High Mechanical Properties of Stretching Oriented Poly(butylene succinate) with Two-Step Chain Extension
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Preparation of Two-Step Chain-Extended and Pre-Stretched Sample
2.2.1. Mechanical Properties
2.2.2. Crystallization Process and Crystalline Structure Characterization
2.2.3. Morphological Characterization
2.2.4. Rheological Analysis
2.2.5. Infrared Spectroscopic Analysis
3. Results and Discussion
3.1. The Influence of Chain Extension Reaction on PBS
3.2. The Energy Release Rate of PBS Samples
3.3. Characterization of the Crystalline Morphology in PBS Samples
3.4. Characterization of Flaw Sensitivity Properties of PBS
3.5. Spherulite Morphology and Crystal Structure
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Sample Code | Chain Extension for PBS a) | Pre-Stretching b) | |||||
---|---|---|---|---|---|---|---|
PBS | ADR9 | BOZ | λpre | λfix | ε (%) | L0 (mm) | |
Virgin PBS | 100 | 0 | 0 | 1.2 | 1 | 120 | 20 |
PBSA0.4 | 99.6 | 0.4 | 0 | 3.2 | 3 | 320 | 20 |
PBS A0.6 | 99.4 | 0.6 | 0 | 5.3 | 5 | 530 | 20 |
PBS A0.6B0.6 | 98.8 | 0.6 | 0.6 | 7.5 | 7 | 750 | 20 |
PBS A0.6B0.8 | 98.6 | 0.6 | 0.8 | 9.8 | 9 | 980 | 20 |
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Li, X.; Xia, M.; Dong, X.; Long, R.; Liu, Y.; Huang, Y.; Long, S.; Hu, C.; Li, X. High Mechanical Properties of Stretching Oriented Poly(butylene succinate) with Two-Step Chain Extension. Polymers 2022, 14, 1876. https://doi.org/10.3390/polym14091876
Li X, Xia M, Dong X, Long R, Liu Y, Huang Y, Long S, Hu C, Li X. High Mechanical Properties of Stretching Oriented Poly(butylene succinate) with Two-Step Chain Extension. Polymers. 2022; 14(9):1876. https://doi.org/10.3390/polym14091876
Chicago/Turabian StyleLi, Xun, Min Xia, Xin Dong, Ren Long, Yuanhao Liu, Yiwan Huang, Shijun Long, Chuanqun Hu, and Xuefeng Li. 2022. "High Mechanical Properties of Stretching Oriented Poly(butylene succinate) with Two-Step Chain Extension" Polymers 14, no. 9: 1876. https://doi.org/10.3390/polym14091876