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Polymers 2017, 9(10), 542;

Novel Polyamides with 5H-Dibenzo[b,f]azepin-5-yl-Substituted Triphenylamine: Synthesis and Visible-NIR Electrochromic Properties

Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, Department of Macromolecular Science and Engineering, School of Chemical, Chemical Engineering and Materials, Heilongjiang University, Harbin 150086, China
School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150080, China
Authors to whom correspondence should be addressed.
Received: 29 September 2017 / Revised: 17 October 2017 / Accepted: 20 October 2017 / Published: 23 October 2017
(This article belongs to the Special Issue High Performance Polymers)
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In this study, a new diamine monomer, namely 4,4′-diamino-4″-(5H-dibenzo[b,f]azepin-5-yl)triphenylamine, was prepared and polymerized with four kinds of dicarboxylic acids via direct polycondensation reaction resulting in a novel series of soluble and electroactive polyamides (PAs). The tough thin films of all PAs could be solution-cast onto an indium-tin oxide (ITO)-coated glass substrate owing to the good solubility in polar organic solvents. Two pairs of obvious redox peaks for these films were observed in cyclic voltammetry (CV) with low onset potentials (Eonset) of 0.37–0.42 V accompanying with remarkable reversible color changes between light yellow and dark blue. A new absorption peak at around 915 nm emerged in near infrared (NIR) spectra; the increasing potential indicated that PAs could be used as a NIR electrochromic material. Moreover, the PAs showed high coloration efficiency (CE; η) in the range of 190–259 cm2 C−1. View Full-Text
Keywords: triphenylamine; 5H-dibenzo[b,f]azepine; polyamide; electrochemical triphenylamine; 5H-dibenzo[b,f]azepine; polyamide; electrochemical

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Lu, Q.; Cai, W.; Niu, H.; Wang, W.; Bai, X.; Hou, Y. Novel Polyamides with 5H-Dibenzo[b,f]azepin-5-yl-Substituted Triphenylamine: Synthesis and Visible-NIR Electrochromic Properties. Polymers 2017, 9, 542.

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