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Polymers 2017, 9(10), 465; https://doi.org/10.3390/polym9100465

Shape Memory Polyurethanes Based on Zwitterionic Hard Segments

1
Shenzhen Key Laboratory of Functional Polymer, College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, China
2
Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, China
3
Guangdong Research Center for Interfacial Engineering of Functional Materials, Shenzhen Key Laboratory of Polymer Science and Technology, Shenzhen Key Laboratory of Special Functional Materials, Nanshan District Key Lab for Biopolymers and Safety Evaluation, College of Materials Science and Engineering, Shenzhen University, Shenzhen 518060, China
*
Authors to whom correspondence should be addressed.
Received: 2 September 2017 / Revised: 17 September 2017 / Accepted: 18 September 2017 / Published: 21 September 2017
(This article belongs to the Special Issue Shape Memory Polymers)
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Abstract

This work aimed at elucidating the influence of zwitterionic hard segments on the structures and properties of shape memory polyurethanes (SMPUs). A series of zwitterionic SMPUs was successfully prepared with N-methyldiethanolamine (MDEA), 1,3-propanesultone (1,3-PS), 1,6-hexamethylene diisocyanate (HDI) and polyethylene glycol (PEG6000). The influence of MDEA-PS-based zwitterionic hard segment on structure, morphology, thermal property, shape memory property and cytocompatibility were systematically investigated. The results demonstrated that the PEG-based zwitterionic SMPUs (PEG-ZSMPUs) formed phase separation structure consisting of crystalline soft phase and amorphous hard phase. The MDEA-PS zwitterionic segments showed a tendency to form ionic clusters in hard segments, which served as reinforced net points. Shape memory analysis showed that zwitterionic PEG-ZSMPUs containing a high content of zwitterionic segments had thermal-induced shape memory effects. Finally, cytotoxic assays demonstrated that MDEA-PS zwitterionic segment improved the biocompatibility of PEG-ZSMPUs. The zwitterionic PEG-ZSMPUs could thus have a promising application in smart biomedical fields. View Full-Text
Keywords: shape memory; polyurethane; N-methyldiethanolamine; zwitterionic polymer; biocompatibility shape memory; polyurethane; N-methyldiethanolamine; zwitterionic polymer; biocompatibility
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Fu, S.; Ren, H.; Ge, Z.; Zhuo, H.; Chen, S. Shape Memory Polyurethanes Based on Zwitterionic Hard Segments. Polymers 2017, 9, 465.

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