Aromatic Copolyamides with Anthrazoline Units in the Backbone: Synthesis, Characterization, Pervaporation Application
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Polymer Synthesis
2.3. Film Preparation
2.4. Thermogravimetric Analysis (TGA)
2.5. Scanning Electron Microscopy
2.6. Physical Properties
2.7. Sorption Experiment
2.8. Pervaporation
3. Results and Discussion
3.1. Physical and Thermal Properties
3.2. Films Structure
3.3. Sorption Study
3.4. Pervaporation of Methanol–Toluene Mixture
3.5. Comparison of Pervaporation Properties with Literature Data
4. Conclusions
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Film | Glass transition temperature, °C | Density, g/сm3 | Solubility parameter δ, (J/сm3)0.5 | Fractional free volume |
---|---|---|---|---|
PA | 184 | 1.307 | 24.84 | 0.342 |
coPA-20 | 204 | 1.313 | 24.92 | 0.355 |
coPA-30 | 211 | 1.319 | 24.96 | 0.361 |
Polymer | T, °C | Total flux, g/m2h | Methanol in permeate, wt % | Permeance (P/l)Methanol, GPU | Selectivity (βMethanol-Toluene) | References |
---|---|---|---|---|---|---|
coPA-20 | 50 | 107.0 | 97.5 | 301 | 11 | Present work |
coPA-30 | 50 | 126.0 | 96.3 | 316 | 7.0 | |
Polyamide/MMT (3%) | 50 | 112 | 99.2 | 78 | 11 | [26] |
Polyimide | 50 | 16.0 | 92.1 | 9.9 | 1.0 | [27] |
Polyimide/polyanyline | 50 | 12.5 | 94.9 | 8.0 | 1.6 | [27] |
Poly(phenyleneoxide) | 30 | 300 | 98.6 | 502 | 19 | [28] |
Cellulose acetate | 30 | 1400 | 92.1 | 2188 | 3.2 | [29,30] |
Cellulose triacetate | 30 | 370 | 92.1 | 578 | 3.2 | [29,30] |
Cellulose acetate/Cellulose butyrate | 30 | 500 | 92.1 | 781 | 3.2 | [29] |
Polyphthalamide/poly(vinylalcohol) | 30 | 250 | 99.6 | 422 | 68 | [31] |
Poly(vinylalcohol)/(Hydroxy(ethyl) methacrylate + aceticanhydride) | 30 | 1100 | 98.6 | 1840 | 19 | [32] |
Chitosan | 35 | 1000 | 99.4 | 1318 | 45 | [33] |
Chitosan/aceticanhydride (4%) | 35 | 1000 | 99.3 | 1932 | 57 | |
Copolymer of perfluoro-2,2-dimethyl-1,1,3-dioxole and tetrafluoroethylene (25% toluene) | 50 | 1.7 | 95.2 | 96 | 15 | [34] |
Interpenetrating network of vinylterminated poly(dimethylsiloxane) and aromatic polyimide (90:10) | 30 | 52 | 92.3 | 2839 | 9.3 | [35] |
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Polotskaya, G.A.; Pulyalinа, A.Y.; Goikhman, M.Y.; Podeshvo, I.V.; Valieva, I.A.; Toikka, A.M. Aromatic Copolyamides with Anthrazoline Units in the Backbone: Synthesis, Characterization, Pervaporation Application. Polymers 2016, 8, 362. https://doi.org/10.3390/polym8100362
Polotskaya GA, Pulyalinа AY, Goikhman MY, Podeshvo IV, Valieva IA, Toikka AM. Aromatic Copolyamides with Anthrazoline Units in the Backbone: Synthesis, Characterization, Pervaporation Application. Polymers. 2016; 8(10):362. https://doi.org/10.3390/polym8100362
Chicago/Turabian StylePolotskaya, Galina A., Alexandra Yu. Pulyalinа, Mikhail Ya. Goikhman, Irina V. Podeshvo, Irina A. Valieva, and Alexander M. Toikka. 2016. "Aromatic Copolyamides with Anthrazoline Units in the Backbone: Synthesis, Characterization, Pervaporation Application" Polymers 8, no. 10: 362. https://doi.org/10.3390/polym8100362