Chitosan–Hydroxyapatite Composite Layers Generated in Radio Frequency Magnetron Sputtering Discharge: From Plasma to Structural and Morphological Analysis of Layers
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Synthesis of Chitosan–Hydroxyapatite Composites
2.3. Synthesis of Chitosan–Hydroxyapatite Layers
2.4. Characterization Methods
3. Results
3.1. Plasma Characterization by Langmuir Probe Electrical Measurements
3.2. Mass Spectra Analysis of Synthesis Plasma
3.3. XPS Analysis of Hydroxyapatite–Chitosan Coatings
3.4. Fourier Transform Infrared Spectroscopy Analyses of Chitosan–Hydroxyapatite Composite Coatings
3.5. SEM Analysis of HAp–Chitosan Coatings
3.6. EDS Analysis of HApCs Coatings
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Ar gas Working Pressure (mbarr) | Ar Gas Flow (sln/min) | Rf Power | Te (eV) HApCh (1 eV = 11,600 K) | ne (m−3) HApCh |
---|---|---|---|---|
2 × 10−3 | 0.8 | 30 W | 3.2 | 7.8 × 1014 |
5 × 10−3 | 2.4 | 30 W | 2.5 | 9 × 1014 |
1.2 × 10−2 | 4.5 | 30 W | 1.9 | 1 × 1015 |
2 × 10−3 | 0.8 | 50W | 2.5 | 1.2 × 1015 |
5 × 10−3 | 2.4 | 50W | 2.2 | 1.3 × 1015 |
1.2 × 10−2 | 4.5 | 50W | 1.8 | 1.6 × 1015 |
2 × 10−3 | 0.8 | 70 W | 2.9 | 1.5 × 1015 |
5 × 10−3 | 2.4 | 70 W | 2.1 | 1.8 × 1015 |
1.2 × 10−2 | 4.5 | 70 W | 1.7 | 1.9 × 1015 |
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Dreghici, D.B.; Butoi, B.; Predoi, D.; Iconaru, S.L.; Stoican, O.; Groza, A. Chitosan–Hydroxyapatite Composite Layers Generated in Radio Frequency Magnetron Sputtering Discharge: From Plasma to Structural and Morphological Analysis of Layers. Polymers 2020, 12, 3065. https://doi.org/10.3390/polym12123065
Dreghici DB, Butoi B, Predoi D, Iconaru SL, Stoican O, Groza A. Chitosan–Hydroxyapatite Composite Layers Generated in Radio Frequency Magnetron Sputtering Discharge: From Plasma to Structural and Morphological Analysis of Layers. Polymers. 2020; 12(12):3065. https://doi.org/10.3390/polym12123065
Chicago/Turabian StyleDreghici, Dragana Biliana, Bogdan Butoi, Daniela Predoi, Simona Liliana Iconaru, Ovidiu Stoican, and Andreea Groza. 2020. "Chitosan–Hydroxyapatite Composite Layers Generated in Radio Frequency Magnetron Sputtering Discharge: From Plasma to Structural and Morphological Analysis of Layers" Polymers 12, no. 12: 3065. https://doi.org/10.3390/polym12123065