2.1. Material Characterization
NatureWorks Ingeo 3251D polylactic acid (PLA) has been used to investigate the effect of different printing parameters on the possibility of minimizing bridging in PAM.
The data required to conduct computational analyses included the following:
Density: expressed as a function of temperature;
Rheology: dynamic viscosity expressed as a function of temperature and shear rate;
Thermodynamics: thermal conductivity () and specific heat capacity (), whose values depend on temperature.
The material properties implemented in the FE simulations are represented in
Figure 2.
Material properties have been extracted through the software Autodesk Moldflow v.21. In particular, the specific heat (
) and glass transition temperature (
) were determined using differential scanning calorimetry (DSC). The measurements adhered to the ASTM E 1269 and ASTM D 3418 standards [
26,
27] for the measurement of
and
, respectively. Samples, in pellet form, were subjected to a controlled cooling rate of 20 °C/min from 230 °C to 50 °C prior to the analysis.
Thermal conductivity (
) was measured using the transient line-source technique, following the specifications of ASTM D 5930 [
28]. Prior to testing, the pellet-form samples were dried in a hopper dryer for 4 h at 70 C to achieve a low initial moisture content of 0.017%.
Rheological data expresses the non-linear relationship between dynamic viscosity (
) and both shear rate (
) and temperature (
). At very low shear rates (i.e., for
11/s, as shown in
Figure 2a), PLA behaves as a Newtonian fluid, while a power–law relationship (i.e., a straight line in the double logarithmic representation of
, see
Figure 2a) can be observed at higher ones. The effective shear rate in a PAM process depends on (i) screw peripheral speed (
), (ii) nozzle diameter (
) and (iii) printhead speed (
).
A model to predict the material behavior in the metering zone of PAM barrel-screw systems depending on
has been proposed in [
29]. However, the influence of process parameters when printing support-free structures has not been modeled yet; it therefore constitutes the main goal of this work.
2.3. Computational Model
The computational domain consisted of a double-clamped beam made up of viscous material. To fully capture the deformation of the viscous beam under the influence of its own weight, the software COMSOL Multiphysics v. 5.3 (COMSOL, Inc., Burlington, MA, USA) was employed.
The fluid is assumed to be purely viscous, i.e., the elongational effects are neglected. In addition, flow is assumed to be laminar since the Reynolds number remains below the unit for all process parameter combinations being investigated.
Consequently, laminar flow and heat transfer in fluid COMSOL modules were combined to define a comprehensive multi-physical model.
The governing equations solved to fully capture the transient gravity-induced deformation of the aforementioned viscous beam are as follows:
These are the continuity, momentum and energy equations, respectively. In particular, is the computational time, is the fluid velocity vector, is the fluid density, is the fluid pressure, is the viscous stress tensor, is the gravity acceleration, is the specific heat, is the extrusion temperature, and is the heat flux.
A schematic representation of the boundary conditions employed to solve the former system and the final deformed shape are represented in
Figure 3.
In the momentum equation, the shear stress tensor
can be calculated as follows:
In the former expression,
,
and
are the dynamic viscosity, shear rate and rate of deformation tensor, respectively. Shear rate is related to the effective amount of fluid deformation as follows:
Because of the highly non-linear dependence of material rheology on shear rate and temperature (see
Figure 2a), Cross-WLF rheological modeling was employed:
Here,
is the zero-shear viscosity, whose dependence on temperature can be expressed with an Arrhenius-type relationship:
is the zero-shear viscosity at a reference temperature
and zero pressure.
governs the slope of the viscosity–temperature curve and the overall temperature sensitivity.
is the critical stress level at the transition to shear-thinning.
is the power–law index, defining the degree of shear-thinning in the high-shear rate regime (i.e., the lower the power–law index, the stronger the shear-thinning behavior). The reference temperature
can be expressed as follows:
Here, is the glass transition temperature, a data-fitted coefficient and the pressure.
The Data Fitting module available for Autodesk Moldflow was used to calculate the best fit for the remaining Cross-WLF parameters (i.e.,
,
,
,
,
and
), which are reported in
Table 2.
The expression for given in Equation (4) was used, together with the shear stress tensorial expression of Equation (2), to model the viscous contribution of the molten thermoplastic and solve Equation (1).
To solve the energy equation, density , specific heat and thermal conductivity data were linearly interpolated between contiguous temperature intervals.
However, a complete model for sagging also requires the solution of the heat transfer between molten thermoplastics and the surrounding air.
Since the overhanging strand can be approximated as a cylinder whose diameter depends on process parameters (e.g., extrusion temperature
and printhead speed
) and geometry (nozzle diameter
), correlations from the literature can be used to model the heat exchanged by convection. These have proved to be efficient with respect to experimental data in the recent literature [
25].
The heat transfer rate boundary condition has been applied to the air-to-thermoplastic interface, pointing outwards orthogonally to the boundary itself (see
Figure 3a).
Here, HTC is the heat transfer coefficient, the air-to-thermoplastic interfacial area, the local thermoplastic temperature and the surrounding air temperature (set to 25 °C in all computations). In this way, the heat transfer is solved locally for each computational cell belonging to the viscous beam geometry and for the exact PAM process parameters.
HTC was evaluated differently when considering 3D printing of overhanging structures with a fan in the On or Off state. In fact, in the former case, HTC is higher because of the influence of forced convection, while in the latter, heat is exchanged only by natural convection.
When considering forced convection, the following correlation can be applied to calculate the Nusselt number:
Here, and represent the Reynolds and Prandtl numbers, respectively.
When the fan is not activated (i.e., Off state), thermoplastics exchange heat with the surrounding air by natural convection. In this case, a different correlation applies [
30]:
In addition to the aforementioned dimensionless parameters, stands for the Rayleigh number.
In the former correlations, all fluid properties were evaluated at the mean film temperature:
In this expression, and are the nozzle and surrounding air temperatures, respectively.
HTC has been evaluated through parameter-dependent values of thermal conductivity
, Nusselt number
and effective strand diameter
, which was considered as the characteristic length:
The calculation of
follows the mass conservation principle; this aspect will be shown in
Section 3.4.
Finally, a free surface boundary condition has been applied to the air-to-thermoplastic interface:
A moving mesh approach was exploited to track the deformation of the computational grid, as gravity exerts its influence on the unsupported viscous thermoplastic strand.
The initial condition needed to solve the energy equation in Equation (1) was imposed in a way that initial temperature was set equal to the extrusion temperature (i.e., ), while zero velocity and pressure were initially set for fluid flow variables. The coupling of energy with the momentum equation is given by the viscous dissipation term (i.e., in energy equation, see Equation (1)).
First-order shape functions were used to solve velocity and pressure fields, and second-order ones for temperature. Simulations were performed on an Intel i7-13620H octa-core processor with 16 GB DDR5 5200 MHz RAM.