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Article

A Unified Equation for Predicting Crack Growth in Rubber Composites Across All Crack Growth Rates

by
Aaron M. Duncan
1,*,
Keizo Akutagawa
1,
Dimitrios G. Papageorgiou
1,
Julien L. Ramier
2 and
James J. C. Busfield
1,*
1
School of Engineering and Material Science, Queen Mary University of London, Mile End Road, London E1 4NS, UK
2
SLB Cambridge Research, Cambridge CB3 0EL, UK
*
Authors to whom correspondence should be addressed.
Polymers 2025, 17(10), 1357; https://doi.org/10.3390/polym17101357
Submission received: 17 April 2025 / Revised: 10 May 2025 / Accepted: 13 May 2025 / Published: 15 May 2025
(This article belongs to the Special Issue Failure of Polymer Composites)

Abstract

The relationship between tearing energy and crack growth rates in elastomers is typically divided into three regions—slow crack growth, fast crack growth, and a transitional region—each described by separate power law relationships, requiring six variables to fully characterize the behavior. This study introduces a novel, unified equation that simplifies this relationship by combining two coexisting energy dissipation mechanisms into a single model with only four variables. The model consists of two terms, one for each energy dissipation mechanism: one term is dominant at slow crack growth rates and limited by a threshold energy, and the other is dominant at fast speeds. The transition region emerges naturally as the dominant mechanism shifts. The model’s simplicity enables new advances, such as predicting fast crack growth tearing and transition energies using only slow crack growth data. This capability is demonstrated across a wide range of non-strain crystallizing rubbers, including filled and unfilled compounds, tested at room temperature and elevated temperatures and in both swollen and unswollen states. This model offers a practical tool for material design, failure prediction, and reducing experimental effort in characterizing elastomer performance. Notably, this is the first model to unify slow, transition, and fast crack growth regimes into a single continuous equation requiring only four variables, enabling the prediction of high-speed behavior using only low-speed experimental data—a major advantage over existing six-parameter models.
Keywords: crack growth rate; tearing energy; energy dissipation; failure prediction crack growth rate; tearing energy; energy dissipation; failure prediction

Share and Cite

MDPI and ACS Style

Duncan, A.M.; Akutagawa, K.; Papageorgiou, D.G.; Ramier, J.L.; Busfield, J.J.C. A Unified Equation for Predicting Crack Growth in Rubber Composites Across All Crack Growth Rates. Polymers 2025, 17, 1357. https://doi.org/10.3390/polym17101357

AMA Style

Duncan AM, Akutagawa K, Papageorgiou DG, Ramier JL, Busfield JJC. A Unified Equation for Predicting Crack Growth in Rubber Composites Across All Crack Growth Rates. Polymers. 2025; 17(10):1357. https://doi.org/10.3390/polym17101357

Chicago/Turabian Style

Duncan, Aaron M., Keizo Akutagawa, Dimitrios G. Papageorgiou, Julien L. Ramier, and James J. C. Busfield. 2025. "A Unified Equation for Predicting Crack Growth in Rubber Composites Across All Crack Growth Rates" Polymers 17, no. 10: 1357. https://doi.org/10.3390/polym17101357

APA Style

Duncan, A. M., Akutagawa, K., Papageorgiou, D. G., Ramier, J. L., & Busfield, J. J. C. (2025). A Unified Equation for Predicting Crack Growth in Rubber Composites Across All Crack Growth Rates. Polymers, 17(10), 1357. https://doi.org/10.3390/polym17101357

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