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Peer-Review Record

In Situ Preparation of Amphibious ZnO Quantum Dots with Blue Fluorescence Based on Hyperbranched Polymers and their Application in Bio-Imaging

Polymers 2020, 12(1), 144; https://doi.org/10.3390/polym12010144
by Gaiying Lei 1,†, Shu Yang 2,3,†, Ranran Cao 2,3,†, Peng Zhou 2,3, Han Peng 2,3, Rui Peng 2,3, Xiaoming Zhang 2,3, Yujiao Yang 2,3, Yueyang Li 2,3, Mengyue Wang 2,3, Yaru He 2,3, Linzhu Zhou 4, Jimin Du 2,3, Weimin Du 2,3, Yunfeng Shi 2,3,* and Hankui Wu 2,3,*
Reviewer 1: Anonymous
Reviewer 2: Anonymous
Polymers 2020, 12(1), 144; https://doi.org/10.3390/polym12010144
Submission received: 24 November 2019 / Revised: 24 December 2019 / Accepted: 1 January 2020 / Published: 6 January 2020
(This article belongs to the Section Polymer Applications)

Round 1

Reviewer 1 Report

The paper reports on the preparation of ZnO quantum dots using hyperbranched Poly (ethyleneimine). The hybrid material shows high solubility in organic and aqueous solvents. The authors suggest that such materials can be used in optoelectronic and in biomedical applications. However, the amount of the ZnO QDs is only 3% in the PEI matrix. Did the authors attempt to increase the QD content? Is this amount enough for the proposed applications? The authors should elaborate on these questions and include the relative discussion on their work. Additionally the references should be updated since there are recent publications in this matter that are missing.

Author Response

Please see the attachment.

Author Response File: Author Response.docx

Reviewer 2 Report

The paper titled "In situ preparation of amphibious ZnO quantum dots with blue fluorescence based on hyperbranched polymers and their application in bio-imaging" deals with the preparation on Quantum Dots based on Zinc Oxide and polyethyleneimines.

The paper is interesting and well written, I have only some minor points to be clarified

1) 2.1 Materials: HPEI is defined via DB and Mn but "DB" is not defined (I guess it is Degree of Branching) and Mn units are not given (should be Daltons). The same occurs in 2.2.3, where che MWCO is 1k with no units.

2) In 2.1 again, zinc acetate is indicated as Zn(AC)2 but usually zinc acetate is indicated as Zn(OAc)2.

3) 2.3 Measurements: measurements are not well specified. For example: how were UV-vis solutions prepared? concentrations, solvents etc.

How were TGA performed? Temperatures, gas, heating rate

How TEM samples were prepared?

This point must be largely improved

Author Response

Please see the attachment.

Author Response File: Author Response.docx

Round 2

Reviewer 1 Report

The authors have addressed all the comments so as the paper can be accepted in its present form.

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