Study on Microstructure Evolution and Deformation Failure Mechanism of PTFE-Cu Composites Under Compression Load

In order to study the microstructure evolution of polytetrafluoroethylene–copper (PTFE-Cu) composites under compression load and reveal the molecular dynamics mechanism of deformation failure, three PTFE-Cu composites with different densities (3.0 g/cm³, 3.5 g/cm³, 4.0 g/cm³) were prepared in this study. The crystallinity of PTFE in each sample was determined via differential scanning calorimetry (DSC). The quasi-static compression mechanical properties test was carried out to analyze the effect of PTFE crystallinity on the macroscopic mechanical response of the composites. It is found that the crystallinity of the three PTFE-Cu composites was 43.05%, 39.49% and 40.13%, respectively, showing a non-monotonic trend of decreasing first and then increasing with an increase in copper powder content. The elastic modulus and yield strength of the material are negatively correlated with the crystallinity. The failure mode is the axial splitting failure and the composite morphology of axial splitting failure and shear tearing. Finally, the molecular dynamics simulation method is used to reveal the microstructure evolution and deformation failure mechanism of PTFE-Cu composites under compression load from the atomic scale, which provides a theoretical basis and experimental support for understanding the mechanical properties of PTFE-Cu composites.