Sustainable Polyurethane Networks Based on Rosin with Reprocessing Performance
Abstract
:1. Introduction
2. Experimental
2.1. Materials
2.2. Synthesis of Maleopimaric Anhydride (MPA)
2.3. Synthesis of an Esterified Adduct of MPA with Pentaerythritol (PEMPA)
2.4. Synthesis of the VPUOH Cross-Linking Network
2.5. Characterizations
3. Results and Discussion
3.1. Covalent Cross-Linking of VPUOH Using HDI
3.2. Mechanical Properties, Thermal Performance, and Dynamic Properties Analysis
3.3. Self-Healing, Welding, and Shape Memory
3.4. Reprocessing
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Acknowledgments
Conflicts of Interest
References
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Sample | Tg (°C) | E′ (Tg + 30 °C) (MPa) | Ve (mol/cm3) | Elongation at Break (%) | Tensile Strength (MPa) | Toughness (MJ/m3) | Young’s Modulus (MPa) | T5d (°C) | T10d (°C) |
---|---|---|---|---|---|---|---|---|---|
30%VPUOH | 72.7 | 1.6 | 1.7 × 10−4 | 119 ± 4.1 | 8.1 ± 0.8 | 581 ± 65.1 | 0.49 ± 0.02 | 176 | 222 |
40%VPUOH | 75.2 | 3.0 | 3.1 × 10−4 | 92 ± 1.0 | 9.5 ± 0.1 | 592 ± 62.1 | 0.64 ± 0.04 | 187 | 224 |
50%VPUOH | 71.0 | 6.5 | 6.8 × 10−4 | 89 ± 4.7 | 10.5 ± 0.9 | 609 ± 60.2 | 0.78 ± 0.04 | 188 | 230 |
60%VPUOH | 71.2 | 7.2 | 7.5 × 10−4 | 84 ± 6.8 | 13.1 ± 1.2 | 743 ± 59.5 | 0.98 ± 0.05 | 191 | 237 |
70%VPUOH | 72.1 | 7.3 | 7.6 × 10−4 | 69 ± 7.9 | 15.4 ± 0.7 | 828 ± 82.7 | 1.19 ± 0.05 | 198 | 251 |
80%VPUOH | 69.3 | 15.3 | 16.1 × 10−4 | 61 ± 4.2 | 16.8 ± 1.6 | 972 ± 68.2 | 2.43 ± 0.06 | 199 | 249 |
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Li, J.; Yang, W.; Ning, Z.; Yang, B.; Zeng, Y. Sustainable Polyurethane Networks Based on Rosin with Reprocessing Performance. Polymers 2021, 13, 3538. https://doi.org/10.3390/polym13203538
Li J, Yang W, Ning Z, Yang B, Zeng Y. Sustainable Polyurethane Networks Based on Rosin with Reprocessing Performance. Polymers. 2021; 13(20):3538. https://doi.org/10.3390/polym13203538
Chicago/Turabian StyleLi, Jiawei, Weiming Yang, Zhao Ning, Bin Yang, and Yanning Zeng. 2021. "Sustainable Polyurethane Networks Based on Rosin with Reprocessing Performance" Polymers 13, no. 20: 3538. https://doi.org/10.3390/polym13203538