evacuating areas with excessive hazardous substances, overhauling underground ventilation measures, and using harmful substance elimination technologies should be taken to improve the air quality in coal mines [
28].
To evaluate the air quality in underground coal mines, the concentration values of the evaluation indicators at each monitoring point should be first measured. Afterward, the comprehensive scale index is derived according to Equations (3) and (5)–(7), and then the evaluation grade is obtained. Finally, a series of disposal measures can be taken regarding the evaluation grade to improve the air quality of underground coal mines.