Analysis of the Cross-Linking Reaction of Lignin with Triethyl Phosphate by MALDI-TOF and 13C NMR
Abstract
:1. Introduction
2. Materials and Methods
2.1. Preparation of Resins
2.2. Characterization of Samples
2.2.1. CP-MAS 13C NMR Analysis
2.2.2. MALDI-TOF Analysis
2.2.3. Wood Surface Coating Application
2.2.4. Metallic Surface Coating Application
3. Results
3.1. CP-MAS 13C NMR Analysis
3.2. MALDI-TOF Analysis
3.3. Wood Surface Coating Application: Contact Angle Measures with Water
3.4. Metallic Surface Coating Application: Adhesion Tests
5. Conclusions
Supplementary Materials
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Sample | Temperature (°C) | Composition | ||||
---|---|---|---|---|---|---|
Lignin 3 g | NH3 (25%) 1.5 g | TEP 3 g | Catechol 3 g | Glycerol 3 g | ||
S0 | - | X | - | - | - | - |
S1 | 180 | X | - | X | - | - |
S2 | 180 | X | X | X | - | - |
S3 | 180 | - | - | X | X | - |
S4 | 180 | - | X | X | X | - |
S5 | 180 | - | - | X | - | X |
S6 | 90 | X | - | X | - | - |
S7 | 90 | - | X | X | - | X |
S8 | 220 | X | - | X | - | - |
S9 | 220 | X | X | X | - | - |
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Basso, M.C.; Pizzi, A.; Delmotte, L.; Abdalla, S. Analysis of the Cross-Linking Reaction of Lignin with Triethyl Phosphate by MALDI-TOF and 13C NMR. Polymers 2017, 9, 206. https://doi.org/10.3390/polym9060206
Basso MC, Pizzi A, Delmotte L, Abdalla S. Analysis of the Cross-Linking Reaction of Lignin with Triethyl Phosphate by MALDI-TOF and 13C NMR. Polymers. 2017; 9(6):206. https://doi.org/10.3390/polym9060206
Chicago/Turabian StyleBasso, María Cecilia, Antonio Pizzi, Luc Delmotte, and Soliman Abdalla. 2017. "Analysis of the Cross-Linking Reaction of Lignin with Triethyl Phosphate by MALDI-TOF and 13C NMR" Polymers 9, no. 6: 206. https://doi.org/10.3390/polym9060206